• Title/Summary/Keyword: Structural Weight

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Ultrasonic Velocity and Absorption Measurements for Polyacrylamide and Water Solutions

  • Bae, Jong-Rim;Kim, Jeong-Koo;Yi, Meyung-Ha
    • The Journal of the Acoustical Society of Korea
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    • v.22 no.4E
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    • pp.155-160
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    • 2003
  • Both ultrasonic velocity at 3 MHz and absorption coefficient for the frequency range of 0.2-2 MHz were measured in an aqueous solution of polyacrylamide for the concentration range of 0.5% to 2.5% by weight. Pulse echo overlap method was taken for measuring the ultrasonic velocity over the temperature range of 10-90℃ and the high-Q ultrasonic resonator method was used for the absorption coefficient at 30℃. The velocity exhibited a maximum value at approximately 70℃, 71℃, 72℃, 73℃ and 74℃ in 2.5%, 2.0%, 1.5%, 1.0%, and 0.5% solutions, respectively. The velocity increased with the concentration at a given temperature. The ultrasonic absorption (a/f²) at a given temperature increased linearly with the concentration for the concentration below 1.5%, but suddenly increased for the concentration above 1.5% concentration. The value of a/f² at 1MHz was entirely due to the classical Stoke's viscous effect. The ultrasonic relaxation in polyacrylamide aqueous solutions, which may be the result of structural fluctuations of polymer molecules such as the segmental motion of the polymer chains, was observed, and at 2.5%, the value of a/f² was found to suddenly increase as frequency decreased.

The Composition of the Rare Earth Based Conversion Coating Formed on AZ91D Magnesium Alloy

  • Chang, Menglei;Wu, Jianfeng;Chen, Dongchu;Ye, Shulin
    • Corrosion Science and Technology
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    • v.17 no.1
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    • pp.1-5
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    • 2018
  • As structural materials, magnesium (Mg) alloys have been widely used in the fields of aviation, automobiles, optical instruments, and electronic products. There are few studies on the effect of coating conditions on the compositional variation during the formation process of the conversion coatings. Rare-earth based conversion coating on AZ91 magnesium alloy was prepared in ceric sulfate and hydrogen peroxide contained solution. The element composition and valence as well as their distribution in the coating were analyzed with energy dispersive X-ray spectroscopy (EDS), Electron probe micro-analyzer (EPMA), X-ray photoelectron spectroscopy (XPS). The effect of treating process on the element composition were also studied. It was found that the conversion coating surface consists of Mg, Al, O, Ce, and the weight content of Ce in the coating was affected by the treating solution concentration and immersion time; the Ce element was distributed in the coating non-uniformly and existed in the form of $Ce^{+3}$ and $Ce^{+4}$, while the O element existed in the form of $OH^-$, $O^{2-}$, $H_2O$. Based on microscopic analysis results, the electrochemical deposition mechanism on the micro-anode and micro-cathode in the process of the coating growth was suggested.

Effects of NaCl Concentration and Solution Temperature on the Galvanic Corrosion between CFRP and AA7075T6

  • Hur, S.Y.;Kim, K.T.;Yoo, Y.R.;Kim, Y.S.
    • Corrosion Science and Technology
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    • v.19 no.2
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    • pp.75-81
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    • 2020
  • To reduce structural weight, light metals, including aluminum and magnesium alloys, have been widely used in various industries such as aircraft, transportation and automobiles. Recently, composite materials such as Carbon Fiber Reinforced Plastics (CFRP) and Graphite Epoxy Composite Material (GECM) have also been applied. However, aluminum and its alloys suffer corrosion from various factors, which include aggressive ions, pH, solution temperature and galvanic contact by potential difference. Moreover, carbon fiber in CFRP and GECM is a very efficient cathode, and very noble in the galvanic series. Galvanic contact between carbon fiber composites and metals in electrolytes such as rain or seawater, is highly undesirable. Notwithstanding the potentially dangerous effects of chloride and temperature, there is little research on galvanic corrosion according to chloride concentration and temperature. This work focused on the effects of chloride concentration and solution temperature on AA7075T6. The increased galvanic corrosion between CRFP and AA7075T6 was evaluated by electrochemical experiments, and these effects were elucidated.

