• Polymer(Korea)
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• v.32 no.5
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• pp.446-457
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• 2008

Three kinds of hydroxypropyl cellulose (HPC) derivatives: 6- (cholesteryloxycarbonyl) pentoxypropyl celluloses(CHPCs) with degree of esterification(DE) ranging from 0.6 to 3, 6-[4-{4'-(nitrophenylazo)phenoxycarbonyl}] pentoxypropyl celluloses (NHPCs) with DE ranging from 0.4 to 3, and fully 6-(cholesteryloxycarbonyl) pentanoated NHPCs (CNHPCs) were synthesized, and their thermotropic liquid crystalline properties were investigated. All the CHPCs and NHPCs with $DE{\leq}1.7$ formed enantiotropic cholesteric phases, whereas CNHPCs with 6-(cholesteryloxycarbonyl) pentanoyl DE(DEC) more than 1.6 exhibited monotropic cholesteric phases. On the other hand, NHPCs with $DE{\geq}2.4$ and CNHPCs with $DEC{\leq}1.3$ showed monotropic nematic phases. NHPCs with $DE{\leq}l$, as well as HPC, formed right-handed helices whose optical pitches (${{\lambda}_m}'s$) increase with temperature, while all the CHPCs formed left-handed helices whose ${{\lambda}_m}'s$ decrease with temperature. In contrast with these derivatives, NHPCs with $1.4{\leq}DE{\leq}1.7$ and CNHPCs with $DEC{\geq}1.6$ did not display reflection colors over the full cholesteric range, suggesting that the helical twisting power of the cellulose chain and the cholesteryl group highly depends on the chemical structure and DE of mesogenic group.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.41 no.5
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• pp.533-541
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• 2021

Retaining walls have been used to prevent slope failure through resistance of earth pressure in railway, road, nuclear power plant, dam, and river infrastructure. To calculate dynamic earth pressure and determine the characteristics for seismic behavior, many researchers have analyzed the nonlinear response of ground and structure based on various numerical analyses (FLAC, PLAXIS, ABAQUS etc). In addition, seismic fragility evaluation is performed to ensure safety against earthquakes for structures. In this study, we used the FLAC2D program to understand the seismic response of the inverted T-type wall with a backfill slope, and evaluated seismic fragility based on relative horizontal displacements of the wall. Nonlinear site response analysis was performed for each site (S2 and S4) using the seven ground motions to calculate various seismic loadings reflecting site characteristics. The numerical model was validated based on other numerical models, experiment results, and generalized formula for dynamic active earth pressure. We also determined the damage state and damage index based on the height of retaining wall, and developed the seismic fragility curves. The damage probabilities of the retaining wall for the S4 site were computed to be larger than those for the S2 site.

• Applied Chemistry for Engineering
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• v.32 no.5
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• pp.509-515
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• 2021

In this study, poly lactic-co-glycolic acid (PLGA) nanoparticles (PNP) were prepared through double (w/o/w) emlusion and emulsifying solvent-evaporation technique using PLGA, which has biocompatibility and biodegradability. To maximize stability and bioavailability of the particles, chitosan-coated PLGA nanoparticles (CPNP) were prepared by charge interaction between PNP and chitosan. We demonstrated that CPNP can be utilized as a drug carrier of oral administration. The chemical structure of CPNP was analyzed by ¹H-NMR and FT-IR, and all characteristic peaks appeared, confirming that it was successfully prepared. In addition, particle size and zeta potential of CPNP were analyzed using dynamic light scattering (DLS) while morphological images were obtained using transmission electron microscope (TEM). Thermal decomposition behavior of CPNP was observed through thermogravimetric analysis (TGA). In addition, the cytotoxicity of CPNP was confirmed by MTT assay at HEK293 and L929 cell lines, and it was proved that there is no toxicity confirmed by the cell viability of above 70% at all concentrations. These results suggest that the CPNP developed in this study may be used as an oral drug delivery carrier.

• Journal of the Korean Applied Science and Technology
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• v.38 no.4
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• pp.1003-1009
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• 2021

A study on the associative properties of sodium hyaluronate (NaHA) and Alkane-bis (dimethylalkylammonium bromide) surfactants in aqueous solution was investigated in relation to the chemical structure of surfactants. As a result of measuring the interfacial tension, a parabolic graph showing the minimum value (c_min) at a specific concentration was shown. Above this minimum concentration the increase in interfacial tension is thought to be related to the formation of aggregates of NaHA chains and dimeric surfactants. The plot of viscosity vs surfactant concentration shows a slight maxium at c_min and a viscosity decrease at high surfactant concentrations. Viscosity nonlinear behavior is related to the size increase due to the complex growth and to the size shrinkage following from the interaction with electrolyte ions and free micelles. The results of surface tension measurements show a broad region of surface tension decrease, indicating the NaHA-surfactant interaction. The increase in surface tension above c_min may be related to the adsorption of clusters, consisting of free NaHA chains and dimeric surfactant. The strong adsorption of surfactant is observed at high concentrations.

