• The Journal of Advanced Prosthodontics
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• 제1권3호
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• pp.113-117
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• 2009

STATEMENT OF PROBLEM. Recently Yttrium-stabilized tetragonal zirconia polycrystal (Y-TZP) has been introduced due to superior flexural strength and fracture toughness compared to other dental ceramic systems. Although zirconia has outstanding mechanical properties, the phenomenon of decrease in the life-time of zirconia resulted from degradation in flexural strength after low temperature aging has been reported. PURPOSE. The objective of this study was to investigate degradation of flexural strength of Y-TZP ceramics after various low temperature aging treatments and to evaluate the phase stability and micro-structural change after aging by using X-ray diffraction analysis and a scanning electron microscope (SEM). MATERIAL AND METHODS. Y-TZP blocks of Vita In-Ceram YZ (Vita Zahnfabrik, Bad $S\ddot{a}ckingen$, Germany) were prepared in 40 mm (length) $\times$ 4 mm (width) $\times$ 3 mm (height) samples. Specimens were artificially aged in distilled water by heat-treatment at a temperature of 75, 100, 125, 150, 175, 200, and $225^{\circ}C$ for 10 hours, in order to induce the phase transformation at the surface. To measure the mechanical property, the specimens were subjected to a four-point bending test using a universal testing machine (Instron model 3365; Instron, Canton, Mass, USA). In addition, X-ray diffraction analysis (DMAX 2500; Rigaku, Tokyo, Japan) and SEM (Hitachi s4700; Jeol Ltd, Tokyo, Japan) were performed to estimate the phase transformation. The statistical analysis was done using SAS 9.1.3 (SAS institute, USA). The flexural strength data of the experimental groups were analyzed by one-way analysis of variance and to detect statistically significant differences ($\alpha$= .05). RESULTS. The mean flexural strength of sintered Vita In-Ceram YZ without autoclaving was 798 MPa. When applied aging temperature at below $125^{\circ}C$ for 10 hours, the flexural strength of Vita In-Ceram YZ increased up to 1,161 MPa. However, at above $150^{\circ}C$, the flexural strength started to decrease. Although low temperature aging caused the tetragonal-to-monoclinic phase transformation related to temperature, the minimum flexural strength was above 700 MPa. CONCLUSION. The monoclinic phase started to appear after aging treatment above $100^{\circ}C$. With the higher aging temperature, the fraction of monoclinic phase increased. The ratio of monoclinic/tetragonal + monoclinic phase reached a plateau value, circa 75% above $175^{\circ}C$. The point of monoclinic concentration at which the flexural strength begins to decrease was between 12% and 54%.

• Journal of Chest Surgery
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• 제37권2호
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• pp.113-118
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• 2004

혈관재건술에 사용되는 냉동 보존된 동종동맥편에 대한 지금까지의 연구는 주로 냉동방법, 냉동전처치, 보존온도에 관심이 집중되어 있었으나, 최근에 해동방법이 균열발생의 중요한 인자가 된다는 연구가 있었다. 이에 저자들은, 같은 조건으로 냉동 보존된 대동맥조직을 서로 다른 두 가지 방법으로 해동시켜, 조직손상 정도를 비교함으로써 이상적인 조직의 해동방법을 알아보고자 하였다. 대상 및 방법: 2,500 g의 토끼에서 대동맥편을 획득한 후, 일반적인 방법에 따라 냉동 보존한 뒤 37$^{\circ}C$의 온수에 급속 해동한 군(RT)과 1$^{\circ}C$/min의 속도로 완속 해동시킨 군(ST)으로 나누고, 각 군에서 apoptosis 발생을 평가하기 위해 각 군의 전체 세포 중 TUNEL (＋) 세포의 비를 비교하였고, 광학현미경하에서 해동된 조직편의 조직학적 특성을 비교 관찰하였다. 결과: 1. TUNEL test상, RT군에서 ST군에 비해 TUNEL (＋) 세포의 비가 유의하게 높았다. 2. 광학현미경하 조직소견상, RT군에서 세포부종과 혈관내피층의 박탈, 소수포 형성, 그리고 이형성세포 등의 소견이 ST군에 비해 더 많이 관찰되었다. 결론: 냉동 보존된 토끼의 대동맥조직에 대한 해동방법의 차이에서, 완속 해동방법이 조직의 형태학적 손상과 apoptosis발생을 감소시켰다. 따라서, 향후 냉동조직을 이용한 이식술에서 술 후 합병증의 발생을 감소시키고 예후를 개선하기 위해서는 기존의 급속 해동하는 방법보다 완속 해동하는 방법의 사용을 고려해야 할 것이다.

