• Title/Summary/Keyword: Strong acid

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Fatigue Crack Growth Behavior of Ni-Cr-Mo Steel under Acid Fog Environment (산성안개 환경하에서 Ni-Cr-Mo 강의 피로크랙전파거동)

  • Kim, Min-Geon;Im, Yong-Ho;Kim, Man-Gu
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.24 no.7 s.178
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    • pp.1841-1846
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    • 2000
  • To examine the effect of acid fog on the corrosion fatigue behavior in structural steel, fatigue tests under acid fog atmosphere were carried out in comparison with distilled water. The corrosive c omponents contained in acid fog pile up the corrosion products on crack face and show a crack branching and crack tip blunting. Therefore, due to these workings crack growth rate was reduced by decreasing the effective stress range in crack tip rather than under distilled water. Also the effect of sulfuric acid, which is the main component of acid fog, and testing speed on fatigue crack growth were examined. It was found that corrosion behavior was remarkably dependent upon pH and Hz rather than components of acid fog. According as pH and testing speed decrease below a specific value, crack growth was accelerated in comparison with distilled water. This reveals that due to liquid having strong acidity and slow speed of test the crack face dissolution was promoted, so crack closure was disturbed in the process of stress descent.

Constituents Analysis of Amino Acid and Antioxidative Activity from Cultivated Callus and Rhizome in Rhodiola sachalinensis

  • Song, Won-Seob;Chi, Hyung-Joon;Rim, Yo-Sup;Yoon, Jae-Ho
    • Plant Resources
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    • v.5 no.1
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    • pp.78-85
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    • 2002
  • The material of Rhodiola sachatinensis collected from an alpine region of the west-northern China. For analysing the effect, 1 used Rhodiola sachatinensis's rhizome and cultivated callus. In EtOAc, BuOH, $H_2O$ separation the plant showed strong antioxidative activity, but not in Hexane. The radical scavenging effect of EtOAc(RC$_{50}$,35(g), BuOH(RC$_{50}$, 43(g), H$_2$0(RC$_{50}$, 50(g) fraction and MeOH extract(RC$_{50}$, 50(g) of the Rhodiola sachatinensis was comparable to that of synthetic antioxidant BHA(RC$_{50}$, 14(g) and $\alpha$-Tocopherol(RC$_{50}$, 12(g). Total amino acid concentration of plant of In nature condition were 18,009ppm, and major components were arginine, glutamic acid, aspartic acid and valine. The ratio of essential/total amino acid on plant of In nature condition was 46.93%. Total amino acid concentration of callus of In vitro condition were 32,435ppm, and major components were valine, histidine, lysine and leucine. The ratio of essential/total amino acid on callus of In vitro condition was 56.07%. was 56.07%.

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Quantity of Ascorbic Acid in the Parts of Vegetable and Its variation by Cooking Method (상용채소의 부위에 따른 환원형 Ascorbic acid량과 조리방법에 따른 C량의 변화)

  • 강신주
    • Journal of the Korean Home Economics Association
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    • v.4 no.1
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    • pp.589-594
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    • 1963
  • Ascorbic acid has a strong power to reduce other materials, so by using this reducing power we can analise many materials quantitatively. Dihydro-ascorbic acid is quantitatively changed into ascorbic acid under a certain condition, if reduced by hydrogen-sulfide. Dihydro-ascorbic acid also has physiolosical effect, but less effect than ascorbic acid. The effect of dihydro-ascorbic acid is regarded as a half of that of ascorbic acid. Among the analytical methods applying this theory the method using 2.6 dichlorophenol indophenol what called the method of Indophenol is used most widely; so does Hydrazine-method. But comparing these two methods the former shows a little higher rate in analytical value. Vegetable are vital sources for vitamin C. According to the report of the commitee of FAO Korean branch the amount of daily per head average intake of vitamin C is about 70mg in raw materials. Since vitamin C is easily affected by heating or oxidation in Cooking the loss is not a little. Consequntly it is regarded that the actual amount of intake will be much less than basic amount. It is therefore very important to find out that how much percent of the loss there will be in case of cooking, in order to dicide the actual amount of in take as proper nutrition for a person. Therefore this paper intended to give some help in setting a standard amount of V.C intake, by measuring the change of the V.C amount using the general cooking method and by measuring amount of V.C contained in the part of vegetable, used in Korea abundantly.

