• Title/Summary/Keyword: Strength decrease

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Nanofiller as Vulcanizing Aid for Styrene-Butadiene Elastomer

  • Sahoo, N.G.;Das, C.K.;Panda, A.B.;Pramanik, P.
    • Macromolecular Research
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    • v.10 no.6
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    • pp.369-372
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    • 2002
  • The use of ZnO and stearic acid is very well known in sulfenamide accelerated sulfur vulcanization of diene elastomers. Zn-ion coated nano filler has been developed and tested, in styrene-butadiene rubber (SBR) as sulfur vulcanizing activator cum reinforcing filler. In this study Zinc oxide has been replaced by the Zn-ion coated nano silica filler with an aim to study the dual role of this nanofiller in SBR. The presence of Zn-ion on the nano silica filler surface activates the sulfur vulcanization by involving Zn++ in to the sulfurating complex formed with thiazole from sulfenamide. The increase of Zn-ion, on the nanofiller, decrease the scorch safety of the elastomer compound but increase the tensile strength, state of cure and tear strength and attain maximum at its 10% level. The presence of stearic acid increases the rate of vulcanization. Replacement of stearic acid with mono-stearate, however, increases the vulcanization rate but decrease the ultimate state of cure. A mechanistic scheme involving dual function of this nanofiller has been suggested.

Ultrasonically enhancing flowability of cement grout for reinforcing rock joint in deep underground

  • Junho Moon;Inkook Yoon;Minjin Kim;Junsu Lee;Younguk Kim
    • Geomechanics and Engineering
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    • v.33 no.2
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    • pp.211-219
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    • 2023
  • This study analyzes the changes in the physical properties of grout by irradiating it with ultrasonic energy and assesses the injectability of the grout into deep rock fractures. The materials used in the research are OPC (Ordinary Portland Cement) and MC (Micro Cement), and are irradiated depending on the water/cement ratio. After irradiating the grout with ultrasonic energy, viscosity, compressive strength, and particle size are analyzed, and the results of the particle size analysis were applied to Nick Barton's theory to evaluate the injectability of the grout into deep rock fractures under those conditions. It was found that the viscosity of the grout decreased after ultrasonic wave irradiation, and the rate of viscosity reduction tended to decrease as the water/cement ratio increased. Additionally, an increase in compressive strength and a decrease in particle size were observed, indicating that the grout irradiated with ultrasonic energy was more effective for injection into rock fractures.

Physical Properties of Concrete According to Changing in The Types of Premix Cements and the Mixing Rate of CGS. (프리믹스 시멘트 종류 변화 및 CGS 치환에 따른 콘크리트의 물리적 특성)

  • Kim, Su-Hoo;Han, Soo-Hwan;Lim, Gun-Su;Hyun, Seung-Yong;Kim, Jong;Han, Min-Cheol
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2021.11a
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    • pp.63-64
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    • 2021
  • In this study, Coal gasification slag(CGS) was replaced with fine aggregate to verify the physical properties of the concrete according to the change in cement types. As a result of the study, the use of CGS resulted in a decrease of superplasticizer and an decrease of AE agent. In addition, when 50% of mixed cement and CGS were replaced, the initial strength expression was delayed, and the strength enhancing effect was judged to be weak.

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Effects of Co Addition in High Strength and Low Thermal Expansion Invar Alloy (고강도 저열팽창 인바합금에 있어서 CO 첨가의 영향)

  • Kim, Bong-Seo;Jo, Yeong-Am;Yoo, Kyung-Jae;Kwon, Hae-Woong;Lee, Hui-Ung;Kim, Byung-Geol
    • Proceedings of the KIEE Conference
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    • 1999.07d
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    • pp.1901-1903
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    • 1999
  • To investigate invar alloy as a core material for increased capacity over-head transmission line which have high strength and low thermal expansion coefficient, hardness and thermal expansion coefficient of Fe-Ni-Co alloy have been studied. It is necessary that invar alloy have low thermal expansion coefficient and high strength for increased capacity over-head transmission line. In this paper. we tried to find out the effect of Ni and Co which has ferromagnetic properties and high saturation magnetization. It was found that Ni decrease thermal expansion coefficient and hardness, Co decrease thermal expansion coefficient but increase hardness in Fe-xNi-Co system. In Fe-(29-x)Ni-Co system, the material has no low thermal expansion properties substituting Co instead of Ni in concentration range of $1\sim7$%Co.

