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Preparation of BaTiO3 Powder in $BaO2-TiO2-Reduction Agent-PSCA (Particle Size Control Agent) System by SHS and Its Dielectric Properties (B3O2-TiO2-환원제-입자제어제계에서 자전연소합성법에 의한 BaTiO3분말의 제조 및 유전특성)

  • Yun, Ki-Seok;Lim, Sung-Jae;Nersisyan, Hayk;Won, Chang-Whan
    • Journal of the Korean Ceramic Society
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    • v.41 no.11
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    • pp.842-850
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    • 2004
  • We have investigated on the preparation of BaTiO$_3$ powder at the system of BaO$_2$-TiO$_2$-Reduction ag.-PSCA by SHS. C and Mg were used as reduction agent, and NaCl was used as PSCA (Particle Size Control Agent). The effects of the various reduction agent and its concentration, particle size control agent, reaction mixture mass on the product in the preparation of BaTiO$_3$ powder at the optimum system by SHS were investigated. The optimum conditions for reaction system and composition were BaO$_2$+TiO$_2$+0.11 Mg +0.2C+0.75NaCl in the As atmosphere. NaCl as PSCA showed the effect of controlling the particle size of product as well as the combustion temperature. The particle size of BaTiO$_3$ synthesized at the optimum condition was about 0.5 ${\mu}{\textrm}{m}$. And as the mixture mass for the reaction was increased, the more stable combustion wave appeared. We have conducted the sintering experiment at the temperature of 130$0^{\circ}C$, the time of 2 h and the atmosphere of air to measure the dielectric properties of BaTiO$_3$ synthesised in this work, and the sample sintered in this condition showed 2,290 of dielectric constant at 10$0^{\circ}C$ and 13,890 at curie point (129$^{\circ}C$).

Neutron Irradiation Effect of YBa2Cu3O7-y Superconductor (YBa2Cu3O7-y 초전도 벌크의 중성자 조사 효과)

  • Lee, Sang Heon
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.34 no.6
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    • pp.438-441
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    • 2021
  • The electrical characteristics of single-crystal composite superconductors produced by a melting process were studied by neutron irradiation. In order to improve the current characteristics of the YBa2Cu3O7-y superconductor, it is necessary to form an effective flux pinning center inside the superconductor. In this study, an increase in flux pinning was attempted through neutron irradiation onto YBa2Cu3O7-y superconductors. The neutron irradiation was performed at 30 MeV for 500 sec, The electrical properties of the superconductors were measured in a magnetic field of 5 Tesla at 50 K using a magnetic properties measurement system (MPMS). After neutron irradiation, the critical current density of the YBa2Cu3O7-y superconductor in a 1 Tesla magnetic field was 1×105 A/cm2. Once neutrons were irradiated at 30 MeV and 10 μA for 500 sec, the critical current density was observed to increase significantly. When neutrons are irradiated to a superconductor, micro-defects are created in the superconductor, and they act as flux pinning centers that hold the magnetic field generated when an electric current flows.

Reduction Method based on Sub-domain Structure using Reduced Pseudo Inverse Method (축소 의사역행렬과 영역분할 기반 축소모델 구축 기법 연구)

  • Kim, Hyun-Gi;Cho, Meang-Hyo
    • Proceedings of the Computational Structural Engineering Institute Conference
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    • 2009.04a
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    • pp.139-145
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    • 2009
  • Reduction scheme is remarkably useful in the case requiring the repeated calculation procedure. Recently, the efficiency of the reduction scheme has been improved by combining scheme of sub-domain method. But, when the global domain is partitioned into a few sub-domains, sub-domains without constraints can be produced. it is needed to extract the ritz vector from each sub-domain to construct the reduced system of each sub-domain. it is easy to extract the ritz vector from sub-domain with constraint. on the other hand, pseudo inverse method should be employed to extract the ritz vector from sub-domain without constraint. generally, the pseudo inverse takes a large number of computing time to obtain a reduced system of a sub-domain without boundary condition. This trouble can be overcome by the reduced pseudo inverse scheme which proposed in this study. This scheme is based on the static condensation that is not related with selection of the primary degrees of freedom. Numerical examples demonstrate that present method saves computational cost effectively and predicts the accurate eigenvalues.