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Evaluation of Antimicrobial Properties of Lichen Substances against Plant Pathogens

  • Paguirigan, Jaycee A.;Liu, Rundong;Im, Seong Mi;Hur, Jae-Seoun;Kim, Wonyong
    • The Plant Pathology Journal
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    • v.38 no.1
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    • pp.25-32
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    • 2022
  • Plant pathogens pose major threats on agriculture and horticulture, causing significant economic loss worldwide. Due to the continuous and excessive use of synthetic pesticides, emergence of pesticide resistant pathogens has become more frequent. Thus, there is a growing needs for environmentally-friendly and selective antimicrobial agents with a novel mode of action, which may be used in combination with conventional pesticides to delay development of pesticide resistance. In this study, we evaluated the potentials of lichen substances as novel biopesticides against eight bacterial and twelve fungal plant pathogens that have historically caused significant phytopathological problems in South Korea. Eight lichen substances of diverse chemical origins were extracted from axenic culture or dried specimen, and further purified for comparative analysis of their antimicrobial properties. Usnic acid and vulpinic acid exhibited strong antibacterial activities against Clavibacter michiganensis subsp. michiganensis. In addition, usnic acid and vulpinic acid were highly effective in the growth inhibition of fungal pathogens, such as Diaporthe eres, D. actinidiae, and Sclerotinia sclerotiorum. Intriguingly, the growth of Rhizoctonia solani was specifically inhibited by lecanoric acid, indicating that lichen substances exhibit some degrees of selectivity to plant pathogens. These results suggested that lichen substance can be used as a selective biopesticide for controlling plant disease of agricultural and horticultural significance, minimizing possible emergence of pesticide resistant pathogens in fields.

Synergistic Effect of Citric Acid on Antioxidant Property of Red Pepper (고추의 산화성(酸化性)에 대한 Citric Acid의 상승효과)

  • Yang, Ki-Sun;Yu, Ju-Hyun;Hwang, Juk-In;Yang, Ryung
    • Korean Journal of Food Science and Technology
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    • v.6 no.4
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    • pp.193-198
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    • 1974
  • The antioxidant activity of ground red pepper, ethyl alcohol extracts of ground red pepper peel and alcohol extracts plus organic acid was studied by using edible soybean oil as a substrate. All the substrates were stored in a dark place at $45.0{\pm}0.5^{\circ}C$ respectively. The results of the study were as follow: 1. Ground red pepper, black pepper and cassia exhibited slight antioxidant activity and there was no significant difference in antioxidant activity among them. 2. Although both ground red pepper peel and red pepper seed showed antioxidant activity, ground red pepper peel exhibited greater antioxidant activity than ground red pepper peel did. 3. Ethyl alcohol extracts of red pepper peel showed strong antioxidant activity, but the residue did not show the antioxidant activity. 4. The antioxidant activity of the ethyl alcohol extracts of red pepper peel increased in direct proportion to the concentration of the extracts. 5. In connection with the synergistic effect of organic acid to the ethyl alcohol extracts of red pepper peel, citric acid showed a very strong synergistic effect on the antioxidant activity of red pepper, while ascorbic acid showed a weak effect. On the other hand, phosphoric acid showed an accelerating effect on the oxidation of oils. 6. The maximum antioxidant activity of the ethyl alcohol of ground red pepper peel was observed at the citric acid concentration of 0.04%, when tested at various concentration of citric acid.

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Theoretical Studies for Strong Hydrogen Bonds in Trimethyl Phosphate-(HNO3)n Complexes, n=1-3

  • Kim, Yong-Ho;Kim, Hak-Won;Park, Kwang-Heon
    • Bulletin of the Korean Chemical Society
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    • v.23 no.12
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    • pp.1811-1815
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    • 2002
  • We have calculated energies and structures for the hydrogen bonded clusters between trimethyl phosphate and nitric acids. The hydrogen bond lengths between phosphoryl oxygen and the proton of nitric acid are short compared to normal hydrogen bonds, and the H-bond strengths are fairly strong. The hydrogen bond length becomes longer, and the strength becomes weaker, as more nitric acids are bound to the TMP. The average H-bond strengths for the $TMP-(HNO_3)_n$ complexes with n = 1, 2, and 3, are 9.6, 7.9 and 6.4kcal/mol at 300K respectively. Weak hydrogen bonds between nitrate oxygen and methyl proton might contribute to the stability of the clusters. Not only the BSSE but also the fragment relaxation energies should be considered to calculate hydrogen bond strengths for the complexes accurately.