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Estimation of Fatigue Life in Butt-Welded Zone of SM45C Steel Rod (강 봉(SM45C) 맞대기 용접부의 피로수명 평가)

  • Oh, Byung-Duck;Lee, Yong-Bok
    • Journal of Welding and Joining
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    • v.26 no.3
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    • pp.45-50
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    • 2008
  • SM45C steel rods being used generally for power transmission shafts and machine components was selected and welded by Butt-GMAW(Gas Metal Arc Welding) method. An estimation of fatigue life was studied by constructing S-N curve. Fatigue strength of base metal zone showed higher values than one of weld zone in low cycles between $10^4$ and $10^6$cycles. However, significant decrease in fatigue strength of base metal was found around $10^6$cycles, which were almost same as one of heat affected zone. This decrease was attributed that initial residual stress of the steel rods distributed by drawing process was diminished by continually applied load, and resulted in softening of base metal. The fatigue limit of the weld zone was highest in the boundary between deposited metal zone and heat affected zone, and followed by in the order of deposited metal zone, base metal zone, and heat affected zone. Based on these results, it is revealed that the stress for safety design of machine components using SM45C butt-welded steel rods must be selected within the region of the lowest fatigue limit of heat affected zone.

Effect of MgO Addition Affecting in Zirconia-Frit Composites' Sintering and Properties of Matter (Zirconia-Frit composites의 소결 및 물성에 미치는 MgO 첨가의 효과)

  • Kwon, Eun-Ja;Lee, Gyu-Sun
    • Journal of Technologic Dentistry
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    • v.32 no.1
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    • pp.9-16
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    • 2010
  • This study sought to apply different MgO additions to Zirconia (20wt % Frit) and thereby determine its mechanical properties depending upon variation of temperature, as a part of elementary study. First, in terms of sintering density depending on sintering conditions, it was found that sintering density increased as temperature varied from $1100^{\circ}C$ to $1300^{\circ}C$. As the addition of MgO increased, it was found that sintering density tended to decrease at each temperature. For the maximum sintering density obtained from pellet, it was found that 3wt% MgO addition specimens sintered at $1300^{\circ}C$ had its maximum sintering density as high as 97.39%. This study measured mechanical properties of these specimens, and it was found that their bending strength tended to decrease as the content of MgO addition increased. And it was found that their bending strength reached up to 162 MPa when 3wt% MgO was added to them for sintering process at $1300^{\circ}\Delta C$. It was also found that those specimens had Vickers microhardness up to 4.6 GPa when 5wt% MgO was added to them for sintering process at $1300^{\circ}C$.

Effects of Manual Therapy Approach for Lumbar Spondylolisthesis (요추부 전방전위증 환자의 도수치료 효과 연구)

  • Kang, Seok-Yeong;Kim, Myung-Joon;Lee, So-Hee
    • The Journal of Korean Academy of Orthopedic Manual Physical Therapy
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    • v.16 no.2
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    • pp.34-39
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    • 2010
  • Purpose : The purpose of this study is to find out the evidence concerning the effectiveness of manual therapy intervention in the treatment of low back pain related to spondylolisthesis Methods : 12men with lumbar pain from L5~S1 spondylolisthesis of 2 or 3 grade were treated during 12-week period. The manual therapy applied twice per week. The results of back and radiating pain were measured by VAS, and abdominal muscle strength was measured by Power track II. The measurement of degree of slip in spondylolisthesis was confirmed by the lateral view of X-ray and took a measurements of the anterior displacement of a vertebral body in relation to the vertebral below. Results : 1. There was significant decrease in the back and radiating pain.(p<0.05) 2. There was significant increase in the abdominal muscle strength.(p<0.05). 3. There was significant decrease in the degree of the anterior displacement. Conclusion: The intervention of manual therapy for lumbar spondylolisthesis is effective in back pain, radiating pain, abdominal muscle strength and degree of the anterior displacement. So, nonsurgical treatment should be attempted before surgical treatment.