• 한국융합학회논문지
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• 제9권9호
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• pp.309-317
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• 2018

본 연구는 초등학교 체육영재 학생들의 골연령이 체격 및 체력에 어떠한 영향을 주는지를 알아보기 위하여 2012년 부터 2016년까지 총 3년간 초등학교 남녀 체육영재 103명의 종단적 골연령, 체격, 체력변화 자료를 바탕으로 구조방정식모형 검증을 실시하였으며, 다음과 같은 결과를 얻었다. 첫째, 남녀 저학년(1~3학년)의 골연령은 체격변화에 직접적인 영향을 주지만 체력변화에는 영향을 주지 않았다. 둘째, 남자 고학년(4~6학년)의 골연령은 체격변화 및 50m 달리기, 윗몸일으키기에 직접효과를 주었으며, 팔굽혀펴기, 앉아 농구공던지기, 제자리멀리뛰기에 간접효과를 주었다. 셋째, 여자 고학년(4~6학년)의 골연령은 체격변화 및 윗몸일으키기, 사이드스텝에 직접효과를 주었으며, 50m 달리기, 하프스쿼트 점프, 제자리멀리뛰기에 간접효과를 주었다. 그러므로 이상의 결과를 통해 초등학교 4학년 이상 남녀 학생의 골연령 평가는 근기능과 관련된 학생들의 운동 잠재성 평가에 활용될 수 있다는 결론을 도출할 수 있다.

• 터널과지하공간
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• 제24권4호
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• pp.255-274
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• 2014

본 연구는 강원도 강릉시 소재의 ${\bigcirc}{\bigcirc}$ 석회석 광산에서 2012년 8월 23일 오후 7시경 붕괴된 대규모 암반사면을 대상으로 한다. 붕괴 이전에 사면의 높이는 약 200 m이고 평균경사는 $45^{\circ}$로 형성되어 있다. 사면 붕괴 후 추정된 붕괴량은 $1,500,000m^3$ 정도이다. 사면 붕괴의 원인을 분석하기 위하여 시추, 물리탐사, 지표지질조사, 선구조분석, 공내영상촬영, 입체사진영상촬영, 실내시험 및 현장시험, 년도별 채광현황 및 강우량 분석등의 현장 및 지반조사를 실시하였다. 사면의 안정성을 파악하기 위하여 SMR, 평사투영법, 한계평형법, 연속체 및 불연속체 해석을 수행하였다. 이 결과들로부터 사면붕괴의 원인은 지형, 강우, 암종 및 암질, 불연속면, 석회암 공동이나 단층의 지질구조적 특성 등 여러 요인들이 복합적으로 작용하여 사면활동이 발생한 것으로 추정되지만, 석회암 공동을 고려하지 않을 경우 사면 붕괴는 발생하지 않는 것으로 분석되었다. 석회암 공동을 고려한 연속체 해석에서 사면 안전율이 0.66으로 나타났다. 따라서 대규모 사면붕괴의 근본적인 원인은 단층대를 따라 발달하고 있는 석회암 공동의 영향에 기인하는 것으로 판단된다.

