• Elastomers and Composites
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• v.47 no.4
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• pp.272-281
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• 2012

Flexible/stretchable electronics have recently focused, since their applications extend to emerging flexible displays, sensors, dielectric elastomer actuator and generators, and smart surgical tools. Flexible/stretchable electrodes should be synchronized with employing mechanical deformations of either flexing or stretching modes. Thus, the research area is one of the tough subjects, since the electrodes should keep their basic functions of electrodes under various mode of mechanical deformations. In this review, we discuss the recent development in the preparation and properties of such flexible/stretchable electrodes.

• Proceedings of the Korean Vacuum Society Conference
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• 2016.02a
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• pp.351.1-351.1
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• 2016

While conventional electronic devices have been fabricated on the rigid and brittle Si based wafer as a semiconducting substrate, future devices are increasingly finding applications where flexibility and stretchability are further integrated to enable emerging and wearable devices. To achieve high flexibility and stretchability, various approaches are investigated such as polymer based conducting composite, thin metal films on the polymer substrate, and structural modifications for stretchable electronics. In spite of many efforts, it is still a challenge to identify a solution that offers both high stretchability and superior electrical properties. In this paper, we introduce a highly stretchable entangled-mesh graphene showing a potential to address such requirements as stretchability and good electrical performance. Entangle-mesh graphene was synthesized by CVD graphene on the Cu foil. To analyze the mechanical properties of entangled-mesh graphene, endurance and stretching tester have been used.

• Proceedings of the Korean Vacuum Society Conference
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• 2016.02a
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• pp.363.2-363.2
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• 2016

Stretchable strain sensors are becoming essential in diverse future applications, such as human motion detection, soft robotics, and various biomedical devices. One of the well-known approaches for fabricating stretchable strain sensors is to embed conductive nanomaterials such as metal nanowires/nanoparticles, graphene, conducting polymer and carbon nanotubes (CNTs) within an elastomeric substrate. Among various conducting nanomaterials, CNTs have been considered as important and promising candidate materials for stretchable strain sensors owing to their high electrical conductivity and excellent mechanical properties. In the past decades, CNT-based strain sensors with high stretchability or sensitivity have been developed. However, CNT-based strain sensors which show both high stretchability and sensitivity have not been reported. Herein, highly stretchable and sensitive strain sensors were fabricated by integrating single-walled carbon nanotubes (SWNTs) and nylon textiles via vacuum-assisted spray-layer-by-layer process. Our strain sensors had high sensitivity with 100 % tensile strain (gauge factor ~ 100). Cyclic tests confirmed that our strain sensors showed very robust and reliable characteristic. Moreover, our SWNTs-based strain sensors were easily and successfully integrated on human finger and knee to detect bending and walking motion. Our approach presented here might be route to preparing highly stretchable and sensitive strain sensors with providing new opportunity to realize practical wearable devices.

• Composites Research
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• v.35 no.4
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• pp.283-287
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• 2022

Stretchable strain sensors have been developed for potential future applications including wearable devices and health monitoring. For practical implementation of stretchable strain sensors, their stability and repeatability are one of the important aspects to be considered. In this work, we utilized 3D printed polymer structures having kirigami patterns to improve the stretchability and reduce the hysteresis. The polymer structures were coated with graphene/carbon nanofiber hybrids to make a robust electrical network. The stretchable strain sensors showed a high gauge of 36 at a strain of 32%. Because of the kirigami structures and the robust graphene/carbon nanofiber coating, the sensors also exhibited stable resistance responses at various strains ranging from 1% to 30%.

• Journal of the Microelectronics and Packaging Society
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• v.23 no.2
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• pp.19-28
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• 2016

This paper presents an overview of selected advanced measurement technologies for the mechanical properties of polymers used for flexible and stretchable electronic packaging. Over the years, a variety of flexible and stretchable electronics have been developed due to their potential applications for next generation IT industry. To achieve more flexible and wearable devices for practical applications, the usage of polymeric components has been increased significantly. Therefore, accurate measurement of mechanical properties of the polymers is necessary in order to design mechanically reliable devices. However, the measurement has been challenging due to the soft nature and thin applications of polymers. Here, we describe novel measurement technologies of mechanical properties of polymers for flexible and stretchable electronics.