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Propagation of Endangered Species, Daphne pseudomezereum var. koreana via in vitro Bud Culture (멸종위기종 두메닥나무(Daphne pseudomezereum var. koreana)의 줄기 기내배양을 통한 식물체 생산)

  • Chu, Yerin;Park, Sanghee;Cheong, Eun Ju
    • Journal of Korean Society of Forest Science
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    • v.109 no.2
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    • pp.189-194
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    • 2020
  • Daphne pseudomezereum var. koreana is native to Korea and is distributedin Kangwon-do, Jeollabuk do, and Gyeongsang-do. This economically valuable species has experienced a dramatic decrease in natural habitat due to climate change and is difficult to cultivate. In this study, we investigate a mass propagation method for D. pseudomezereum through in vitro culture and genetic resource preservation.WPM medium was better than the MS medium for shoot growth. As a result, we compared the shoot number and length of apical (W/AP) and non-apical shoots (W0/AP) with BA and GA3 treatments in WPM medium. Their shoots and length grew well in both BA 8ìM + GA38ìM-treated apical shoot and without-apical shoot. NAA did not effectively induce rooting of the in vitro plantlet.

Characteristics of Liquid-Liquid Direct Contact Heat Exchanger for a Solar System (태양열 이용을 위한 직접접촉식 액-액 열교환기 특성)

  • 강인석;김종보;강용혁;곽희열
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.18 no.12
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    • pp.3276-3286
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    • 1994
  • In most direct contact liquid-liquid heat exchangers, oil or hydrocarbon with a density less than water is normally used as dispersed working fluid. The main difficulty that arises with this arrangement lies in the control of the interface at the top of the column. When it is connected with a solar collector which uses water as its working fluid, the main difficulties arise from the fact that the water can be frozen during winter time. In order to solve these problems and to demonstrate the technical feasibility of a direct contact liquid-liquid heat exchanger, liquids heavier than water with low freezing temperature has been utilized as dispersed phase liquids in a small laboratory scale model made of pyrex glass. In the present investigation, dimethyl phthalate(C/sub 6/H/sub 4/)COOCH/sub 3/)/sub 2/) and diethyl phthalate (C/sub 6/H/sub 4/(CO/sub 2/C/sub 2/H/sub 5/)/sub 2/) are utilized as heavy dispersed phase working fluids. The results of the present investigation the technical in the utilization of heavier dispersed working liquid in the spray-column liquid-liquid heat exchanger for a solar system. The overall average temperature difference along the column is found to be almost half of the initial temperature difference between the dispersed and the continuous phase. Despite the fact that the two phthalates tested in the experiment differ significantly in some of their physical properties, the volumetric heat transfer coefficients in terms of dispersed fluid superficial velocities were found to be similar for both phthalates tested.

Effects of Bentonite Illitization on Cesium Sorption (벤토나이트의 일라이트화에 의한 세슘 수착 특성 변화 연구)

  • Hwang, Jeonghwan;Choung, Sungwook;Han, Weon Shik;Yoon, Wonwoo
    • Journal of Soil and Groundwater Environment
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    • v.26 no.5
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    • pp.29-38
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    • 2021
  • This study investigated the mineralogical properties of bentonite and illite and evaluated the Cs sorption at various concentrations (Cw≈1-105 ㎍/L). Bentonite samples, collected from South Korea and USA, majorly consisted of Ca- and Na-montmorillonite, showed large cation exchange capacity (CEC, 91.4 and 47.3 meq/100 g) and specific surface area (SSA, 46.1 and 39.7 m2/g). In contrast, illite sample (USA) had relatively low values for 14.4 meq/100g of CEC and 29.3 m2/g of SSA, respectively. Bentonite and illite had different non-linear sorption for Cs along with Cw. At low Cw<10 ㎍/L, illite showed higher sorption capacity than bentonite despite low CEC because of the existence of specific sorption sites at the weathered mineral edge. However, as Cw increased, bentonite represented high sorption capacity because the cation exchange between Cs and interlayer cations was effective at high Cw conditions. These results implicated that the Cs concentration is important to evaluate the sorption performance of bentonite and illite. Finally, the Cuadros' kinetic model for illitization using various K concentrations (2×10-5 and 1.7×10-3 mol/L) and temperature (100-200℃) showed that up to 50% of the montmorillonite in bentonite could be converted to illite, suggesting that the illitization should be considered to evaluate the sorption performance of the bentonite in deep geological disposal repository.

Review of the Silicon Oxide and Polysilicon Layer as the Passivated Contacts for TOPCon Solar Cells

