• Bulletin of the Korean Chemical Society
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• v.18 no.11
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• pp.1166-1172
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• 1997

[FeⅢ(BLPA)DBC]BPh4, a new functional model for the catechol dioxygenases, has been synthesized, where BLPA is bis((6-methyl-2-pyridyl)methyl)(2-pyridylmethyl)amine and DBC is 3,5-di-tert-butylcatecholate dianion. The BLPA complex has a structural feature that iron center has a six-coordinate geometry with N4O2 donor set. It exhibits EPR signals at g=5.5 and 8.0 which are typical values for the high-spin FeⅢ (S=5/2) complex with axial symmetry. The BLPA complex reacts with O2 within a few hours to afford intradiol cleavage (75%) and extradiol cleavage (15%) products which is very unique result of all [Fe(L)DBC] complexes studied. The iron-catecholate interaction of BLPA complex is significantly stronger, resulting in the enhanced covalency of the metal-catecholate bonds and low energy catecholate to FeⅢ charge transfer bands at 583 and 962 nm in CH3CN. The enhanced covalency is also reflected by the isotropic shifts exhibited by the DBC protons, which indicate increased semiquinone character. The greater semiquinone character in the BLPA complex correlates well with its high reactivity towards O2. Kinetic studies of the reaction of the BLPA complex with 1 atm O2 in CH3OH and CH2Cl2 under pseudo-first order conditions show that the BLPA complex reacts with O2 much slower than the TPA complex, where TPA is tris(2-pyridylmethyl)amine. It is presumably due to the steric effect of the methyl substituent on the pyridine ring. Nevertheless, both the high specificity and the fast kinetics can be rationalized on the basis of its low energy catecholate to FeⅢ charge transfer bands and large isotropic NMR shifts for the BLPA protons. These results provide insight into the nature of the oxygenation mechanism of the catechol dioxygenases.

• Earthquakes and Structures
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• v.17 no.2
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• pp.143-162
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• 2019

Motivated by a simpler and more compact hybrid active tuned mass damper (ATMD) system with wide frequency spacing (i.e., high robustness) but not reducing the effectiveness using the least number of ATMD units, the active tuned tandem mass dampers (ATTMD) have been proposed to attenuate undesirable oscillations of structures under the ground acceleration. Likewise, it is expected that the frequency spacing of the ATTMD is comparable to that of the active multiple tuned mass dampers (AMTMD) or the multiple tuned mass dampers (MTMD). In accordance with the mode generalised system in the specific vibration mode being controlled (simply referred herein to as the structure), the closed-form expression of the dimensionless displacement variances has been derived for the structure with the attached ATTMD. The criterion for the optimum searching may then be determined as minimization of the dimensionless displacement variances. Employing the gradient-based optimization technique, the effects of varying key parameters on the performance of the ATTMD have been scrutinized in order to probe into its superiority. Meanwhile, for the purpose of a systematic comparison, the optimum results of two active tuned mass dampers (two ATMDs), two tuned mass dampers (two TMDs) without the linking damper, and the TTMD are included into consideration. Subsequent to work in the frequency domain, a real-time Simulink implementation of dynamic analysis of the structure with the ATTMD under earthquakes is carried out to verify the findings of effectiveness and stroke in the frequency domain. Results clearly show that the findings in the time domain support the ones in the frequency domain. The whole work demonstrates that ATTMD outperforms two ATMDs, two TMDs, and TTMD. Thereinto, a wide frequency spacing feature of the ATTMD is its highlight, thus deeming it a high robustness control device. Furthermore, the ATTMD system only needs the linking dashpot, thus embodying its simplicity.

• Korean Journal of Heritage: History & Science
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• v.35
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• pp.236-282
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• 2002

Among elements of play, there are puppets performances and shadows performance which are replacing actors by puppets and shadows. Puppet performance is characteristic of expressing various movements and symbols at its conveniences by the reduced models of human form with various materials. Shadow performance is realized in various colors that cannot be discovered in other countries by expressing mysterious cubic effect in reflecting the light against various forms. Mansukjung Nolum is a unique shadow performance that has been inherited in Korea. There are found many shadow performances inherited in the northern Europe and South-eastern Asia. Recently the silhouette animation in application of shadow performance is made. In the northern Europe and South-eastern Asia, they performed in white and black color while Mansukjung Nolum is performed in natural colors. Since they adopted the leather materials for making puppets, their opaque feature cannot reflect the colored light. But in Korea we adopted the specially colored semi-transparent Korean paper, which gives the colored shadows to spectators. Mansukjung Nolum consists of three acts for arousing attention of fallen monks destroying the teaching of Buddha. Seosanbakchumji Nolum is a puppet performance inherited in a village in Seosan, Choongnam instead of wandering artists. The story and form of performance in Namsadangpae's puppet play is mostly similar to it, but it is woven by its villages natural environment and specific dialects, reflecting their consciousness in mind. The villagers made the puppets and manipulate them in communicating their wisdom of life between them. Parkchumji Nolum is a kind of integral art combining puppet manipulation, witticism, songs and dances. The hero of Parkchumji discloses the social and structural conflicts of feudalism, in arousing the spectators' rich attention of self-awareness and lessons.