• Journal of the Korea institute for structural maintenance and inspection
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• v.25 no.4
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• pp.83-91
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• 2021

In this study, to improve the connection performance between the existing reinforced concrete (R/C) frame and the strengthening member, we proposed a new H-section steel frame with elastic pad (HSFEP) system for seismic rehabilitation of existing medium-to-low-rise reinforced concrete (R/C) buildings. This HSFEP strengthening system exhibits an excellent connection performance because an elastic pad is installed between the existing structure and reinforcing frame. The method shows a strength design approach implemented via retrofitting, to easily increase the ultimate lateral load capacity of R/C buildings lacking seismic data, which exhibit shear failure mechanism. Two full-size two-story R/C frame specimens were designed based on an existing R/C building in Korea lacking seismic data, and then strengthened using the HSFEP system; thus, one control specimen and one specimen strengthened with the HSFEP system were used. Pseudodynamic tests were conducted to verify the effects of seismic retrofitting, and the earthquake response behavior with use of the proposed method, in terms of the maximum response strength, response displacement, and degree of earthquake damage compared with the control R/C frame. Test results revealed that the proposed HSFEP strengthening method, internally applied to the R/C frame, effectively increased the lateral ultimate strength, resulting in reduced response displacement of R/C structures under large scale earthquake conditions.

• Journal of the Korea institute for structural maintenance and inspection
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• v.25 no.4
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• pp.28-36
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• 2021

It is known that buried rebars inside concrete structures are protected from corrosion due to passive layer. It is very important to delay the timing of corrosion or evaluate a detection of corrosion initiation for the purpose of cost-beneficiary service life of a structure. In this study, corrosion monitoring was performed on concrete specimens considering 3 levels of cover depth(60 mm, 45 mm, and 30 mm), W/C(water to cement) ratio(40.0%, 50.0%, and 60.0%) and chloride concentration(0.0%, 3.5%, and 7.0%). OCP(Open Circuit Potential) was measured using agar-based socket type sensors. The OCP measurement showed the consistent behavior where the potential was reduced in wet conditions and it was partially recovered in dry conditions. In the case of 30 mm of cover depth for most W/C ratio cases, the lowest OCP value was measured and rapid OCP recovery was evaluated in increasing cover depth from 30 mm to 45 mm, since cover depth was an effective protection against chloride ion ingress. As the chloride concentration increased, the effect on the cover depth tended to be more dominant than the that of W/C ratio. After additional monitoring and physical evaluation of chloride concentration after specimen dismantling, the proposed system can be improved with increasing reliability of the corrosion monitoring.

• Journal of the Korean Society for Aeronautical & Space Sciences
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• v.47 no.7
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• pp.489-498
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• 2019

The airloads and structural loads of Light Civil Helicopter (LCH) rotor are investigated using a loose CFD/CSD coupling. The structural dynamics model for LCH 5-bladed rotor cwith elastomeric bearing and inter-bladed damper is constructed using CAMRAD-II. Either isolated rotor or rotor-fuselage model is used to identify the effect of the fuselage on the aeromechanics behavior at a cruise speed of 0.28. The fuselage effect is shown to be marginal on the aeromechanics predictions of LCH rotor, though the effect can be non-negligible for the tail structure due to the prevailing root vortices strengthened by the fuselage upwash. A lifting-line based comprehensive analysis is also conducted to verify the CFD/CSD coupled analysis. The comparison study shows that the comprehensive analysis predictions are generally in good agreements with CFD/CSD coupled results. However, the predicted comprehensive analysis results underestimate peak-to-peak values of blade section airloads and elastic motions due to the limitation of unsteady aerodynamic predictions. Particularly, significant discrepancies appear in the structural loads with apparent phase differences.

