• Title/Summary/Keyword: Stripping process

Search Result 160, Processing Time 0.03 seconds

Selective transport of Cadmium by PVC/Aliquat 336 polymer inclusion membranes (PIMs): the role of membrane composition and solution chemistry

  • Adelung, Sandra;Lohrengel, Burkhard;Nghiem, Long Duc
    • Membrane and Water Treatment
    • /
    • v.3 no.2
    • /
    • pp.123-131
    • /
    • 2012
  • This study investigated the extraction and stripping performance of PIMs consisting of PVC and Aliquat 336. Extraction and stripping of three representative heavy metals - namely $Cd^{2+}$, $Cu^{2+}$, and $Zn^{2+}$ - by the synthesized membranes were evaluated as a function of sodium chloride concentration and under different stripping solutions (0.01 M $HNO_3$, Milli-Q water, 0.01 M HCl and 0.01 M NaOH), respectively. Results reported here indicate that the formation of negatively charged metal chloride complex species was responsible for the extraction of the target metal to PIMs. Experimental results and thermodynamic modeling of the speciation of chloro metal complexes further confirm that the extraction selectivity between $Cd^{2+}$, $Cu^{2+}$ and $Zn^{2+}$ can be controlled by regulating the chloride concentration of the feed solution. An acidic solution without any chloride was the most effective stripping solution, followed by Milli-Q water, and a diluted hydrochloric acid solution. On the other hand, the stripping of metals from PIMs did not occur when a basic stripping solution was used.

Optimization of down stream plasma ashing process (감광제 건식제거공정의 최적화)

  • 박세근;이종근
    • Electrical & Electronic Materials
    • /
    • v.9 no.9
    • /
    • pp.918-924
    • /
    • 1996
  • A downstream oxygen plasma is generated by capacitively coupled RF power and applied to photoresist stripping. Stripping rate (ashing rate) is measured in terms of RF power, chamber pressure, oxygen flow rate and temperature. Ashing reaction is thermally activated and depends on oxygen radical density. The ashing process is optimized to have the high ashing rate, good uniformity and minimal plasma damage using a statistical method.

  • PDF

Modeling of Ammonia Mass Transfer Using a Hollow Fiber Membrane Contactor (중공사막 접촉기를 이용한 암모니아 물질전달 모델링)

  • Oh, Dae-Yang;Jeong, Joo-Young;Choi, Won-Ho;Park, Joo-Yang
    • Journal of Korean Society of Water and Wastewater
    • /
    • v.25 no.4
    • /
    • pp.503-510
    • /
    • 2011
  • Ammonia in water which is toxic to human, its concentration is regulated below 0.5 mg/L in drinking water. Current study aimed to develop appropriate models for ammonia stripping using hollow fiber membrane contactor. Two different models were developed during the study. Model 1 was assumed only free ammonia ($NH_3$) transfer in stripping process, whereas the Model 2 was assumed with total ammonia ($NH_3+{NH_4}^+$) transfer. Ammonium chloride ($NH_4CI$), sodium hydroxide(NaOH) were used to make ammonia solution, which was concentration of 25 mg as N/L at a pH of 10.5. The experimental conditions were such that, the liquid flow was in tube-side in upward direction and t he gas flow was on shell-side in downward direction a t room temperature. The experimental and modeling results showed that marginal difference were observed at low gas flux. However the difference between the both models and experimental value were increased when the gas flux was increased. The study concludes that the Model 1 with free ammonia is more appropriate when both models were compared and useful in ammonia stripping process at low gas flux.

