• Title/Summary/Keyword: Structural effect

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Effect of Al2O3 Inter-Layer Grown on FeCrAl Alloy Foam to Improve the Dispersion and Stability of NiO Catalysts (NiO 촉매의 분산성 및 안정성 향상을 위하여 FeCrAl 합금 폼 위에 성장된 Al2O3 Inter-Layer 효과)

  • Lee, Yu-Jin;Koo, Bon-Ryul;Baek, Seong-Ho;Park, Man-Ho;Ahn, Hyo-Jin
    • Korean Journal of Materials Research
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    • v.25 no.8
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    • pp.391-397
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    • 2015
  • NiO catalysts/$Al_2O_3$/FeCrAl alloy foam for hydrogen production was prepared using atomic layer deposition (ALD) and subsequent dip-coating methods. FeCrAl alloy foam and $Al_2O_3$ inter-layer were used as catalyst supports. To improve the dispersion and stability of NiO catalysts, an $Al_2O_3$ inter-layer was introduced and their thickness was systematically controlled to 0, 20, 50 and 80 nm using an ALD technique. The structural, chemical bonding and morphological properties (including dispersion) of the NiO catalysts/$Al_2O_3$/FeCrAl alloy foam were characterized by X-ray diffraction, X-ray photoelectron spectroscopy, field-emission scanning electron microscopy and scanning electron microscopy-energy dispersive spectroscopy. In particular, to evaluate the stability of the NiO catalysts grown on $Al_2O_3$/FeCrAl alloy foam, chronoamperometry tests were performed and then the ingredient amounts of electrolytes were analyzed via inductively coupled plasma spectrometer. We found that the introduction of $Al_2O_3$ inter-layer improved the dispersion and stability of the NiO catalysts on the supports. Thus, when an $Al_2O_3$ inter-layer with a 80 nm thickness was grown between the FeCrAl alloy foam and the NiO catalysts, it indicated improved dispersion and stability of the NiO catalysts compared to the other samples. The performance improvement can be explained by optimum thickness of $Al_2O_3$ inter-layer resulting from the role of a passivation layer.

The Effects of work and psychosocial stress on job satisfaction, organizational commitment, and leaving intention in general hospital female office workers (종합병원 사무직 여성의 직무 및 사회심리적 스트레스가 직무만족, 조직몰입, 이직의향에 미치는 영향)

  • Lee, Jeong-Hyun;Cho, Woo-Hyun;Chang, Sei-Jin;Kim, Young-Hoon
    • Korea Journal of Hospital Management
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    • v.17 no.1
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    • pp.1-22
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    • 2012
  • This study tires to examine affects that job and socio-psychological stresses of female office workers influence job satisfaction, organization commitment, and leaving intentions. A complete data are collected by conducting a survey with 240 female office workers from 9 medical institutions regarded as almost general hospital in Seoul. It is analyzed that the relation between socio-psychological stress and job satisfaction, organization commitment, and leaving intentions by using t-test; analysis of variance; correlation analysis; principal component analysis; linear structural equation modeling; etc. The results of this study are summarized as following. First, as it was comprehended by specific characteristics of subjects that the female office workers' level of job and socio-psychological stress, job satisfaction, organizational commitment, and leaving intention, there were statistically significant distinctions from their age, marital status, presence of children, position in the organization, type of employment, and monthly average income. Second, this study regarded relationship between the female office workers' level of job and socio-psychological stresses, job satisfaction, organizational commitment, and leaving intention. Job and socio-psychological stresses were negatively correlated with job satisfaction and organizational commitment, but the stresses were positive with leaving intention. Third, after evaluating effect that 8 features related to the job stress could influence job stress, the most effective valuables were in order to unfairness in organizational structure, workplace culture, inadequate compensation, and relationship conflict. Fourth, when looking at the overall effects of the job and sociopsychological stresses on job satisfaction, organizational commitment, and leaving intention, work autonomy was the most influencing factor of work stress levels. The level of the job stress seemed to be a prevalent impact on the leaving intention and it showed the most negative relationship that path coefficient from leaving intention to organizational commitment and also from organizational commitment to job satisfaction. Based on these findings, it can be defined that the job and socio-psychological stresses strongly influence job satisfaction, organizational commitment, and leaving intention.