• Journal of Microbiology and Biotechnology
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• v.29 no.3
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• pp.367-372
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• 2019

Deactivation of aminoglycosides by their modifying enzymes, including a number of aminoglycoside O-phosphotransferases, is the most ubiquitous resistance mechanism in aminoglycoside-resistant pathogens. Nonetheless, in a couple of biosynthetic pathways for gentamicins, fortimicins, and istamycins, phosphorylation of aminoglycosides seems to be a unique and initial step for the creation of a natural defensive structural feature such as a 3',4'-dideoxy scaffold. Our aim was to elucidate the biochemical details on the beginning of these C3',4'-dideoxygenation biosynthetic steps for aminoglycosides. The biosynthesis of istamycins must surely involve these 3',4'-didehydroxylation steps, but much less has been reported in terms of characterization of istamycin biosynthetic genes, especially about the phosphotransferase-encoding gene. In the disruption and complementation experiments pointing to a putative gene, istP, in the genome of wild-type Streptomyces tenjimariensis, the function of the istP gene was proved here to be a phosphotransferase. Next, an in-frame deletion of a known phosphotransferase-encoding gene forP from the genome of wild-type Micromonospora olivasterospora resulted in the appearance of a hitherto unidentified fortimicin shunt product, namely 3-O-methyl-FOR-KK1, whereas complementation of forP restored the natural fortimicin metabolite profiles. The bilateral complementation of an istP gene (or forP) in the ${\Delta}forP$ mutant (or ${\Delta}istP$ mutant strain) successfully restored the biosynthesis of 3',4'-dideoxy fortimicins and istamycins, thus clearly indicating that they are interchangeable launchers of the biosynthesis of 3',4'-dideoxy types of 1,4-diaminocyclitol antibiotics.

• Journal of Broadcast Engineering
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• v.24 no.2
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• pp.315-328
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• 2019

Image steganalysis is an algorithm that classifies input images into stego images with steganography methods and cover images without steganography methods. Previously, handcrafted feature-based steganalysis methods have been mainly studied. However, CNN-based objects recognition has achieved great successes and CNN-based steganalysis is actively studied recently. Unlike object recognition, CNN-based steganalysis requires preprocessing filters to discriminate the subtle difference between cover images from stego images. Therefore, CNN-based steganalysis studies have focused on developing effective preprocessing filters as well as network structures. In this paper, we compare previous studies in same experimental conditions, and based on the results, we analy ze the performance variation caused by the differences in preprocessing filter and network structure.

• Journal of the Korean Society for Aeronautical & Space Sciences
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• v.49 no.7
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• pp.539-547
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• 2021

Helicopter rotor blade is required to be designed by considering the interacting effects among aerodynamics, flexibility, and controllability. The reverse design allows the structural components to have common characteristics by using the configuration numerics and experimental results. This paper aims to design the composite rotor blade which will feature common characteristics with that of BO-105. The present engineering design procedure is done by dividing the rotor blade into a few sections and composite laminates across the cross section. For each section, variational asymptotic beam sectional analysis (VABS) program is used to evaluate its flapwise, lagwise, and torsion stiffnesses to have discrepancy smaller than certain tolerance. Finally, CAMRAD II is used to predict the stress acting on the rotor blade during the specific flight condition and to check whether the present deign is structurally valid.

• KSII Transactions on Internet and Information Systems (TIIS)
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• v.16 no.10
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• pp.3313-3332
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• 2022

This study is an investigation into the factors affecting patient dissatisfaction among Saudi hospitals. The selected factors considered for analysis are security of information sharing, operational practices, disruptive technologies, and the ease of use of EHR patient information management systems. From the literature review section, it was clear that hardly any other studies have embraced these concepts in one as was intended by this study. The theories that the study heavily draws from are the service dominant logic and the feature integration theory. The study surveyed 350 respondents from three large major hospitals in three different metropolitan cities in the Kingdom of Saudi Arabia. This sample came from members of the three hospitals that were willing to participate in the study. The number 350 represents those that successfully completed the online questionnaire or the limited physical questionnaires in time. The study employed the structural equation modelling technique to analyze the associations. Findings suggested that security of information sharing had a significant direct effect on patient satisfaction. Operational practice positively mediated the effect of security of information sharing on patient dissatisfaction. However, ease of use failed to significant impact this association. The study concluded that to improve patient satisfaction, Saudi hospitals must work on their systems to reinforce them against the active threats on the privacy of patients' data by leveraging disruptive technology. They should also improve their operational practices by embracing quality management techniques relevant to the healthcare sector.

