• Title/Summary/Keyword: Stoichiometric Method

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Growth and Variance of Properties Er2O3 Doped Near Stoichiometric LiNbO3Single Crystals by the Czochralski Method (Czochralski법으로 Er2O3이 첨가된 Near Stoichiometric 조성 LiNbO3 단결정의 성장 및 특성변화)

  • ;;;Masayuki Habu;Takeshi Ito;Masakimi Natori
    • Journal of the Korean Ceramic Society
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    • v.40 no.8
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    • pp.746-750
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    • 2003
  • Using the Czochralski method, Er$_2$O$_3$ doped near stoichiometric LiNbO$_3$ single crystals were grown 15~20 mm in diameter and 30-35 mm in length for Z-axis. Lattice constants were inspected by the X-Ray Diffractometer (XRD) and through Fourier Transform-Infrared Spectrophotometer (FT-IR), it observed absorption band. Also, the distributions of Er concentration were confirmed by the Electron Probe Micro Analysis (EPMA).

Experimental Study on Spray Characteristics of Piezo Injector Group-hole Nozzle for Common Rail Diesel Engine (커먼레일 디젤기관용 피에조 인젝터 그룹홀 노즐의 분무 특성에 관한 실험적 연구)

  • Sung, K.A.
    • Journal of Power System Engineering
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    • v.12 no.5
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    • pp.14-19
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    • 2008
  • In order to meet stringent future emission regulations, especially to reduce Particulate Matter (PM) and NOX, stoichiometric diesel combustion technology with a piezo group-hole nozzle injector is being researched for reduction harmful emissions. A new nozzle layout, namely a group-hole nozzle, which has one group of small orifices with a wide spray included angle was investigated to improve the efficiency of stoichiometric diesel combustion. From this point of view, the group-hole nozzle suggested by Dense Co. is an attractive candidate method applicable to stoichiometric diesel combustion. The group-hole nozzle concept is to reduce the injector nozzle hole diameters without sacrificing spray penetration by closely locating two holes. Experimental studies have proven that the spray from group-hole nozzles have similar spray penetration to that of a single hole with equivalent overall nozzle hole area, but the spray drop sizes (SMD) are reduced, aiding vaporization and mixing.

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Crystal growth and optical properties of near-stoichiometric $Zn:LiNbO_3$ fiber single crystal by ${\mu}-PD$ method (${\mu}-PD$ 법으로 성장시킨 near-stoichiometric 조성 $Zn:LiNbO_3$ fiber 단결정 성장 및 광손상 특성)

  • Lee, H.J.;Shur, J.W.;Shin, T.I.;Song, W.Y.;Yoon, D.H.
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.16 no.6
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    • pp.235-239
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    • 2006
  • ZnO-doped near-stoichiometric $LiNbO_3$ single crystals of $0.8{\sim}1.0mm$ diameter and $30{\sim}35mm$ length were grown by the micro-pulling down (U-PD) method. The structure of the grown crystals was confirmed by powder x-ray diffraction (XRD) patterns. Electron probe micro analysis (EPMA) showed that Zn ions were homogeneously incorporated In grown crystals. The threshold in ZnO doping level was confirmed that an abrupt change in the features of $OH^-$ absorption band as doping level reaching about 2 mol%.

A Study on Nitridation and Oxidation Reaction of Titanium Powder (금속티타늄분말의 질화반응과 산화반응에 관한 연구)

  • Lee, Young-Ki;Sohn, Yong-Un;Cho, Young-Soo;Kim, Yong Seog;Kim, Suk-Yoon
    • Journal of the Korean Society for Heat Treatment
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    • v.8 no.2
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    • pp.137-148
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    • 1995
  • The nitridation kinetics of titanium powder were studied by isothermal and non-isothermal (dynamic) methods in high purity nitrogen under I atm pressure. For the comparison with nitridation, the oxidation kinetics of titanium powder were also studied in dry oxygen at I atm pressure. An automatic recording electrobalance was used to measure the weight gain as a function of time and temperature. For the reaction with nitrogen, the nitride was formed at over $700^{\circ}C$. The reaction with nitrogen followed the parabolic rate law, and the activation energy was calculated to be 31 kcal/mol in the isothermal method (above $900^{\circ}C$). The non-stoichiometric TiNx has been synthesized by the nitridation at a proper temperature and time, followed by the homogenizing treatment above $1100^{\circ}C$. In comparison with the stoichiometric $TiN_{1.0}$ and the non-stoichiometric TiNx ($TiN_{0.5}$ and $TiN_{0.65}$), the hot oxidation characteristics of the former is superior to that of the latter. However, both non-stoichiometric nitrides make little difference in the hot oxidation characteristics.

