• Proceedings of the KWS Conference
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• 2002.10a
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• pp.355-360
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• 2002

ElectroSlag Strip Overlaying (ESSO) process has been around since 1970. ESSO process had limited acceptance due to a few problems associated with the use of this process in its very early stage. Limited knowledge and, most significantly, poor quality of the equipment and welding flux gave the ESSO process a bad name. However, this process is well accepted today and used in North America, Europe and Japan. The ESSO process provides low dilution overlays at high deposition rates, excellent and consistent deposit chemistry with excellent surface quality, and virtually no defects. Capitan has taken this process one step further through extensive research and development of the process itself as well as the equipment. The improvement brought to the process warranted the issuance in May 2000 of an US patent. This study demonstrates the feasibility of this process with immediate positive production results. The main achievements of this work are as follows: $\textbullet$ Development of six various strip-flux combinations on three different base materials: carbon steel, $\frac{1}{4}$ Cr/.5 Mo and 2 $\frac{1}{4}$ Cr/l Mo, fully tested with: penetrant, ultrasound, bends, hardness, overlay chemistry, corrosion and hydrogen disbonding. $\textbullet$ 12" dia. 90 hot formed elbows from straight pipe electroslag overlayed with "1 layer" and "2 layer" Alloy 625 $\textbullet$ a very unique development of miniaturized overlaying equipment able to perform overlay in pipe with diameters as low as 10" (254 mm). This development has large applications in the field of offshore, petrochemical, refining, pulp and paper and power generation industries. The aftermath of this development was its immediate acceptance by major end users with the completion of four projects of overlayed pipe in the USA and Far East Asia.

• Journal of the Korean Recycled Construction Resources Institute
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• v.5 no.4
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• pp.488-495
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• 2017

In this study, we conducted the kinetic hydration modeling of OPC and the final product according to the substitution ratio of GGBS by using the geochemical code, GEMS, in order to calculate the thermodynamic equilibrium. The thermodynamic data was used by GEMS's 3rd party database, Cemdata18, and the cement hydration model, the Parrot & Killoh model was applied to simulate the hydration process. In OPC modeling, ion concentration of pore solution and hydration products by mass and volume were observed according to time. In the GGBS modeling, as the substitution rate increases, the amount of C-S-H, which contributes the long-term strength, increases, but the amount of Portlandite decreases, which leads to carbonation and steel corrosion. Therefore, it is necessary to establish prevention of some deterioration.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.31 no.5C
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• pp.171-185
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• 2011

Ready-mixed shotcrete that mixed with high quality aggregate and can improve construction quality is produced in a dry mortar plant and transported to construction sites. Because of using aggregate that produced in a special plant, Ready-mixed shotcrete has many advantages : good grain-size distribution, minimum stone powder, high quality and standardization material, etc. In this basic study different from the existing study that limited to additive and accelerator, the improvement of aggregate quality was tried to upgrade the shotcrete performance. The investigation about the construction conditions of shotcrete was performed and the result of an opinion poll was analyzed for a good grasp of the problems in domestic shotcrete quality. Pilot Plant Test was also performed to minimize the material segregation in plant manufacturing process. In additions, the field test was performed to find the optimum contents of synthetic fiber, appearing the same flexible toughness with that of steel fiber, and to find the optimum replacement ratio of blast furnace slag.

• Journal of the Korea institute for structural maintenance and inspection
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• v.20 no.5
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• pp.44-49
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• 2016

Among the deteriorating agents, chloride ion is reported to be one of the most harmful ions due to its rapid diffusion and direct effect on steel corrosion. Cold joint which occurs in mass concrete placing is vulnerable to shear resistance and more severe deterioration. The paper presents an quantitative evaluation of chloride diffusion coefficient in OPC(Ordinary Portland Cement) and GGBFS(Ground Granulated Blast Furnace Slag) concrete containing cold joint. GGBFS concrete shows $6.6{\times}10^{-12}m^2/sec$ which is almost 30% level of OPC concrete results and the trend is repeated in the case of cold joint concrete. Compared with OPC concrete, GGBFS concrete is evaluated to have better resistance to chloride penetration, showing 0.30 times of chloride diffusion coefficient in concrete without cold joint 0.39 times with cold joint, respectively.

• Journal of the Korean Recycled Construction Resources Institute
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• v.10 no.4
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• pp.523-530
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• 2022

The problem in the construction of seawall reinforcing the seawall where there is seawater flow is the outflow of materials. Gravity-type pouring of concrete is difficult to fill the voids smoothly, and the cement of concrete that has not hardened is likely to be dispersed in seawater. This phenomenon not only reduces the reliability of quality after concrete hardening, but can also adversely affect the surrounding environment. Therefore, there is a need for a gel-like injection material that can be injected, In this study, the initial strength and durability improvement effect of seawater immersion were evaluated by using electrofurnace reduction slag and blast furnace slag with acute properties. As a result of the experiment, it was possible to prepare a gel-like injection material having flowability through reaction with silica-based chemical liquid. The flowability of the gel is 105~143 mm depending on the formulation, and the on-site simulation test can fill the voids without external leakage, confirming its on-site applicability.