• Progress in Medical Physics
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• v.32 no.4
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• pp.92-98
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• 2021

Purpose: This study automatically discriminates homogeneous and structure edge regions on computed tomography (CT) images, and it evaluates the noise level and edge preservation ratio (EPR) according to the different types of iterative reconstruction (IR). Methods: The dataset consisted of CT scans of 10 patients reconstructed with filtered back projection (FBP), statistical IR (iDose⁴), and iterative model-based reconstruction (IMR). Using the 10th and 85th percentiles of the structure coherence feature, homogeneous and structure edge regions were localized. The noise level was estimated using the averages of the standard deviations for five regions of interests (ROIs), and the EPR was calculated as the ratio of standard deviations between homogeneous and structural edge regions on subtraction CT between the FBP and IR. Results: The noise levels were 20.86±1.77 Hounsfield unit (HU), 13.50±1.14 HU, and 7.70±0.46 HU for FBP, iDose⁴, and IMR, respectively, which indicates that iDose⁴ and IMR could achieve noise reductions of approximately 35.17% and 62.97%, respectively. The EPR had values of 1.14±0.48 and 1.22±0.51 for iDose⁴ and IMR, respectively. Conclusions: The iDose⁴ and IMR algorithms can effectively reduce noise levels while maintaining the anatomical structure. This study suggested automated evaluation measurements of noise levels and EPRs, which are important aspects in CT image quality with patients' cases of FBP, iDose⁴, and IMR. We expect that the inclusion of other important image quality indices with a greater number of patients' cases will enable the establishment of integrated platforms for monitoring both CT image quality and radiation dose.

• International Journal of Computer Science & Network Security
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• v.21 no.7
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• pp.35-42
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• 2021

In the article, the authors investigate the economic security system in the conditions of the powers transformation. It is substantiated that economic security acts as a certain system that includes components and at the same time acts as a subsystem of the highest order. It is determined that the economic security system of regions acting as a system has its subsystems, which include: production, financial, environmental, innovation, investment and social subsystems. The parameters of the economic security system include relative economic independence, economic stability and self-development of economic systems, and it is proved that an important feature of economic security in addition to its systemic nature is multi-vector. It is substantiated that the monitoring of ensuring the economic security system of the development of economic systems of different levels in the conditions of the powers transformation should contain the analysis of social, economic and ecological development of regions; spheres of possible dangers of the development of regional economic systems; the nature of the threats; the degree of the possibility of threats; time perspective of economic development threats; possible consequences of losses for economic entities; the impact of threats to the object of the economic entities' activity; possible asymmetry of economic development of regional economic entities. Possible threats as a consequence of the powers transformation have been identified. A PEST analysis of the impact of factors of different nature on economic security and the development of regional economic systems in the powers transformation is carried out. A recurrent ratio is proposed for the economic security system in the conditions of the powers transformation.

• KSII Transactions on Internet and Information Systems (TIIS)
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• v.15 no.11
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• pp.4065-4083
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• 2021

Super-resolution can improve the clarity of low-resolution (LR) images, which can increase the accuracy of high-level compute vision tasks. Portable devices have low computing power and storage performance. Large-scale neural network super-resolution methods are not suitable for portable devices. In order to save the computational cost and the number of parameters, Lightweight image processing method can improve the processing speed of portable devices. Therefore, we propose the Enhanced Information Multiple Distillation Network (EIMDN) to adapt lower delay and cost. The EIMDN takes feedback mechanism as the framework and obtains low level features through high level features. Further, we replace the feature extraction convolution operation in Information Multiple Distillation Block (IMDB), with Ghost module, and propose the Enhanced Information Multiple Distillation Block (EIMDB) to reduce the amount of calculation and the number of parameters. Finally, coordinate attention (CA) is used at the end of IMDB and EIMDB to enhance the important information extraction from Spaces and channels. Experimental results show that our proposed can achieve convergence faster with fewer parameters and computation, compared with other lightweight super-resolution methods. Under the condition of higher peak signal-to-noise ratio (PSNR) and higher structural similarity (SSIM), the performance of network reconstruction image texture and target contour is significantly improved.