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Seismic Performance of Reinforced Concrete Shear Wall Buildings with Piloti (필로티를 갖는 철근콘크리트 전단벽식 건물의 내진성능)

  • Kwon Young-Wung;Kim Min-Su
    • Journal of the Korea Concrete Institute
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    • v.17 no.4 s.88
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    • pp.587-594
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    • 2005
  • The purpose of seismic design is to ensure the serviceability of buildings against earthquake, which might be occurred during the service life of buildings, and to minimize the loss of life by preventing their failure under strong earthquake. The lack resistance of walls resulting from a tendency toward high-rise apartment buildings with shear walls and use of piloti would lead to a concentration of inelastic behaviors in their weak story. In this study, the seismic performance of reinforced concrete shear wall buildings haying piloti was analyzed by using the evaluation techniques which was proposed by FEMA 273 and ATC-40. The results from comparison with these two techniques are summarized as follows.; The results of elastic analysis method for seismic performance evaluation show that the effect of piloti and building height decrease performance index. In case of shear wall building, the state of insufficient shear stress governs their overall performance and it becomes evident in the case of the buildings with more than 25 stories. For the buildings of piloti, the change of mass, weak story, as well as insufficient shear stress, decrease the performance index rapidly compared with the performance index of the buildings without piloti. The results, obtained from the nonlinear static analysis using capacity spectrum method, indicate that the performance Point increases for the structure having Piloti and high story. Also, deformation limits of buildings satisfy the allowable criteria at the life safety level, but the immediate occupancy level is exceeded in buildings which have more than 25 stories.

Seismic structural demands and inelastic deformation ratios: Sensitivity analysis and simplified models

  • Chikh, Benazouz;Laouami, Nacer;Mebarki, Ahmed;Leblouba, Moussa;Mehani, Youcef;Kibboua, Abderrahmane;Hadid, Mohamed;Benouar, Djillali
    • Earthquakes and Structures
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    • v.13 no.1
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    • pp.59-66
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    • 2017
  • Modern seismic codes rely on performance-based seismic design methodology which requires that the structures withstand inelastic deformation. Many studies have focused on the inelastic deformation ratio evaluation (ratio between the inelastic and elastic maximum lateral displacement demands) for various inelastic spectra. This paper investigates the inelastic response spectra through the ductility demand ${\mu}$, the yield strength reduction factor $R_y$, and the inelastic deformation ratio. They depend on the vibration period T, the post-to-preyield stiffness ratio ${\alpha}$, the peak ground acceleration (PGA), and the normalized yield strength coefficient ${\eta}$ (ratio of yield strength coefficient divided by the PGA). A new inelastic deformation ratio $C_{\eta}$ is defined; it is related to the capacity curve (pushover curve) through the coefficient (${\eta}$) and the ratio (${\alpha}$) that are used as control parameters. A set of 140 real ground motions is selected. The structures are bilinear inelastic single degree of freedom systems (SDOF). The sensitivity of the resulting inelastic deformation ratio mean values is discussed for different levels of normalized yield strength coefficient. The influence of vibration period T, post-to-preyield stiffness ratio ${\alpha}$, normalized yield strength coefficient ${\eta}$, earthquake magnitude, ruptures distance (i.e., to fault rupture) and site conditions is also investigated. A regression analysis leads to simplified expressions of this inelastic deformation ratio. These simplified equations estimate the inelastic deformation ratio for structures, which is a key parameter for design or evaluation. The results show that, for a given level of normalized yield strength coefficient, these inelastic displacement ratios become non sensitive to none of the rupture distance, the earthquake magnitude or the site class. Furthermore, they show that the post-to-preyield stiffness has a negligible effect on the inelastic deformation ratio if the normalized yield strength coefficient is greater than unity.