• Bulletin of the Korean Chemical Society
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• 제33권1호
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• pp.48-54
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• 2012

The $[Fe_4S_4]^{2+}$ clusters with 2-, 3-, and 4-pyridinemethanethiolate (S2-Pic, S3-Pic, and S4-Pic, respectively) terminal ligands have been synthesized from the ligand substitution reaction of the $(^nBu_4N)_2[Fe_4S_4Cl_4]$ (I) cluster. The new $(^nBu_4N)_2[Fe_4S_4(SR)_4]$ (R = 2-Pic; II, 3-Pic; III, 4-Pic; IV) clusters were characterized by FTIR and UV-Vis spectroscopy. Cluster II was crystallized in the monoclinic space group C2/c with a = 24.530 (5) $\AA$, b = 24.636(4) $\AA$, c = 21.762(4) $\AA$, ${\beta}=103.253(3)^{\circ}$, and Z = 8. The X-ray structure of II showed two unique 2:2 site-differentiated $[Fe_4S_4]^{2+}$ clusters due to the bidentate-mode coordination by 2-pyridinemethanethiolate ligands. Cluster III was crystallized in the same monoclinic space group C2/c with a = 26.0740(18) $\AA$, b = 23.3195(16) $\AA$, c = 22.3720(15) $\AA$, ${\beta}=100.467(2)^{\circ}$, and Z = 8. The 3-pyridinemethanethiolate ligand of III was coordinated to the $[Fe_4S_4]^{2+}$ core as a terminal mode. Cluster IV with 4-pyridinemethanethiolate ligands was found to have a similar structure to the cluster III. Fully reversible $[Fe_4S_4]^{2+}/[Fe_4S_4]^+$ redox waves were observed from all three clusters by cyclic voltammetry measurement. The electrochemical potentials for the $[Fe_4S_4]^{2+}/[Fe_4S_4]^+$ transition decreased in the order of II, III and IV, and the reduction potential changes by the ligands were explained based on the structural differences among the complexes. The complex III was reacted with sulfonium salt of $[PhMeSCH_2-p-C_6H_4CN](BF_4)$ in MeCN to test possible radical-involving reaction as a functional model of the [$Fe_4S_4$]-SAM (S-adenosylmethionine) cofactor. However, the isolated reaction products of 3-pyridinemethanethiolate-p-cyanobenzylsulfide and thioanisole suggested that the reaction followed an ionic mechanism and the products formed from the terminal ligand attack to the sulfonium.

• 유통과학연구
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• 제11권1호
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• pp.45-53
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• 2013

Purpose - The environment-friendly agricultural product market in Korea sees continual high growth. Recently, the Korean government has been actively fostering environment-friendly agriculture as an engine of future growth. Korean people have increasingly become more health-conscious and interested in food safety issues. Many distribution and retailing companies have responded with various promotional activities. However, most of these are not strategic and appear to have unsatisfactory outcomes. The main purpose of this paper is to suggest effective marketing strategies for environment-friendly agricultural products. To achieve this aim, the study empirically investigates the effects of consumer characteristics and trust on the purchase intention of environment-friendly agricultural products. Research design, data, methodology - Based on the theory of planned behavior, and previous studies related to the purchase intention and consumption of environment-friendly agricultural products, we set up five study hypotheses. These related to the demographic characteristics of consumers, purchase intention, and behavior of the products. We then set up a study model and four study hypotheses relating to health consciousness, environmental consciousness, consumer trust level, purchase intention, and behavior of the products. The data were collected using a questionnaire given to consumers living in Seoul and southern Geonggi Province. The final sample size is 403 and mean age is 44.3. SPSS 15.0 for Windows and Amos 7.0 were used as statistical analysis tools. Meaningful results were derived using frequency analysis, correlation analysis, a t-test, and structural equation modeling. Results - Empirical results of this research are as follows. (1) First, it is shown that consumers consider such attributes as intimacy and health to be important when they buy environment-friendly agricultural products. (2) We also found that consumers recognize the value of environment-friendly agricultural products as high, but their trust level as low. (3) Consumer groups consisting of married couples, with higher education, higher income, and higher age are shown to have a higher intention of buying environment-friendly agricultural products than any other consumer group. (4) It is estimated that the level of consumer trust positively affects the purchase intention of environment-friendly agricultural products. The path coefficient (.138) between consumer trust and purchase intention is statistically significant at the α = .05 level. (5). It is also estimated that environmental consciousness positively affects purchase intention. The path coefficient (.245) between environmental consciousness and purchase intention is statistically significant at the α = 0.05 level. The standardized path coefficients of consumer trust and environmental consciousness with purchase intention are .556 and .288 respectively. Therefore, consumer trust affects purchase intention more than environmental consciousness. (6) Finally, purchase intention is estimated to positively affect purchase behavior. Conclusions - Based upon empirical results, this research suggests that marketers of environment-friendly agricultural products should focus more on increasing consumer trust levels, emphasizing the training and education of employees. The government also should pay attention to a standardized certification system for environment-friendly agricultural products. Marketers of environment-friendly agricultural products should consider the consumer groups of married couples, with higher education, higher income, and higher age as a major target segment.