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Experiment Study for Fracture Characterist of the Ash solid (석탄회 고형물의 파괴특성에 관한 실험적 연구)

  • 조병완;박종빈;김효원
    • Proceedings of the Korea Concrete Institute Conference
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    • 2002.05a
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    • pp.335-340
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    • 2002
  • By the recently, Environmental pollution is serious by the highly economic growth and expansion of lively country basic industry. Especially, in case of industrial waste and life waste leaped into a pollution source. Also, research for processing of waste and recycling countermeasure is a pressing question on national dimension because it is prohibited an ocean disposal and reclamation. In this study, it looked for fracture characteristic value of recycling a coal ash to decrease environmental pollution by picky and exhaustion of natural resources and to reduce self-weight to prepare for a tall building and earthquake. So a coal ash examined to be possible to do as construction material. It achieved compressive strength test and three points bending test with initial notch depth rate and age for variables to show a basic research data. From the basis of the three points bending test, the fracture parameters - notch sensitivity, fracture energy, initial compliance were experimentally proposed. From the results of the compressive strength test, the elastic modulus was experimentally proposed. Also on the basis of the three points bending test, the fracture parameters - notch sensitivity, fracture energy, initial compliance were experimentally proposed. The results that the strength and fracture energy value are lower than concrete or mortar is described in this paper. Also, it shows that the deflection at fracture decreases as the age increases and the notch sensitivity decrease. However, it is judged to be available to construction material if research is continuously gone forward.

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Percolation Threshold and Critical Exponent of Dielectric Breakdown Strength of Polyethylene Matrix Composites added Carbon Black (카본블랙 첨가 PMC(Polyethylene Matrix Composites)의 문턱스며들기(Percolation Threshold)와 절연파괴 강도 임계지수)

  • Shin, Soon-Gi
    • Korean Journal of Materials Research
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    • v.21 no.9
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    • pp.477-481
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    • 2011
  • Composites of insulating polyethylene and carbon black are widely used in switching elements, conductive paint, and other applications due to the large gap of resistance value. This research addresses the critical exponent of dielectric breakdown strength of polymer matrix composites (PMC) made with carbon black and polyethylene below the percolation threshold (Pt) for the first time. Here, Pt means the volume fraction of carbon black of which the resistance of the PMC is transferred from its sharp decrease to gradual decrease in accordance with the increase of carbon-black-filled content. First, the Pt is determined based on the critical exponents of resistivity and relative permittivity. Although huge cohesive bodies of carbon black are formed in case of being less than the Pt, a percolation path connecting the conducting phases is not formed. The dielectric breakdown strength (Dbs) of the PMC below Pt is measured by using an impulse voltage in the range from 10 kV to 40 kV to avoid the effect of joule heating. Although the observed Dbs data seems to be well fitted to a straight line with a slope of 0.9 on a double logarithm of (Pt-$V_{CB}$) and Dbs, the least squares method gives a slope of 0.97 for the PMC. It has been found that finite carbon-black clusters play an important role in dielectric breakdown.

Generation of Hydration Heat of the Concrete Combined Coarse Particle Cement and Blast Furnace Slag (조분 시멘트와 고로슬래그를 조합 사용한 콘크리트의 수화발열 특성)

  • Noh, Sang-Kyun;Baek, Dae-Hyun;Jang, Duk-Bae;Kim, Young-Pil;Cha, Wan-Ho;Han, Cheon-Goo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2008.05a
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    • pp.61-65
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    • 2008
  • This study, having combined and displaced blast furnace slag("BS" hereinafter) known as admixture material that delays hydration reaction with coarse particle cement("CC" hereinafter) collected in particle classification method during ordinary portland cement("OPC" hereinafter), reviewed the hydration heat characteristics affecting the concrete. To reduce hydration heat, the study plain-mixed which used 100% OPC for W/B 50% level 1, displaced CC at level 3 of 25%, 50% and 75% for OPC, and by displacing BS with admixture material at level 5 of 0%, 20%, 40%, 60% and 80% for cement(OPC+CC), experimented totally 16 batches. As a result of experiment, in the case of flow, the more CC displacement rate increased, the more it tended to decrease, and the more BS displacement rate increased, the more it decreased. Also, as for simple adiabatic temperature rise by the CC and BS displacement rates, it decreased as displacement rate increased, and particularly in the case of displaced BS of 80%, It showed temperature reduction effect of about 63% companing with plain. Compressive strength decreased in proportion to displacement rate, however strength reduction increment was shown to decrease with age progress.

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