Application of magnetic activated sludge process for a milking parlor wastewater treatment with nitrogen and phosphorus recovery

  • Onodera, Toshihito;Sakai, Yasuzo;Kashiwazaki, Masaru;Ihara, Ikko;Lal, Saha Mihir
    • Progress in Superconductivity and Cryogenics
    • /
    • v.23 no.3
    • /
    • pp.20-25
    • /
    • 2021
  • Milking parlor wastewater contains high concentration suspended solid (SS), nitrogen, and/or phosphate as well as organic compounds. A new biological wastewater process by magnetic separation, magnetic activated sludge (MAS) process, was applied to milking parlor wastewater treatment process. A three step wastewater treatment process of coagulation sedimentation / ammonia stripping (C/S), magnetic activated sludge process and contact oxidation (CO) was proposed for removal of these pollutants. First step, C/S process recovered 96% TN and 96% PO43--P as resource for fertilizer from the wastewater. 81% biochemical oxygen demand (BOD) in wastewater was removed after MAS process. As a results, all pollutant concentrations satisfied Japanese effluent standards. Most of residual BOD and SS were removed by the CO process. It was estimated that the proposed process could reduce the process space to 1/7.

A Study on Off-Gas Treatment of an Air Stripping Tower Using a Plasma Reactor

  • Lim, Gye-Gyu;Yoo, Ho-Sik
    • Journal of Korean Society for Atmospheric Environment
    • /
    • v.9 no.E
    • /
    • pp.382-389
    • /
    • 1993
  • An evaluation of a plasma reactor was conducted to investigate its potential as a feasible and economical off-gas control technology for an air stripping tower (AST). The plasma reactor was powered by an alternating current with frequencies up to 1000Hz. The study showed that over 90% conversion of gas-phase trichloroethylene (TCE) can be achieved. An optimum frequency for the laternating current existed for maximum power input. The optimum frequency was dependent on the reactor geometry and the primary voltage applied. for a fixed geometry, a plasma reactor has a limited capacity for flow rate. Even though it is a feasible process to control off-gases, further investigations should be conducted to develop a more economic process.

  • PDF

A Study on Photoresist Strip Process using DIO3 (오존수를 이용한 감광막 제거 공정에 관한 연구)

  • Chai, Sang-Hoon;Son, Young-Soo
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
    • /
    • v.17 no.11
    • /
    • pp.1143-1148
    • /
    • 2004
  • In this study, photoresist stripping in semiconductor or LCD (liquid crystal display) fabrication processes using DIO, was investigated. In order to obtain the high PR stripping efficiency of DIO. we have developed new ozone-generating system with high ozone concentration and ozone-resolving system with high contact ratio. In this study, we obtained ozone gas concentrations of 11 % by new ozone-generating system, ozone-resolving efficiency of 99.5 % and maximum solubility of 130 ppm in deionized water. We applied the newly designed equipments to photoresist stripping processes and obtained similar results to SPM(sulfuric-peroxide mixture) process characteristics.

A Study on Photoresist Stripping Using High Density Oxygen Plasma (고밀도 산소 플라즈마를 이용한 감광제 제거공정에 관한 연구)

  • Jung, Hyoung-Sup;Lee, Jong-Geun;Park, Se-Geun;Yang, Jae-Kyun
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
    • /
    • v.11 no.2
    • /
    • pp.95-100
    • /
    • 1998
  • A helical inductively coupled plasma asher, which produces low energy and high density plasma, has been built and investigated for photoresist stripping process. Oxygen ion density in the order of $10^{11}/cm^3$ is measured by Langmuir probe, and higher oxygen radical density is observed by Optical Emission Spectrometer. As RF source power is increased, the plasma density and thus photoresist stripping rate are increased. Independent RF bias power to the wafer stage provides a dc bias to the wafer and an ability to add the ion assisted reaction. At 1 KW of the source power, the coupling mechanism of the RF power to the plasma is changed from the inductive mode to the capacitive one at about 1 Torr. This change causes the plasma density and ashing rate decreases abruptly. The critical pressure of the mode change becomes larger with larger RF power.

