• Title/Summary/Keyword: Structural modification

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Preparation of Silica/collagen Microsphere Composit Doped with Silver Nanoparticles (은 나노입자를 담지한 collagen/silica microsphere 복합체의 제조)

  • Jung, Hyo Jung;Kim, Yeon Bum;Chang, Yoon Ho
    • Korean Chemical Engineering Research
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    • v.46 no.4
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    • pp.722-726
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    • 2008
  • Silica microsphere is a world leading innovative material used in adsorbent packing materials in HPLC technology. The application of microsphere lies in the ability to the surface modification of silica with the special materials such as polymers, metals and bio-active materials. Collagen is a major structural protein of connective tissues and has a good biocompatibility. In this study, we prepared the purified silica porous microsphere, having micro diameters in the range of a pore volume at least 50% by the aggregation procedure of colloidal silica with the polymerization method (PICA). The microspheres were modified by collagen hydrogel to improve the biocompatible properties for biomedical product. The silica/collagen microsphere composite doped with silver nanoparticles was prepared and investigated the capabilities of biomaterial application through the evaluation of the structure characteristics of the microsphere composit.

Requirements Analysis in ID-based Future Internet (식별자 기반 미래 인터넷에서의 요구사항 분석)

  • Kwak, Byeong-Ok;Lee, Sang-Ho
    • Journal of Convergence Society for SMB
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    • v.6 no.3
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    • pp.43-48
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    • 2016
  • Current address-based Internet has started to expose the number of limitations, with the growth of the Internet. Most of the problems have been solved by adding new features to the Internet or some modification of existing features but some problems can not be solved because it is believed that the structural limitations of the Internet. Overcoming to fundamentally the limitations of the Internet, ID-based Future Internet research is under active research going on in the competitive atmosphere of the United States and Europe. However, most studies have been promoted in a specific field is concentrated in a limited area. For the future Internet, there is a need to derive the requirements to overcome the limitation and accommodate the features and advantages of the existing studies. This paper compares and analyzes the characteristics and advantages and disadvantages for the ID-based Future Internet Research, and describes the requirements to have the ID-based Future Internet.

NO Gas Sensing of ACFs Treated by E-beam Irradiation in H2O2 Solution (과산화수소 용액에 담지 된 활성탄소섬유의 전자선 조사에 따른 일산화질소 가스 감응)

  • LEE, SANGMIN;PARK, MI-SEON;JUNG, MIN-JUNG;LEE, YOUNG-SEAK
    • Journal of Hydrogen and New Energy
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    • v.27 no.3
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    • pp.298-305
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    • 2016
  • In this study, we treated pitch-based activated carbon fibers (ACFs) in hydrogen peroxide using electron beam (E-beam) irradiation to improve nitrogen monoxide (NO) sensing ability as an electrode material of gas sensor. The specific surface area of ACFs treated by E-beam irradiation with 400 kGy increased from $885m^2/g$ (pristine) to $1160m^2/g$ without any changes in structural property and functional group. The increase in specific surface area of the E-beam irradiated ACFs enhanced NO gas sensing properties such as response time and sensitivity. When the ACFs irradiated with 400 kGy, response time was remarkably reduced from 360 s to 210 s and sensitivity was increased by 4.5%, compared to the pristine ACFs. These results demonstrate convincingly that surface modification of ACFs using E-beam in hydrogen peroxide solution can enhance textural properties of ACFs and NO gas sensing ability of gas sensor at room temperature.

A Study on the Optimum Design of Three Span Continuous Preflex Composite Girder Bridge (3경간 연속 Preflex 합성형교의 최적설계에 관한 연구)

  • Koo, Min Se;Chang, Suong Su;Jeong, Jin Il
    • Journal of Korean Society of Steel Construction
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    • v.10 no.1 s.34
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    • pp.125-135
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    • 1998
  • This study presents a design method for three-span continuous preflex composite girder bridges (3S-PCB) which imposes prestresses in the negative moment region by lifting or lowering interior supports and the design method is automated by a computer program which incorporates optimal design procedure. The objective function for the design of 3S-PCB minimizes the cost of construction materials and the constraint functions represent the limited dimensions of the design section and the allowable stress for each structural member as given in the specifications. Optimal design procedure used in this study is a modification of existing sequential unconstrained minimization technique (SUMT), a numerical analyses procedure for two-span continuous preflex composite bridges. The optimized design sections determined for each span length are compared with those of simple preflex composite beams (SPCB) and the optimal girder depth is determined by defining the relationship between girder depth and construction material costs.