• 한국항공우주학회지
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• 제36권6호
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• pp.541-549
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• 2008

피로해석은 반복하중 하에서의 항공우주 구조물에 대한 구조적 파괴를 예방하기 위해 수행된다. 본 논문에서는 틸트로터형 무인 항공기에 대하여 피로수명에 대한 평가를 하였다. 먼저 틸트로터형 무인항공기의 기동에 맞는 하중 스펙트럼을 생성해 내었으며, F.C.L. 부품중 하나인 플랩퍼론 연결부위에 대하여 피로해석을 수행 하였다. 틸트로터형 무인항공기는 크게 두 가지 기동 형태로 나눌 수 있는데, 이 착륙시의 헬리콥터 형태와 순항시의 고정익 형태가 되겠다. 전체적인 피로하중 스펙트럼을 만들기 위해서 헬리콥터 형태에는 FELIX를, 고정익 형태에서는 TWIST를 사용하였다. 한편으로는, S-N 실험점이 해석에 사용될 때 재료수명의 전 영역에 대한 S-N 회귀식을 얻기 위하여 크리깅 메타 모델이 사용되었다. 그리고 최소 자승법을 이용한 이차 회귀식에 대한 S-N 커브 역시 생성하였다. 더욱이 이 커브들이 갖고 있는 정확도를 측정하기 위하여 결정 계수법을 사용하였다. 마지막으로는 플랩퍼론 연결 부위에 대한 피로수명 결과를 MSC. Fatigue와 비교하였다.

• The Korean Journal of Physiology and Pharmacology
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• 제19권4호
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• pp.309-318
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• 2015

Alcohol consumption increases the risk of type 2 diabetes. However, its effects on prediabetes or early diabetes have not been studied. We investigated endoplasmic reticulum (ER) stress in the pancreas and liver resulting from chronic alcohol consumption in the prediabetes and early stages of diabetes. We separated Otsuka Long-Evans Tokushima Fatty (OLETF) rats, a type-2 diabetic animal model, into two groups based on diabetic stage: prediabetes and early diabetes were defined as occurrence between the ages of 11 to 16 weeks and 17 to 22 weeks, respectively. The experimental group received an ethanol-containing liquid diet for 6 weeks. An intraperitoneal glucose tolerance test was conducted after 16 and 22 weeks for the prediabetic and early diabetes groups, respectively. There were no significant differences in body weight between the control and ethanol groups. Fasting and 120-min glucose levels were lower and higher, respectively, in the ethanol group than in the control group. In prediabetes rats, alcohol induced significant expression of ER stress markers in the pancreas; however, alcohol did not affect the liver. In early diabetes rats, alcohol significantly increased most ER stress-marker levels in both the pancreas and liver. These results indicate that chronic alcohol consumption increased the risk of diabetes in prediabetic and early diabetic OLETF rats; the pancreas was more susceptible to damage than was the liver in the early diabetic stages, and the adaptive and proapoptotic pathway of ER stress may play key roles in the development and progression of diabetes affected by chronic alcohol ingestion.

• 유통과학연구
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• 제14권4호
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• pp.67-79
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• 2016