Characteristics of Thick Film Gas Sensors Using Nano ZnO:CNT (나노 ZnO:CNT를 이용한 후막 가스센서의 특성연구)

  • Yoon, So-Jin;Yu, Il
    • Korean Journal of Materials Research
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    • v.24 no.8
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    • pp.413-416
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    • 2014
  • The effects of an addition of CNT on the sensing properties of nano ZnO:CNT-based gas sensors were studied for $H_2S$ gas. The nano ZnO sensing materials were grown by a hydrothermal reaction method. The nano ZnO:CNT was prepared by ball-milling method. The weight range of the CNT addition on the ZnO surface was from 0 to 10%. The nano ZnO:CNT gas sensors were fabricated by a screen-printing method on alumina substrates. The structural and morphological properties of the ZnO:CNT sensing materials were investigated by XRD, EDS, and SEM. The XRD patterns revealed that nano ZnO:CNT powders with a wurtzite structure were grown with (1 0 0), (0 0 2), and (1 0 1) dominant peaks. The size of the ZnO was about 210 nm, as confirmed by SEM images. The sensitivity of the nano ZnO:CNT-based sensors was measured for 5 ppm of $H_2S$ gas at room temperature by comparing the resistance in air with that in target gases.

New Bioactive Compounds from Korean Native Mushrooms

  • Kim, Seong-Eun;Hwang, Byung Soon;Song, Ja-Gyeong;Lee, Seung Woong;Lee, In-Kyoung;Yun, Bong-Sik
    • Mycobiology
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    • v.41 no.4
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    • pp.171-176
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    • 2013
  • Mushrooms are ubiquitous in nature and have high nutritional attributes. They have demonstrated diverse biological effects and therefore have been used in treatments of various diseases, including cancer, diabetes, bacterial and viral infections, and ulcer. In particular, polysaccharides, including ${\beta}$-glucan, are considered as the major constituents responsible for the biological activity of mushrooms. Although an overwhelming number of reports have been published on the importance of polysaccharides as immunomodulating agents, not all of the healing properties found in these mushrooms could be fully accounted for. Recently, many research groups have begun investigations on biologically active small-molecular weight compounds in wild mushrooms. In this mini-review, both structural diversity and biological activities of novel bioactive substances from Korean native mushrooms are described.

Structural Effects on the Tensile and Morphological Properties of Zeolite-filled Polypropylene Derivative Composites

  • Jagannath, Jagannath Biswas;Kim, Hyun;Yim, Chai-Suk;Cho, Jungh-Wan;Kim, Geon-Joong;Choe, Soon-Ja;Lee, Dai-Soo
    • Macromolecular Research
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    • v.12 no.5
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    • pp.443-450
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    • 2004
  • We have studied the effects that inorganic zeolite powder have on structurally different copolymer [poly(propylene-co-ethylene)] and terpolymer [poly(propylene-co-ethylene-co-l-butene)] systems and the possibility of preparing suitable porous composite films. The impact strength and yield stress of the composites did not improve upon any further loading of zeolite, but the modulus increased gradually with respect to the filler loading. The experimental modulus of each of the two systems was compared with theoretical models. We performed a morphological study of the filler mixing efficiency and image analysis. The number-, weight-, and z-average air hole diameters were compared with respect to the draw ratio as well as the zeolite loading. The experimental results suggest that these two matrices can provide a new choice for preparing future multiphase polymeric porous films by stretching them unidirectionally. In particular, we suggest that a 40 wt% zeolite loading at a draw ratio of 4 is useful for porous film applications.