• Polymer(Korea)
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• v.27 no.4
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• pp.323-329
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• 2003

Stretchable Polypyrrole films using functionalized doping agent, di(2-ethylhexyl) sulfosuccinate sodium salt (NaDEHS), were synthesized by chemical and electrochemical method. Chemically and electrochemically Prepared Polypyrrole films were stretch-oriented (L/L$\_$0/＝ 1.0 ∼ 2.5) by zone drawing method and the electrical conductivities were measured. As the draw ratio was increased, the electrical conductivities were increased. This result was confirmed by the increase in crystallinity through the increase in draw ratio. The temperature dependence of electrical conductivity showed that 3D-variable range hopping model (L/L$\_$0/ ＝ 1.0∼2.0) and ID-VRH model (L/L$\_$0/ ＝ 2.5) gave the best fit to the data for stretched Ppy-DEHS films.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.30 no.10
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• pp.609-614
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• 2017

The proposed stretchable transparent electrodes based on silver nanowires (AgNWs) were prepared on a polyurethane (PU) substrate. In order toavoid the surface roughness caused by the silver nanowires, a titanium oxide ($TiO_2$) buffer layer was addedby coating and heating the organometallic sol-gel solution. The fabricated stretchable electrodes showedan electrical sheet resistance of $24{\Omega}sq^{-1}$, 78% transmittance at 550 nm, and an average surface roughness below 5 nm. Furthermore, the AgNW-based electrode maintained its initial electrical resistance under 130% strain testing conditions, without the assistance of additional conductive polymer layers. In this paper, the critical role of the $TiO_2$ buffer layer between the AgNW network and the PU substrate has been discussed.

• Journal of the Semiconductor & Display Technology
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• v.14 no.3
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• pp.51-55
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• 2015

We have fabricated silver nanowire (AgNW) films as a stretchable and transparent electrode on polydimethylsiloxane (PDMS) substrates using a spray coater. Inherently, they show poor surface roughness and stretchability. To tackle it, we have employed a conductive polymer, poly (3,4-ethylenedioxythiophene) : Poly(styrene sulfonate) (PEDOT : PSS). PEDTO : PSS solution is mixed with AgNWs or spin-coated on the AgNW film. Compared with AgNW film only, PEDOT : PSS film only, and polymer-mixed AgNW films, the AgNW/polymer bilayer films exhibit much better surface roughness and stretchability. It is found that spray-coating of AgNWs on uncured PDMS and spin-coating of PEDOT : PSS solution on the AgNW films enhance the surface roughness of electrodes. Such a bilayer structure also provides a stable resistance under tensile strain due to the fact that each layer acts as a detour route for carriers. With this structure, we have obtained the peak-to-peak roughness ($R_{pv}$) as low as 76.8nm and a moderate increase of sheet resistance (from $10{\Omega}/{\Box}$ under 0% strain to $30{\Omega}/{\Box}$ under 40% strain).

• Journal of the Microelectronics and Packaging Society
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• v.25 no.4
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• pp.155-161
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• 2018

A Si chip with the Cu/Au bumps of $100-{\mu}m$ diameter was flip-chip bonded using different anisotropic conductive adhesives (ACAs) onto the local stiffness-variant stretchable substrate consisting of polydimethylsiloxane (PDMS) and flexible printed circuit board (FPCB). The average contact resistances of the flip-chip joints processed with ACAs containing different conductive particles were evaluated and compared. The specimen, which was flip-chip bonded using the ACA with Au-coated polymer balls as conductive particles, exhibited a contact resistance of $43.2m{\Omega}$. The contact resistance of the Si chip, which was flip-chip processed with the ACA containing SnBi solder particles, was measured as $36.2m{\Omega}$, On the contrary, an electric open occurred for the sample bonded using the ACA with Ni particles, which was attributed to the formation of flip-chip joints without any entrapped Ni particles because of the least amount of Ni particles in the ACA.

• Journal of the Korean Electrochemical Society
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• v.24 no.4
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• pp.93-99
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• 2021

In order to decrease the weight of stretchable energy storage devices, interest in developing lightweight materials to replace metal current collectors is increasing. In this study, nanofibers prepared by electrospinning a conductive polymer, PEDOT:PSS, were used as current collectors for lithium ion batteries. The nanofiber showed improved electrical conductivity by using DMSO, a dopant, and indicated a stretch rate of 30% or more from the elasticity evaluation result. In addition, the use of the nanofiber current collector facilitates penetration of the liquid electrolyte and exhibits the effect of increasing the electronic conductivity through the nanofiber network. The lithium-ion battery using the DMSO-doped PEDOT:PSS@PAM nanofiber current collector indicated a high discharge capacity of 135mAh g^-1, and indicated a high capacity retention rate of 73.5% after 1000 cycles. Thus, the excellent electrochemical stability and mechanical properties of conductive nanofibers showed that they can be used as lightweight current collectors for stretchable energy storage devices.