  • Mengmeng Chu;Muhammad Quddamah Khokhar;Hasnain Yousuf;Xinyi Fan;Seungyong Han;Youngkuk Kim;Suresh Kumar Dhungel;Junsin Yi
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.36 no.3
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    • pp.233-240
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    • 2023
  • p-type Tunnel Oxide Passivating Contacts (TOPCon) solar cell is fabricated with a poly-Si/SiOx structure. It simultaneously achieves surface passivation and enhances the carriers' selective collection, which is a promising technology for conventional solar cells. The quality of passivation is depended on the quality of the tunnel oxide layer at the interface with the c-Si wafer, which is affected by the bond of SiO formed during the subsequent annealing process. The highest cell efficiency reported to date for the laboratory scale has increased to 26.1%, fabricated by the Institute for Solar Energy Research. The cells used a p-type float zone silicon with an interdigitated back contact (IBC) structure that fabricates poly-Si and SiOx layer achieves the highest implied open-circuit voltage (iVoc) is 750 mV, and the highest level of edge passivation is 40%. This review presents an overview of p-type TOPCon technologies, including the ultra-thin silicon oxide layer (SiOx) and poly-silicon layer (poly-Si), as well as the advancement of the SiOx and poly-Si layers. Subsequently, the limitations of improving efficiency are discussed in detail. Consequently, it is expected to provide a basis for the simplification of industrial mass production.

A Development of Resource Planning System for Footwear Manufacturing (운동화 생산을 위한 자원관리 시스템 개발)

  • 류영근;조남호
    • Journal of Korean Society of Industrial and Systems Engineering
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    • v.23 no.57
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    • pp.93-102
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    • 2000
  • The objective of this paper is to introduce to development of resource planning system of footwear manufacturing. The system development is to be done separately by module and each of which makes interface possible. And the final goal of the system development is to combine those modules to be ERP system covering all works from order to make, shipment, accounting. First, in this case study, introduce analysis of existing business flow and design of standard business process for development of systems. Second, describe in and out of the standard business process for shoes production and information management. Third, basic structure and design of the total system flow, configuration of completed 6 sub-systems of developing total 13 sub-system are presented. Fourth, function of software modules and principal algorithm and basic data structuring techniques o the 6 sub-systems are explained. Finally, hereafter implementation and development plans are presented.

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Electrocatalytic properties of Nd1.5Ba1.5CoFeMnOx for water splitting (수전해용 Nd1.5Ba1.5CoFeMnOx 전기촉매 특성 분석)

  • Lee, Ho Jun;Cho, Kyungwon;Ryu, Jeong Ho
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.30 no.1
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    • pp.17-20
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    • 2020
  • Developing effective and earth-abundant electrocatalyst for oxygen evolution reaction (OER) and hydrogen evolution reaction (HER) is critical for the commercialization of a water splitting system. In particular, the overpotential of the OER is relatively higher than the HER, and thus, it is considered that one of the important methods to enhance the performance of the electrocatalyst is to reduce the overpotential of the OER. In this work, we present a simple synthetic route for triple perovskite Nd1.5Ba1.5CoFeMnOx with high performance OER and HER activity. This triple perovskite structure which shows high crystallinity through combustion method shows superior bifunctional catalytic performance in alkaline media. We believe that the prepared triple provskite with high performance OER and HER activity can give further feasibility for the commercialization of a water splitting system.

Scavenging Efficiency Based on Long-Term Characteristics of Precipitation and Particulate Matters in Seoul, Korea (서울지역 장기간 강수와 미세먼지의 특성 분석에 기반한 미세먼지 세정효과)

  • Suji Han;Junshik Um
    • Atmosphere
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    • v.33 no.4
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    • pp.367-385
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    • 2023
  • The variabilities of precipitation and particulate matters (i.e., PM10 and PM2.5) and the scavenging efficiency of PMs by precipitation were quantified using long-term measurements in Seoul, Korea. The 21 years (2001~2021) measurements of precipitation and PM10 mass concentrations, and the 7 years (2015~2021) of PM2.5 mass concentrations were used. Statistical analysis was performed for each period (i.e., year, season, and month) to identify the long-term variabilities of PMs and precipitation. PM10 and PM2.5 decreased annually and the decreasing rate of PM10 was greater than PM2.5. The precipitation intensity did not show notable variation, whereas the annual precipitation amount showed a decreasing trend. The summer precipitation amount contributed 61.10% to the annual precipitation amount. The scavenging efficiency by precipitation was analyzed based on precipitation events separated by 2-hour time intervals between hourly precipitation data for 7 years. The scavenging efficiencies of PM10 and PM2.5 were quantified as a function of precipitation characteristics (i.e., precipitation intensity, amount, and duration). The calculated average scavenging efficiency of PM10 (PM2.5) was 39.59% (35.51%). PM10 and PM2.5 were not always simultaneously scavenged due to precipitation events. Precipitation events that simultaneously scavenged PM10 and PM2.5 contributed 42.24% of all events, with average scavenging efficiency of 42.93% and 43.39%. The precipitation characteristics (i.e., precipitation intensity, precipitation amount, and precipitation duration) quantified in these events were 2.42 mm hr-1, 15.44 mm, and 5.51 hours. This result corresponds to 145% (349%; 224%) of precipitation intensity (amount; duration) for the precipitation events that do not simultaneously scavenge PM10 and PM2.5.