TWO-STEP THERMOCHEMICAL CYCLES FOR HYDROGEN PRODUCTION WITH DISH TYPE SOLAR THERMAL SYSTEM (접시형 태양열 집광 시스템을 이용한 열화학 사이클의 수소생산)

  • Kwon, Hae-Sung;Oh, Sang-June;Seo, Tae-Beom
    • 한국태양에너지학회:학술대회논문집
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    • 2011.11a
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    • pp.169-176
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    • 2011
  • The two-step water splitting thermochemical cycle is composed of the T-R (Thermal Reduction)and W-D (Water Decomposition)steps. The mechanism of this cycle is oxidation-reduction, which produces hydrogen. The reaction temperature necessary for this thermochemical cycle can be achieved by a dish-type solar thermal collector (Inha University, Korea). The purpose of this study is to validate a water splitting device in the field. The device is studied and fabricated by Kodama et al (2010, 2011). The validation results show that the foam device, when loaded with $NiFe_2O_4/m-ZrO_2$powder, was successfully achieved hydrogen production with 9 (10 with a Xe-light solar simulator, 2009, Kodama et al.) repeated cycles under field conditions. Two foam device used in this study were tested for validation before an experiment was performed. The lab scale ferrite-conversion rate was in the range of 24~76%. Two foam devices were designed to for structural stability in this study. In the results of the experiments, the hydrogen percentage of the weight of each foam device was 7.194 and $9.954{\mu}mol\;g^{-1}$ onaverage, and the conversion rates 4.49~29.97 and 2.55~58.83%, respectively.

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Structural Characterization of an IgM-like Immunoglobulin in the Serum of Swamp Eel, Monopterus albus (드렁허리(Monopterus albus) 혈청내 lgM유사 면역글로불린의 구조적 특성)

  • 손영종;이정우;장정순
    • The Korean Journal of Zoology
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    • v.33 no.1
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    • pp.103-107
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    • 1990
  • lgM-like immunoglobulin was purified from the immune serum of M albus which immunized with bovine Serum albumin(BSA) as an antigen(Ag) and characterized. The Ag-specific antibody activity of the immune serum was increased after the immunization. The purified lgM-like immunoglobulin had a tetrameric structure which had a molecular weight of 800 kD and the monomer of IgM-like Ig had a mass of 199 kD which was composed of two heavy chains (Mol. wt. 70 kD) and iwo light chains (Mol. wt. 29.5 kD). The IgM-like Ig showed hemaggluti nating activity to mammalian RBC slightly.

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Development of a Closed-die Design with Backpressure to Forge Rotating Scrolls (압축기용 구동스크롤의 밀폐형 배압 금형 개발)

  • Kim, Y.B.;Jung, K.H.;Lee, S.;Kim, E.;Lee, J.;Choi, D.S.;Lee, G.A.
    • Transactions of Materials Processing
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    • v.22 no.4
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    • pp.183-188
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    • 2013
  • Scroll compressors are widely used in air conditioning systems and in automobiles due to their low pressure loss, minimal vibrations, and light-weight. Open-die forging with back pressure is used to forge the rotating scroll, and it requires special care since the forging die can be severely damaged at the fixed end of the spiral cavity similar to a fracture of a cantilever beam. To overcome the inevitable weakness of the forging die due to such damage, an innovative design is necessary. In this study, structural analysis using the finite element method was conducted to determine the reason for the fracture of the forging die. A novel design to avoid stress concentrations and vertical deflection, causing serious damage to the die, is suggested.

Analysis of Strengthening Structures of Steel Manhole Cover (강재 맨홀뚜껑의 보강구조 해석)

  • Kim, Heung-Kyu;Yang, Young-Soo;Bae, Kang-Yul
    • Journal of Welding and Joining
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    • v.32 no.2
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    • pp.54-62
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    • 2014
  • Manhole cover, which is usually made of grey cast iron and consists of frame and cover, should have enough strength to support the heavy traffic load. The manhole cover made of cast iron has heavy weight to handle manually and is vulnerable to impact force with its brittle characteristics. Moreover, its production process of casting has been regulated in terms of environmental pollution. In this study, steel manhole cover is proposed to substitute the cast cover with a series of structural analyses to confirm its strength to support the test load for manhole cover. The cover of the proposed steel manhole cover is made of thin circular pate and stiffeners below the plate. Rectangular columns and hollow circular plate were selected for the shape of the stiffener. In order to give enough strength for the cover to behave within elastic range in the loading, strengthening structures of the cover were varied with increasing the number and the size of the stiffeners. The results of the analyses revealed that when both the hollow circular stiffener and cross stiffeners were additionally applied at the same time to the steel cover with longitudinal stiffeners, the maximum stress level in the cover could be reduced to that level presented in the cast cover.