Amino Acid Imbalance-Biochemical Mechanism and Nutritional Aspects

  • Park, Byung-Chul
    • Asian-Australasian Journal of Animal Sciences
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    • v.19 no.9
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    • pp.1361-1368
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    • 2006
  • Amino acid imbalances refer to the deleterious effects that occur when a second-limiting amino acid or mixture of amino acid lacking a particular limiting amino acid is supplemented in diets marginal in one or more indispensable amino acids. In spite of variation in the conditions that have been used to induce amino acid imbalances, such as protein level in the diet, the extent of difference in total nitrogen content between basal and imbalanced diets, and kinds of amino acids used as imbalancing agents, the conspicuous common features of amino acid imbalances have been a decreased concentration of the limiting amino acid in blood, depression of feed intake and weight gain, and increased dietary content of the limiting amino acid needed to correct the imbalances. There is strong evidence that a decrease in the concentration of a limiting amino acid detected in the anterior prepyriform cortex of the brain is followed by behavioral effects, especially a decrease in feed intake. This might be due to the competition between the limiting amino acid and the amino acids in the imbalancing mixture for transport from blood into brain. One of the biochemical responses of animals fed amino acid imbalanced diets is a rapid decrease in the concentration of the limiting amino acid, which are due in part to an increase in catabolism of the limiting amino acid by the increased activities of enzymes involved in the catabolism of the amino acid. Practically, specific amino acid imbalances could be induced in swine and poultry diets that have been supplemented with lysine, methionine, tryptophan when threonine, isoleucine, valine, etc. are potentially third- or fourth-limiting in diets. In these cases supplementation of the limiting amino acid could be beneficial in preventing the decrease of feed intake that could otherwise occur as a result of amino acid imbalance.

Evaluation of dye-ability and harmfulness of the reactive dyes replacing the metallic acid dyes for wool

  • Park, Ji-Yang;Park, Young-Hwan;Kang, Tae-Jin
    • Journal of Fashion Business
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    • v.14 no.3
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    • pp.116-127
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    • 2010
  • Metal acid dyes are usually used to dye wool fabric to achieve high concentrated color and strong color fastness. However, metal acid dyes contain lots of heavy metal. That causes not only environmental pollution but also diseases to human. In this study, wool reactive dyes instead of metal acid dyes for wool, which are environmental friendly, are compared and analyzed in the evaluation system of their harmfulness, containing heavy metals and examined exhaustion rates and dyeing characteristics.

A Study on Permanent Wave Form According to the Reductant (퍼머넨트 웨이브의 형태 변화에 미치는 환원제의 영향)

  • Bea, Young-Sil
    • Fashion & Textile Research Journal
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    • v.7 no.6
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    • pp.641-649
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    • 2005
  • This study is to make pH 9 reduction by adding NaOH to 1, 3, 5, 7, 9, 11% solution of thioglycollic acid, cysteine, cysteamin, to add it on helically winded natural hair and colored hair and leave them for 20, 40, 60 minutes, to add $NaBrO_3$ oxidant for 15 minutes and to compare and analyze the wave form. This study showed the results of permanent using thioglycollic acid, cysteine, cysteamin. In the permanent wave form according to the kind of reductant, concentration, and processing time, there were a little difference between thioglycollic acid and cysteine. But cysteamine not only showed apparent difference but also formed strong and elastic wave. The permanent wave is affected by the diagonosis of hair, the choice of permanent solution and the processing time. Therefore the scientific diagonosis of hair is to be considered first of all. By choosing the kind of solution, the concentration and the processing time according to the results of hair diagonosis and wave form, we can prevent the lengthening and damage of hair.

Studies on the Colouring matters for Rubber Industry [I] -Kinetics of the Coupling reaction of H-acid- (고무용(用) azo계(系) 착색제(着色劑)에 관한 연구(硏究) -H-산(酸)의 Coupling반응(反應)에 관한 속도론적(速度論的) 고찰(考察)-)

  • Park, Heung-Cho
    • Elastomers and Composites
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    • v.12 no.1
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    • pp.27-32
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    • 1977
  • The kinetics of azo-coupling reaction of N-acetyl-H-acid (1-acetamino-8-hydroxynaphthalene-3, 6-disulfonic acid) with several heterocyclic diasonium compounds such as diazotiged 3-aminopyridine, 3-aminoquinoline, 8-aminoauinoline and aniline was studied. It was found that reactions proceeded at remarkably different rate. Reaction rate was in increasing order; 3-aminopyridine, 3-aminoquinoline, 8-aminoauinoline and aniline. And the activation energies were 9.62, 10.10, 10.39, 10.70 Kcal/mole, respectively. Especially, the rate constant of 3-aminopyridine was 100 times larger than that of benzene diasonium compound even in strong acidity. Hammett plot was also made of the rate constants obtained against the heterocyclic substituent constants reported in the literature. A good linear relationship was obtained and the reaction constant of N-acetyl H-acid was calculated to be 3.14.

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