• Journal of the Korea institute for structural maintenance and inspection
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• v.23 no.3
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• pp.143-149
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• 2019

In this study, a U-shape composite beam was developed to be effectively used for a steel parking lot which is 8m or lower in height. When the U-shape composite beam was applied to a steel parking lot, essential considerations were story-height and long-span. In addition, due to the mixed structural system with reinforced concrete and steel material, the U-shape composite beam needed to have a structural integrity and reliable performance over demand capacity. The main objective of this study was to investigate the performance of the structure consisting of the reinforced concrete (RC) slab and U-shape beam. A U-shape composite beam generally used at a parking lot served as a control specimen. Four specimens were tested under four-point bending. To calculate theoretical values, strain gauges were attached to rebar, steel plate, and concrete surface in the middle of the specimens. As the results, initial yielding strength of the control specimen occurred at the bottom of the U-shaped steel. After yielding, the specimen reached the maximum strength and the RC slab concrete was finally failed by concrete crush due to compressive stress. The structural performance such as flexural strength and ductility of the specimen with the increased beam depth was significantly improved in comparison with the control specimen. Furthermore, the design of the U-shape composite beam with the consideration of flexural strength and ductility was effective since the structural performance by a negative loading was relatively decreased but the ductile behavior was evidently improved.

• Korean Journal of Ichthyology
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• v.31 no.2
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• pp.67-76
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• 2019

This study was conducted from 2017 to 2018 to determine habitat aspects of Acheilognathus signifier, an endangered species reintroduced (2010~2012) to Heukcheon Stream, a tributary of the Hangang River, Korea. A total of 329 individuals were collected in 2017 (two surveys) and 723 individuals were collected in 2018 (four surveys) at about 5 km habitat area, including the discharge station. A. signifier's habitat was about 0.4 to 1.2 meters deep in slow water flow upstream of the discharge area. It was a place with many boulders and cobbles. The spawning period was estimated from April to June in terms of spawning behavior and collected juvenile size. Sex ratio of females (438) and males (412) was 1 : 0.94. Estimated age of A. signifier based on their total length distribution during the spawning period (April) indicated that 1-, 2-, 3-year old groups and more than 4-year-old group were 32~43 mm, 50~61 mm, 62~75 mm, and 76~89 mm, respectively. Age-specific composition costs differed depending on the timing of the collection. They were relatively high in the order of first-year (juvenile)>third-year> and fourth-year or higher, showing a stable age structure. Thus, A. signifier reintroduced to Heukcheon Stream has successfully settled down and formed a stable population, showing a tendency to proliferate.

• Korean Journal of Heritage: History & Science
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• v.36
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• pp.267-297
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• 2003

The plain coarse pottery from the Unjeonri Bronze Age relic sites in the Cheonan, Korea were studied on the basis of clay mineralogy, geochemistry and archaegeological interpretations. For the research, the potteries are utilized at the analysis for 6 pieces of plain coarse potteries. Color of the these potteries are mainly light brown, partly shows the yellowish brown to reddish brown. The interior, surface and inside of the pottery appear as different colors in any cases. Original source materials making the Unjeonri potteries are used of mainly sandy clay soil with extreme coarse grained irregularly quartz and feldspar. The magnetic susceptibility of the Unjeonri pottery range from 0.20 to 1.20. And the Unjeonri soil's magnetic susceptibility agree almost with 0.20 to 1.30. In the same magnetization of soil and pottery, the results revealed that the Unjeonri soil and low material of pottery are same produced by identical source materials. The Unjeonri potteries and soil are very similar patterns with all characteristics of soil mineralogy, geochemical evolution trend. The result seems to be same relationships between the behavior and enrichment patterns on the basis of a compatible and a incompatible elements. Consequently, the Unjeonri potteries suggest that made the soil to be distributed in the circumstance of the relic sites as the raw material are high in a greater part. In the Unjeonri soil, the kaolinite is common occurred minerals. However, in the Unjeonri pottery, the kaolinite was not detected in all broken pieces. The kaolinite was presumed to destroy crystal structure during the firing processes of over $550^{\circ}C$. The quartz is phase transition from ${\alpha}$-quartz to ${\beta}$-quartz at $573^{\circ}C$, but the Unjeonri pottery did not investigated any phase transition evidences of quartz. The chorite was detected within the mostly potteries and soils. As the results, the Unjeonri potteries can be interpreted by not experiencing a firing temperature over $800^{\circ}C$. The colloidal and cementing materials between the quartz and low materials during the heating did not exist in the internal part of the potteries. An any secondary compounds by heating does not appear within the crack to happen during the dry of the pottery. The hyphae group are kept as it is with the root tissue of an organic matters to live in the swampy land. In the syntheses of all results, the general firing condition to bake and make the Unjeonri pottery is presumed from $550^{\circ}C$ to $800^{\circ}C$. However, the firing condition making the Unjeonri pottery can be different firing temperature partially in one pottery. Even, the some part of the pottery does not take a direct influence on the fire.