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http://dx.doi.org/10.12925/jkocs.2021.38.4.1003

A Study on the Aggregation properties of Sodium hyaluronate with Alkanediyl-bis(dimethylalkylammonium bromide) surfactants in aqueous solution  

Ahn, Beom-Shu (Division of Life Science & Chemistry, Daejin University)
Publication Information
Journal of the Korean Applied Science and Technology / v.38, no.4, 2021 , pp. 1003-1009 More about this Journal
Abstract
A study on the associative properties of sodium hyaluronate (NaHA) and Alkane-bis (dimethylalkylammonium bromide) surfactants in aqueous solution was investigated in relation to the chemical structure of surfactants. As a result of measuring the interfacial tension, a parabolic graph showing the minimum value (cmin) at a specific concentration was shown. Above this minimum concentration the increase in interfacial tension is thought to be related to the formation of aggregates of NaHA chains and dimeric surfactants. The plot of viscosity vs surfactant concentration shows a slight maxium at cmin and a viscosity decrease at high surfactant concentrations. Viscosity nonlinear behavior is related to the size increase due to the complex growth and to the size shrinkage following from the interaction with electrolyte ions and free micelles. The results of surface tension measurements show a broad region of surface tension decrease, indicating the NaHA-surfactant interaction. The increase in surface tension above cmin may be related to the adsorption of clusters, consisting of free NaHA chains and dimeric surfactant. The strong adsorption of surfactant is observed at high concentrations.
Keywords
sodium hyaluronate; dimeric surfactant; surface tention; viscosity; interface; polymeric surfactant complex;
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Times Cited By KSCI : 3  (Citation Analysis)
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