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Exsolution of $Bi_4Ge_3O_12$ in $Bi_12GeO_20$ Crystals Grown by Pulling Method (인상 육성한 $Bi_12GeO_20$ 결정내의 $Bi_4Ge_3O_12$석출상)

  • 이태근;정수진
    • Journal of the Korean Ceramic Society
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    • v.28 no.12
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    • pp.981-988
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    • 1991
  • Various crystal defects such as voids, inclusions dislocations, stacking faults and precipitates were observed in the Czochralski-grown Bi12GeO20 crystals. Particularly, precipitates were found in the whole crystals. The phase of these precipitates was identified as Bi4Ge3O12 by EPMA and transmission electron microscopy. The precipitates were produced by pulling rapidly from a non-stoichiometric charge. During the pulling of Bi12GeO20 crystals, the melt composition of stoichiometric charge was changed Bi-deficent with gradual volatilization of Bi2O3. Precipition of the second phase may have been affected by an abrube thermal stress. By adding excess Bi2O3 into the stoichiometric batch, the precipitation of Bi4Ge3O12 was suppressed. At a pulling speed of 2 mm/hr, clear and precipitate from crystals of Bi12GeO20 were grown from the melt of the Bi2O3 excess charge.

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Determination of Non-stoichiometry of Tubular Titanium Carbide Formed by Self-Propagating High Temperature Synthesis

  • Choi, Y.;Cho, N.I.
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09b
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    • pp.782-783
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    • 2006
  • Titinium carbide $(TiC_x)$ was produced by self-propagating high temperature synthesis (SHS) method. The morphology and non-stoichiometric number of the SHS product were observed by scanning electron microscopy and neutron diffractometry, respectively. Tubular titanium carbide with hole inside was formed with different non-stoichiometric number (x), which value increased with combustion temperature.

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Analysis of Nitride traps in MONOS Flash Memory (MONOS 플래시 메모리의 Nitride 트랩 분석)

  • Yang, Seung-Dong;Yun, Ho-Jin;Kim, Yu-mi;Kim, Jin-Seob;Eom, Ki-Yun;Chea, Seong-Won;Lee, Hi-Deok;Lee, Ga-Won
    • Journal of the Institute of Electronics and Information Engineers
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    • v.52 no.8
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    • pp.59-63
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    • 2015
  • This paper discusses the capacitance-voltage method in Metal-Oxide-Nitride-Oxide-Silicon (MONOS) devices to analyzed the characteristics of the top oxide/nitride, nitride/bottom oxide interface trap distribution. In the CV method, nitride trap density can be calculated based on the program characteristics of the nitride thickness variations. By applying this method, silicon rich nitride device found to have a larger trap density than stoichiometric nitride device. This result is consistent with previous studies. If this comparison analysis can be expected to result in improved reliability of the SONOS flash memory.

Crystal Growth and Photoluminescence Property of Stoichiometric LiNbO3 Single Crystal Fiber by Addition of Nd2O3 (Nd\2O3 첨가에 따른 화학양론조성 LiNbO3 단결정의 성장 및 형광특성)

  • Shur, Joong-Won;Yoon, Seok-Gyu;Lee, Sung-Mun;Yoon, Dae-Ho
    • Journal of the Korean Ceramic Society
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    • v.39 no.10
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    • pp.977-980
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    • 2002
  • Using the micro-pulling down method, $Nd_2O_3$ doped crack-free stoichiometric $LiNbO_3$ single crystals were grown in 1 mm diameter and 30∼35 mm length. The homogeneous distributions of $Nd_2O_3$ concentration were confirmed by the electron probe micro analysis. The absorption and photoluminescence spectra were measured with respect to the $Nd_2O_3$ doping.

Air-Fuel Ratio Control of Automobile Engines in Steady States by Neural Networks (신경회로망을 이용한 정상상태에서의 자동차 엔진의 공연비제어)

  • 최종호;원영준;고상근;노승탁
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.16 no.11
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    • pp.2119-2125
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    • 1992
  • An air-fuel ratio control method is studied to keep the air-fuel ratio of the exhaust gas in the neighborhood of the stoichiometric air-fuel ratio to maximize the conversion efficiency of the three-way catalytic converter. Estimators, which estimate the air-fuel ratio of the exhaust gas, are proposed using neural networks to overcome the limit of the presently used bang-bang type exhaust gas oxygen sensor. Using these estimators, PI controller for air-fuel ratio control is designed and is experimented for an automobile engine. The proposed controller reduces the variation of air-fuel ratio of the exhaust gas from the stoichiometric air-fuel ratio by 50%-75% when compared to the existing controller.

Preparations of Nano-scale Mullite Powder from Solution Combustion Synthesis (용액연소합성에 의한 나노크기 물라이트 분말의 제조)

  • Lee, Sang-Jin;Yun, Jon-Do;Gwon, Hyeok-Bo;Jeon, Byeong-Se
    • Korean Journal of Materials Research
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    • v.11 no.9
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    • pp.797-801
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    • 2001
  • In this study, the solution combustion method was employed to synthesize stoichiometric mullite, and hence the attrition process was employed to prepare ultrafine mullite particles with nano size. The thermal decomposition behavior and partial pressure of equilibrium species of both oxidizer and fuel were considered during solution combustion process. The synthesized product was mullite phase with 40 nm crystalline size, and the alumina contents of the product by TEM/EDS quantity analysis was 3.12$\pm$04 mole. The result showed that the synthesized mullite was almost close to the it's stoichiometric composition. For attrition process, the dispersion behavior of the mullite suspension was controlled and was comminuted with the condition of 800 rpm for 4 hours using 0.3 mm zirconia ball media. As a result of comminution, the mean particle size was 80 nm.

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