Study of the effect of vacuum annealing on sputtered SnxOy thin films by SnO/Sn composite target (SnO/Sn 혼합 타겟으로 스퍼터 증착된 SnO 박막의 열처리 효과)

  • Kim, Cheol;Cho, Seungbum;Kim, Sungdong;Kim, Sarah Eunkyung
    • Journal of the Microelectronics and Packaging Society
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    • v.24 no.2
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    • pp.43-48
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    • 2017
  • Conductive $Sn_xO_y$ thin films were fabricated via RF reactive sputtering using SnO:Sn (80:20 mol%) composite target. The composite target was used to produce a chemically stable composition of $Sn_xO_y$ thin film while controlling structural defects by chemical reaction between tin and oxygen. During sputtering pressure, RF power, and substrate temperature were fixed, and oxygen partial pressure was varied from 0% to 12%. Annealing process was carried out at $300^{\circ}C$ for 1 hour in vacuum. Except $P_{O2}=0%$ sample, all samples showed the transmittance of 80~90% and amorphous phase before and after annealing. Electrically stable p-type $Sn_xO_y$ thin film with high transmittance was only obtained from the oxygen partial pressure at 12%. The carrier concentration and mobility for the $P_{O2}=12%$ were $6.36{\times}10^{18}cm^{-3}$ and $1.02cm^2V^{-1}s^{-1}$ respectively after annealing.

The Effect of Oral Health Index and Dental Prosthesis Needs on Oral Health Related Quality of Life in Korean Elderly (한국 노인의 구강보건지수와 치과보철물 필요도가 구강건강관련 삶의 질에 미치는 영향)

  • Lee, Hee-Sung;Kim, Han-Gon
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.17 no.1
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    • pp.72-78
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    • 2016
  • This study examined the oral health-related quality of life of the elderly using the oral health index and dental prosthesis status, and explored methods to improve the oral health status. The data collected from 'The fifth Korean national health and nutrition examination survey 2010' were analyzed. The subjects were 2273 elderly people, aged 65 years or older, who had completed an oral examination, health questionnaires and nutrition examination. Statistical analysis was done using the SPSS 22.0 for Windows. Frequency analysis, multiple regression analysis and structural equation model were used for statistical analysis. The general characteristics, oral health index and dental prosthesis showed differences in the subjective oral health status associated with as age, ST, FS-T, T-Health, maxillary crown needs, maxillary denture needs, mandibular denture needs, chewing status associated with the income level, FS-T, maxillary crown needs, maxillary denture needs, mandibular denture needs, speaking status associated with the ST, T-Health, maxillary implant status, and maxillary denture needs. In conclusion, both the oral health index and dental prosthesis needs affect the oral health related quality of life of the elderly. Governments should implement a variety of oral health programs and dental prosthesis policies to improve the quality of life related oral health of the elderly.

A Case Study on the Blasting Analysis of Slope Using Monitored Vibration Waveform (실측진동파형을 이용한 비탈면 발파진동 해석 사례)

  • Park, Do-Hyun;Cho, Young-Gon;Jeon, Seok-Won
    • Explosives and Blasting
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    • v.24 no.2
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    • pp.41-50
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    • 2006
  • Excavation by explosives blasting necessarily involves noise and vibration, which is highly prone to face claims on the environmental and structural aspects from the neighbors. When the blasting carried out in the vicinity of a structure, the effect of blasting vibration on the stability of the structure should be carefully evaluated. In the conventional method of evaluation, an equation for blast vibration is obtained from test blasting which is later used to determine the amount of charge. This method, however, has limitations in use since it does not consider topography and change in ground conditions. In order to overcome the limitations, dynamic numerical analysis is recently used in continuum or discontinuous models, where the topography and the ground conditions can be exactly implemented. In the numerical analysis for tunnels and rock slopes, it is very uncommon to simulate multi-hole blasting. A single-hole blasting pressure is estimated and the equivalent overall pressure at the excavation face is used. This approach based on an ideal case usually does not consider the ground conditions. And this consequently results in errors in calculation. In this presentation of a case study, a new approach of using blast waves obtained in the test blast is proposed. The approach was carried out in order to improve the accuracy in calculating blasting pressure. The stability of a structure in the vicinity of a slope blasting was examined using the newly proposed method.