• Journal of the Korea Institute of Building Construction
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• v.23 no.2
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• pp.113-121
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• 2023

In this study, the applicability and reproducibility of laser induced breakdown spectroscopy(LIBS) for heavy metal analysis in clinker and 5 types of by-products(crushed stone sludge, blast furnace slag, steel slag, waste concrete sludge, bottom ash) were experimentally reviewed. As a result of ICP-MS, XRF, and LIBS analysis of the six samples, the difference between ICP and XRF was confirmed in the quantitative analysis, but the LIBS analysis showed a difference by element from the standard analysis, and only qualitative analysis of the sample was possible. LIBS analysis wavelength was set for three types of heavy metals(Cd - 214.44nm, Pb - 405.78nm, Hg - 253.65nm). As a result of laser irradiation on the surface of the membrane impregnated with a solution of each concentration(1~1000ppm) and dried, the correlation between the spectral intensity and the concentration was confirmed.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.19 no.5
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• pp.661-671
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• 2018

Domestic studies on steel plate concrete structures have focused on nuclear structures with high strength. In this study, the SC structure was applied to the general structure, and the SC structure that is advantageous in terms of safety and construction was limited to a special structure. As a basic study for applying SC, this paper proposes basic design information of a SC structure applying cement concrete to plan the structure, which is suitable for eco - friendliness by replacing concrete cement, an important factor in a SC structure, with blast furnace slag. This study examined the compression characteristics and the effective length factor under central compression load. To calculate the effective length factor, the Euler column theory was applied without applying plate theory. The effective length factor was calculated from the yield strength of the steel plate, buckling of the steel plate, and the point at which the concrete was broken. In addition, this study examined whether the maximum compressive strength meets the national and international reference equations with the slenderness ratio (B/t) as a parameter. By analyzing the buckling of the specimen by applying the column theory and selecting the strain of the measured steel plate, the effective length factor was analyzed and compared with the value presented in the reference equation.

• Resources Recycling
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• v.28 no.4
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• pp.44-50
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• 2019

In the electric arc furnace process, the chemical energy such as the heat of oxidation reaction and the heat of carbon combustion etc. is consumed as 30% of the total input energy. In order to reduce $CO_2$ emission in EAF, it is necessary to decrease the use of electric power energy during scrap melting stage and increase the use of chemical energy. In general, when the carbon materials is individually charged into the molten steel, the carbon materials floated to the slag layer due to low density before it is dissolved in molten steel. When the concentration of carbon in the molten steel is high, the combustion energy of carbon by oxygen injection can lower the electric power energy and improve the chemical energy consumption. Therefore, an efficient charging methods of carbon material is required to increase the efficiency of carbon combustion heat. On the other hand, Al-dross, which is known as a by-product after Al smelting, includes over 25 mass% of metallic Al, and the oxidation heats of Al is lager than that of carbon. However, the recycling ratio fo Al-dross was very low and is almost landfilled. In order to effectively utilize the heats of oxidation of Al in Al-dross, it is necessary to study the application of Al-dross in the steel process. In this study, the dissolution efficiency of carbon and aluminum in molten steel was investigated by varying the reaction temperature and the mixing ratios of coke and Al-dross.

• Korean Journal of Soil Science and Fertilizer
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• v.44 no.5
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• pp.734-744
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• 2011

A soil stabilization method is an effective and practical remediation alternative for arsenic (As) and heavy metal contaminated farmland soils nearby abandoned metal mine in Korea. This method is a technique whereby amendments are incorporated and mixed with a contaminated soil. Toxic metal bind to the amendments, which reduce their mobility in soil, so the successful stabilization of multi-element contaminated soil depends on the combination of critical elements in the soil and the type of amendments. The objective of this study is to investigate the treatment effects and applicability of limestone (LS) and steel refining slag (SRS) as the amendment for farmland soil contaminated with As and heavy metals, and a lab-column test was conducted for achieving this purpose. The result showed that soil treated with LS and SRS maintained pH buffer capacity and, as a result, the heavy metal leaching concentration was quite low below the water quality standard compared to untreated soil which leachate exceeding the water quality standard was observed, however, the arsenic concentration rather increased with increasing mixture ratio of SRS. This was believed to be related to phosphorus (P) contained in SRS, and dominancy in the competitive adsorption relation between As and P binding strongly to iron might be different according to soil characteristic. We suggested that LS is a effective amendment for reducing heavy metals in soil, and SRS should be used after investigating its applicability based on the adsorption selectivity of arsenic and phosphorus in selected soil.

• Korean Journal of Soil Science and Fertilizer
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• v.45 no.6
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• pp.961-967
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• 2012

There have been many studies about efficiency of amendments for heavy metal stabilization through chemical assessment. The objective of this study was to evaluate the efficiency of several soil amendments (lime, agric-lime, dolomite, steel slag, fly ash and acid mine drainage sludge) on heavy metals stabilization through not only chemical but also biological assessments (phytotoxicity test) in abandoned mining area soil. In order to achieve the goal, we conducted preliminary screening experiment targeting 12 types of crop plants such as radish, young radish, chinese cabbage, winter grown cabbage, cabbage, bok choy, chicory, crown daisy, carrot, chives, spinach, and spring onion. The results of inhibition rates of early plant growth in metal-contaminated soil against non-contaminated soil and the correlations between inhibitions items showed that the bok choy was appropriate specie with respect to confirm the effect of several amendments. Several amendment treatments on contaminated soil brought about the changes in the root and shoot elongation of bok choy after 1 week. Agric-lime, dolomite and steel slag treatments showed the great efficiency of reducing on mobility of heavy metals using chemical assessment. But in contrary, these treatments resulted in the reduction of root and shoot elongation and only AMD sludge increased that of elongation, significantly. When considering both chemical and biological assessments, AMD sludge could be recommended the compatible amendment for target contaminated soil. In conclusion, biological assessment was also important aspect of decision of successful soil remediation.