Purpose - Over recent years, we have concerned about safety and quality on food products because of delivery complexity. The dependence of foreign food products escalate supply of products. And there are often negligent accident of marine and agricultural products. Therefore, the complexity increases the importance of safety on food and information quality for consumers. In spite of the interest augmentation of various interested parties, there is decrease in reliability and effectiveness, if it would be established without the right directivity. For the study, we tried to examine the first considerations the point of - view in service environment and information quality with accepting and diffusing the Traceability System. Then, we tried to verify the relationships between the factors of TS and the determinants of behavior decision. Next, we made efforts to find the mutual relationship among distributors, producers, consumers and the other prerequisite factors from the point of view in service environment and information quality in order to operate effectively the information perspective and system. Research design, data, and methodology - For the purpose of this study, the samples of consumers were targeted to Traceability System, and 661 people have been investigated. Through theoretical discussion of previous research, nine hypotheses were established, the influence of Continuous User Intention in TS. In order to test the hypotheses, a survey had conducted for 661 consumers as opinion leaders in their 20s-60s as data, and structural equation modeling was used. The difference analysis between Agricultural and Marine Products in TS; SPSS 22.0 and AMOS 22.0 were used for statistical analysis. Results - The major findings from this study were as follow; all factors of information quality excluding completeness and a social-impact had effects on the ease of use; all factors excluding understand ability in information quality and a social-impact had effects on the usefulness; completeness and social-impact had effects on perceived value; the ease of use had effects on usefulness and perceived value; usefulness had effects on perceived value and the intention of continuous use. From the results of different analysis, the CPLT(Completeness) factor has positive effects on Easy of USE and PV(Perceived Value) strongly in agricultural products. On the other hand, Social Duty has positive effects on Easy of Use strongly in marine products. Conclusion - In the age of information overflowing, TS will be a burden for users if it places too much emphasis upon accessibility. To accept and diffuse TS safely, therefore, Information System should be settled first into initial market formation. In addition, if TS elements are considered in conjunction with information factors and user environment, the acceptance and diffusion of TS would make synergy effect, even better. That is, this study contributes to the acceptance and diffusion of Traceability System. Accordingly, information quality will be settled into initial market formation. Also, social-impact element will be considered in conjunction with information quality's factors, and it will make synergy effect.

• 유통과학연구
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• 제12권8호
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• pp.17-29
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• 2014

Purpose - The use of corporate social activities to implement the concept of corporate social responsibility enhances brand equity and attitude, and strengthens economic competitiveness. In areas such as mobile communications, companies take the responsibility of protecting customers and enhance the quality of the mobile communication service, helping to make an effort to obey the regulations of the public trade order and fair trade agreement, enabling a healthy society through communication with elderly living alone or youths without parents, and enhancing marketing strategies. Research design, data, and methodology - To test the hypothesis, a survey was conducted. The surveyed population includes people who use the big three mobile communication services. The survey was conducted from October 4th to October 14th, 2013. A total of 500 survey questionnaires were circulated and 483 were collected; out of these, 32 were excluded due to missing or incomprehensible information. The data was analyzed with SPSS 18.0 via frequency analysis, trust analysis, search factor analysis, relationship analysis, confirmation factor analysis using AMOS 18.0, and structural equation model analysis. Results - Research on corporate social responsibility has been frequently conducted recently. Companies are perceived as social constituents satisfying the social desires of people in addition to customer needs. Further, companies are returning profits to society to satisfy community needs, because there is greater emphasis on the social responsibilities of companies. Companies' social responsibilities should include marketing strategies and the identification of customer needs. This study shows that social service activities influence brand value, which influences customer attitudes; therefore, social service activities indirectly influence customer attitudes. In order to increase customers' purchasing intention, it is essential to improve brand image via social services and provide a distinctive quality of service. Conclusions - This research has used the purposive selection method in the empirical analysis to identify the effect of social services on brand value and customer attitude. Therefore, this study revealed that businesses, whose ultimate objective is to improve customers' purchasing intention, should promote their brand equity through corporate social responsibility activities and offer a distinct service quality. Limitations in the progress of research were found and future indications to overcome these limitations are suggested as follows. First, survey responders had a limited understanding of social responsibilities; therefore, this concept needs to be explained to people first. Second, the research was done on people who live in Daejeon; thus, it is not representative of the entire country. The research has to be repeated with people in other cities. Third, there is a limitation in the study because the purposive selection method was used on Daejeon customers. In the future, a more precise selection of the population is needed. Fourth, Daejeon has unique geographical and size characteristics. Thus, customers in Seoul and other areas may display different characteristics and research on them may reveal different findings. Therefore, again, this study has to be repeated in other areas.