Structural and photoelectrical properties of copper phthalocyanine(CuPc) thin film on Si substrate by thermal evaporation (Si 기판위에 열증착법으로 제조한 copper phthalocyanine(CuPc) 박막의 구조 및 광전특성)

  • Lee, Hea-Yeon;Jeong, Jung-Hyun;Lee, Jong-Kyu
    • Journal of Sensor Science and Technology
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    • v.6 no.5
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    • pp.407-413
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    • 1997
  • The crystallized CuPc(copper phthalocyanine) film on a p-type <100> Si substrate is prepared at the substrate temperature of $300^{\circ}C$ by thermal evaporation. X -ray diffraction analysis showed the CuPc film to have a-axis oriented structure. For the measurement of photovoltaic characteristics of the CuPc/Si film and the Si substrate, a transverse current-voltage (I-V) curve is observed. In the dark, the Au/Si junction is shown to be ohmic contact. However, under illumination, a photovoltaic effect is not observed. The I-V curve in the dark indicates that the CuPc film on Si may form an ohmic contact. Since the CuPc film is a p-type semiconductor, the CuPc/p-Si junction has no barrier at the interface. Under illumination, the CuPc/Si junction shows a large photocurrent comparing with that of the wafer. The result indicates that the CuPc layer plays an important role in the photocarrier generation under red illumination (600 nm). The CuPc/Si film shows the photo voltaic characteristics with a short-circuit photocurrent ($J_{sc}$) of $4.29\;mA/cm^{2}$ and an open-circuit voltage ($V_{oc}$) of 12 mA.

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Effects of Consumer Tendencies and Positive Emotion on Impulse Buying Behavior for Apparel (의류제품 충동구매행동에 대한 소비자성향과 긍정적 감정 영향)

  • Park, Eun-Joo;Kim, Eun-Young
    • Journal of the Korean Society of Clothing and Textiles
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    • v.32 no.6
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    • pp.980-990
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    • 2008
  • This study tested how impulse buying behavior for apparel was related to hedonic consumption and impulse buying tendencies and emotion in the context of shopping. A total of 290 self-administered questionnaires were obtained from college students during scheduled classes. A structural equation model using a correlation matrix with maximum likelihood was estimated for examining the relationships among consumer tendencies of hedonic consumption and impulse buying, positive emotion, and impulse buying behaviors by LISREL 8.53. Findings showed that impulse buying behaviors for apparel could be classified into planned, reminded, and fashion-oriented impulse buying typologies. Hedonic consumption and impulse buying tendencies had significant effects on positive emotion. Positive emotion had a significant effect on planned, reminded, and fashion-oriented impulse buying for apparel. This study suggests that positive emotion plays an important role in determining impulse buying behaviors relevant to hedonic and impulse buying tendencies. Managerial implications for apparel retailers are discussed.

Purification and Properties of ${\beta}-Mannanases$ from Germinated Guar Bean (${\beta}-Mannanase$ 군(群)의 정제(精製) 및 그들의 성질(性質)에 관(關)한 연구(硏究))

  • Lee, Su-Rae
    • Applied Biological Chemistry
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    • v.7
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    • pp.1-13
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    • 1966
  • 1) Three ${\beta}-1$, 4-mannanases were isolated from germinated guar bean through extraction, ammonium sulfate fractionation, column chromatography on cellulose derivatives and gel filltration on Sephadex G-100. They were designated as ${\beta}-1$, 4-mannanase A,B and C, respectively, in the order of isolation. 2) These enzymes were different in several aspects such as pH optimum, effect of metal ions, adsorbability on cellulose derivatives, molecular weight, Michaelis constant toward reduced ivory nut mannan A, mode of action and extent of hydrolysis of the mannan. 3) ${\beta}-1$, 4-Mannanases A and C were proposed to be two different endo-enzymes of random-splitting type producing a series of oligosaccharides from ${\beta}-1$, 4-mannans. ${\beta}-1$, 4-Mannanase B was suggested to be possibly an exe-type enzyme catalyzing a stepwise splitting from the non-reducing end of ${\beta}-1$, 4-mannans to produce mannose. 4) Guaran was subjected to hydrolysis by the purified enzymes and the consequence was discussed in connection with structural requirements of the enzymes toward substituted ${\beta}-1$, 4-mannans and their role in germinating guar seeds.

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