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Evolution the surface morphology and mechanical properties of Polyimide induced by Ion Beam Irradiation

  • Ahmed, Sk. Faruque;Nho, Gun-Ho;Moon, Myoung-Woon;Han, Jun-Hyun;Lee, Kwang-Ryeol
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.02a
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    • pp.98-98
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    • 2010
  • Ion beam irradiation has been extensively used for surface modification of polymers, glassy metals and amorphous and crystalline materials at micron and submicron scales. The surface structures created by exposure to an ion beam range from dots, steps and one-dimensional straight wrinkles to highly complex hierarchical undulations and ripples. In general, the morphology of these nanoscale features can be selected by controlling the ion beam parameters (e.g. fluence and acceleration voltage), making ion beam irradiation a promising method for the surface engineering of materials. In the work, we presented that ion beam irradiation results in creation of a peculiar nanoscale dimple-like structure on the surface of polyimide - a common polymer in electronics, large scale structures, automobile industry, and biomedical applications. The role of broad Ar ion beam on the morphology of the structural features was investigated and insights into the mechanisms of formation of these nanoscale features were provided. Moreover, a systematic experimental study was performed to quantify the role of ion beam treatment time, and thus the morphology, on the coefficient of friction of polyimide surfaces covered by nanostructure using a tribo-experiment. Nano-indentation experiment were performed on the ion beam treated surfaces which shows that the hardness as well as the elastic modulus of the polyimide surface increased with increase of Ar ion beam treatment time. The increased of hardness of polyimide have been explained in terms of surface structure as well as morphology changes induced by Ar ion beam treatment.

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Pressure Drop and Vibration Characteristics of the Capsule with the Modification of Bottom Structures (캡슐 하단부 구조변경에 따른 압력강하 및 진동특성)

  • Choi, M.H.;Choo, K.N.;Cho, M.S.;Lee, K.H.;Kim, B.G.
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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    • 2005.11a
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    • pp.782-787
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    • 2005
  • The bottom structure of an instrumented capsule is a part which is joined at the receptacle of the flow tube in the reactor in-core. A geometrical change or the bottom structure has an effect on the pressure drop and the vibration of the capsule. The out-pile test to evaluate the structural Integrity of the material capsule called 04M-l7U was performed by using a single channel and a half core test loop. From the pressure drop test, the optimized diameter of the cone shape's bottom structure which satisfies HANARO's flow requirement (19 6 kg/s) is 71 mm. The maximum displacement of the capsule measured at the half core test loop is lower than 1.0 mm. From the analysis results, it is found that the test hole will not be interfered with near the flow tubes because its displacement due to the cooling water is very small at 0.072 mm. The fundamental frequency of the capsule under water is 9.64 Hz. It is expected that the resonance between the capsule and the fluid flow due to the cooling water in HANARO's In-core will not occur. Also, the new bottom structure of a solid cone shape with 71 mm in diameter will be applicable to the material and special capsules in the future.

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Development and Evaluation of Non-Hydrous Skin Analogue Liquid Crystal using Thermo-Sensitivity Smart Sensor

  • Yoo, Kwang-Ho;Hong, Jae-Hwa;Eun, So-Hee;Jeong, Tae-Hwa;Jeong, Kwan-Young
    • Journal of the Korean Applied Science and Technology
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    • v.31 no.3
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    • pp.367-374
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    • 2014
  • In this study, skin permeation enhancement was confirmed by designing it to have a structure and composition similarity to the intercellular lipids that improve miscibility with skin by cross-linked lipids poloxamer. The cross-linked lipids poloxamer was synthesized and analyzed by 1H NMR that structure dose had conjugated pluronic with ceramide3. Active component is released by modification of liquid crystal structure because PPO part, large-scale molecule block of pluronic, has hydrophobic nature at skin temperature of $35^{\circ}C$. Conjugated pluronic with ceramide3 was synthesized using Pluronic F127 and p-NPC (4-nitrophenyl chloroformate) at room temperature yielded 89%. Pluronic(Ceramide 3-conjugated Pluronic) was synthesized by reaction of p-NP-Pluronic with Ceramide3 and DMAP. The yield was 51%. This cross-linked lipids poloxamer was blended and dissolved at isotropic state with skin surface lipids, phospholipid, ceramide, cholesterol and anhydrous additive solvent. Next step was preceded by ${\alpha}$-Transition at low temperature for making the structure of Meso-Phase Lamella, and non-hydrous skin analogue liquid crystal using thermo-sensitivity smart sensor, lamellar liquid crystal structure through aging time. For confirmation of conjugation thermo-sensitivity smart sensor and non-hydrous skin analogue liquid crystal, structural observation and stability test were performed using XRD(Xray Diffraction), DSC(Differential Scanning Calorimetry), PM (Polarized Microscope) And C-SEM (Cryo-Scanning Electron Microscope). Thermo-sensitivity observation by Franz cell revealed that synthesized smart sensor shown skin permeation effect over 75% than normal liquid crystal. Furthermore, normal non-hydrous skin analogue liquid crystal that not applied smart sensor shown similar results below $35^{\circ}C$ of skin temperature, but its effects has increased more than 30% above $35^{\circ}C$.

