• Bulletin of the Korean Chemical Society
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• 제28권11호
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• pp.1980-1984
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• 2007

An HPLC chiral stationary phase (CSP) which has only two ureide functional groups was prepared starting from (1S,2S)-1,2-diaminocyclohexane. The CSP was successful in the resolution of various N-(3,5- dinitrobenzoyl)-α-amino acids, the separation (α) and the resolution factors (RS) being within the range of 1.11-1.35 and 2.19-5.17, respectively with the use of 20% 2-propanol in hexane containing 0.1% trifluoroacetic acid as a mobile phase. However, ethyl esters of N-(3,5-dinitrobenzoyl)-α-amino acids were not resolved or resolved with only marginal separation and resolution factors on the CSP under the identical mobile phase condition. From these results, the complexation of the carboxylate anions of analytes inside the double-ureide pocket of the CSP was expected to play some important role for the chiral recognition. In contrast, N-(3,5- dinitrobenzoyl)-α-amino acid N-propylamides were resolved on the CSP with reasonable separation and resolution factors. Enantioselective hydrogen bonding interactions between analytes and the CSP were presumed to be responsible for these resolutions.

• 대한수학회논문집
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• 제28권2호
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• pp.383-396
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• 2013

We consider an M/PH/1 queue with deterministic impatience time. An exact analytical expression for the stationary distribution of the workload is derived. By modifying the workload process and using Markovian structure of the phase-type distribution for service times, we are able to construct a new Markov process. The stationary distribution of the new Markov process allows us to find the stationary distribution of the workload. By using the stationary distribution of the workload, we obtain performance measures such as the loss probability, the waiting time distribution and the queue size distribution.

• 한국군사과학기술학회지
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• 제13권2호
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• pp.304-312
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• 2010

The function of IRCM(Infrared Countermeasures) jamming is to cause the missile to miss its intended target by disturbing the seeker tracking process. This paper analyzes the jamming effect of IRCM jamming for a stationary reticle seeker. The phase error containing the azimuth angle information of target is analyzed for the intensity, frequency and duty ratio variation of the jammer pulse signal. We confirmed that the more the jammer frequency is similar to the spinning frequency of the stationary seeker, the more jamming effect is high.

• Journal of Mechanical Science and Technology
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• 제20권6호
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• pp.849-863
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• 2006

IBM (Immersed Boundary Method) with feedback momentum forcing was applied to stationary and moving bodies. The capability of IBM to treat the obstacle surfaces, especially with moving effect has been tested for two dimensional problems. Stationary and oscillating cylinders were simulated by using IBM based on finite volume method with Cartesian coordinates. For oscillating cylinder, lateral and vertical motions are considered, respectively. Present results such as time histories of drag and lift coefficients for both stationary and oscillating cases are in good agreement with previous numerical and experimental results. Also, the instantaneous wake patterns of oscillating cylinder with different oscillating frequency ratios well represented those of previous researches. More feasibility study for IBM has been carried out to two oscillating cylinders. Drag and lift coefficients are presented for two cylinders oscillating sinusoidally with phase difference of $180^{\circ}$.

• 전기전자학회논문지
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• 제24권1호
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• pp.154-160
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• 2020

본 논문에서는 계통연계인버터용 정지좌표기반 전류제어알고리즘을 제안한다. PI 제어기는 계통 연결 인버터의 전류 제어기로 사용되고 있다. 정지좌표기반 PI 제어기를 사용할 경우, AC 신호 제어로 인하여 정상 상태 오류와 위상지연현상이 발생한다. 본 논문에서는 전향보상기를 추가하여 명령 추적 성능을 높이고 과도 응답을 개선하는 방법을 제안한다. 또한 계통 전압을 외란으로 사용하여 계통 오류 발생 시 시스템을 보호하기 위해 외란을 측정 및 제거하는 제어 방법을 제안한다. 제안된 제어 방법은 수학적으로 유도하고 전달 함수로 표현하였으며 시뮬레이션을 통하여 검증하였다.

• Membrane and Water Treatment
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• 제5권3호
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• pp.171-182
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• 2014

Organic compounds are adsorbed on RO/NF membranes, and the adsorption may influence the rejection of organic compounds by the membranes. Because almost RO/NF membranes are composite membranes, the results obtained by adsorption experiment with using membrane pieces are unable to avoid the influence by the support membrane. In this work, the interaction between membrane polymer and organic solutes was examined by an inverse HPLC methodology. Poly (m-phenylenetrimesoylate), the constituent of skin layer of RO/NF membranes, was coated on silica gel particles and used as a stationary phase for HPLC. When water was used as a mobile phase, almost hydrophilic aliphatic compounds were not effectively adsorbed on the stationary phase, although hydrophobic compounds were slightly adsorbed. The results indicated that the hydrophilic aliphatic compounds are useful probe solutes to examine the molecular sieving effect of a membrane. When water was used as a mobile phase, the aromatic compounds were strongly retained, and therefore $CH_3CN/H_2O$ (30/70) was used as a mobile phase. It was revealed that the adsorption of aromatic compounds was controlled by stacking between solute and polymer and was hindered by non-planar structure and substituents.

• Bulletin of the Korean Chemical Society
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• 제19권8호
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• pp.819-821
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• 1998

• Bulletin of the Korean Chemical Society
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• 제17권5호
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• pp.409-412
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• 1996

• Bulletin of the Korean Chemical Society
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• 제20권10호
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• pp.1245-1247
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• 1999

• Bulletin of the Korean Chemical Society
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• 제11권3호
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• pp.189-190
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• 1990