  • PDF

Technical Trend on the Recycling Technologies for Stripping Process Waste Solution by the Patent and Paper Analysis (특허(特許)와 논문(論文)으로 본 스트리핑 공정폐액(工程廢液) 재활용(再活用) 기술(技術) 동향(動向))

  • Lee, Ho-Kyung;Lee, In-Gyoo;Park, Myung-Jun;Koo, Kee-Kahb;Cho, Young-Ju;Cho, Bong-Gyoo
    • Resources Recycling
    • /
    • v.22 no.4
    • /
    • pp.81-90
    • /
    • 2013
  • Since the 1990s, the rapid development of information and communication industry, the demand for semiconductor and LCD continues to increase. Therefore in the formation of fine circuit patterns, which are the cores of sensitizer and the most expensive thinner and stripper liquor used to remove photoresist and its dilution, the amount in demand are dramatically increasing, emerging need for recycling of waste thinner and stripper liquor. Recently, recycling technologies of stripping process waste solution has been widely studied by economic aspects and environmental aspects, in terms of efficiency of the stripping process. In this study, analyzed paper and patent for recycling technologies of waste solution from stripping process. The range of search was limited in the open patents of USA (US), European Union (EP), Japan (JP), Korea (KR) and SCI journals from 1981 to 2010. Patents and journals were collected using key-words searching and filtered by filtering criteria. The trends of the patents and journals was analyzed by the years, countries, companies, and technologies.

Study on the Ethanol Recovery Process using Dircet Contact Heat Exchange (고온의 기포접촉에 의한 에탄올 회수공정에 관한 연구)

  • Lee, Won-Young;Yeo, Sang-Do;Choi, Yong-Hee
    • Korean Journal of Food Science and Technology
    • /
    • v.27 no.2
    • /
    • pp.176-180
    • /
    • 1995
  • Direct contact heat exchange (DCHE) method has been employed to investigate the separation of ethanol from dilute aqueous solutions. Bubbles at high temperature were dispersed into a continuous liquid phase, generating temperature gradient in air-liquid interface, which causes heat and mass transfer accordingly. The experiments were performed in the ranges of jet regime air flow. The air-water stripping coefficient increased $5{\sim}10,\;and\;1{\sim}1.5$ times as temperature and air flow rate increased, respectively. The recovery ratio based on the initial ethanol concentration reached into 80% at the air flow rate of 84.88 m/min. The initial ethanol concentration showed little effect on the stripping coefficient and the recovery ratio.

  • PDF

Formation of Furans during the Acid Hydrolysis of Agar and Their Removal by Treatments of Lime, Steam-stripping and Hydrophobic Resins (한천의 산 당화에 의한 Furan화합물의 생성 및 제거)

  • Kim, Na-Hyun;Lee, Jae-Won;Seo, Yung-Bum;Yoon, Min-Ho
    • Korean Journal of Agricultural Science
    • /
    • v.36 no.2
    • /
    • pp.225-232
    • /
    • 2009
  • The ratio of saccharification and formation of furans during the acid hydrolysis of agar with oxalic acid and sulfuric acid were examined base on the contents of the agar and acids. The ratio of saccharification in oxalic acid appeared to be 51~59% somewhat higher than 49~61% of sulfuric acid. Formation of the furans during the acid hydrolysis increased proportional to the contents of agar and acid. The relative formation ratio was high 10~47% for furfural (FUR) and 15~29% for hydroxy-methyl furfural (HMF) in 0.5~1.25% sulfuric acid rather than those of oxalic acid. When comparing the removal efficiency of the furans using an alkali treatment, steam stripping and hydrophobic resins, FUR was eliminated 60% by the alkali treatment, 62~90% by steam stripping and 71~75% by Amberlite XAD4 and 7HP, while HMF was removed to low levels of 10.5%, 4~17% and 13~25%, respectively. The loss of reducing sugar was also observed in process of the removal of furans, and the loss rate was the level of 2~4% in alkali treatment, 11~16% in steam stripping and 7~9% in Amberlite resins.

  • PDF