POWER UPRATES IN NUCLEAR POWER PLANTS: INTERNATIONAL EXPERIENCES AND APPROACHES FOR IMPLEMENTATION

  • Kang, Ki-Sig
    • Nuclear Engineering and Technology
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    • v.40 no.4
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    • pp.255-268
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    • 2008
  • The greater demand for electricity and the available capacity within safety margins in some operating NPPs are prompting nuclear utilities to request license modification to enable operation at a higher power level, beyond their original license provisions. Such plant modifications require an in-depth safety analysis to evaluate the possible safety impact. The analysis must consider the thermo hydraulic, radiological and structural aspects, and the plant behavior, while taking into account the capability of the structures, systems and components, and the reactor protection and safeguard systems set points. The purpose of this paper is to introduce international experiences and approaches for implementation of power uprates related to the reactor thermal power of nuclear power plants. The paper is intended to give the reader a general overview of the major processes, work products, issues, challenges, events, and experiences in the power uprates program. The process of increasing the licensed power level of a nuclear power plants is called a power uprate. One way of increasing the thermal output from a reactor is to increase the amount of fissile material in use. It is also possible to increase the core power by increasing the performance of the high power bundles. Safety margins can be maintained by either using fuels with a higher performance, or through the use of improved methods of analysis to demonstrate that the required margins are retained even at the higher power levels. The paper will review all types of power uprates, from small to large, and across various reactor types, including light and heavy water, pressurized, and boiling water reactors. Generally, however, the content of the report focuses on power uprates of the stretch and extended type. The International Atomic Energy Agency (IAEA) is developing a technical guideline on power uprates and side effects of power uprates in nuclear power plants.

Anti-inflammatory effect of Distylium racemosum leaf biorenovate extract in LPS-stimulated RAW 264.7 macrophages cells (LPS로 유도된 RAW 264.7 세포에 대한 조록나무 잎 Biorenovation 추출물의 항염증 활성)

  • Hong, Hyehyun;Lee, Kyung-Mi;Park, Taejin;Chi, Won-Jae;Kim, Seung-Young
    • Journal of Applied Biological Chemistry
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    • v.64 no.4
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    • pp.375-382
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    • 2021
  • Biorenovation is a microbial enzyme-based structural modification of component compounds in natural products and synthetic compounds including plant extracts with the potential benefits of improved biological activities compared with its reaction substrates. In this study, we investigated the anti-inflammatory activity of Distylium racemosum leaf extract and D. racemosum leaf biorenovation extract (DLB). As a result, DLB inhibited nitric oxide, prostaglandin E2, and inflammatory cytokines including tumor necrosis factor-α, interleukin-6, interleukin-1β at non-toxic concentrations. In addition, DLB significantly inhibited inducible nitric oxide synthase and cyclooxygenase-2 on LPS-treated RAW 264.7 macrophages. Based on these results, we suggest that the DLB could be used as a potent anti-inflammatory agents. It also suggests that the application of biological evolution has potential usefulness to increase the practical value of natural products.

An Experimental Study on the Deflection Estimation of RC Flexural Member by Corrosion of Reinforcement (철근 부식에 따른 철근콘크리트 휨 부재의 처짐 산정에 대한 실험적 연구)

  • Kim, Jee-Sang;Moon, Hyeong-Gab
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.9 no.2
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    • pp.143-151
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    • 2021
  • Flexural test of reinforced concrete beam with corroded reinforcement were performed to measure the deflection, curvature and cracking moment for various bar diameter and amounts of corrosion. The amounts of corrosion are varied from 0% to 10% by weight and the bar diameters are chosen as 10mm, 13mm, and 19mm. The changes in reinforcement diameter do not affect the flexural behaviors significantly according to this experiment. If the amounts of corrosion is greater than 2%, the deflection and curvature of the beam increased and the cracking moment decreased. It means that the lower amounts of corrosion does not result structural damage in flexural member significantly as in direct tensile test. A modification factor considering an effect of amounts of corrosion is proposed based on the experiment, which can be used to determine the deflection of reinforced concrete beam with corroded reinforcement.