• Title/Summary/Keyword: State of Mixing

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Phase Equilibria Measurement of Binary Mixture for the Propoxylated Neopentyl Glycol Diacrylate in Supercritical Carbon Dioxide

  • Byun, Hun-Soo
    • Korean Chemical Engineering Research
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    • v.54 no.2
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    • pp.206-212
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    • 2016
  • Experimental data are reported on the phase equilibrium of propoxylated neopentyl glycol diacrylate in supercritical carbon dioxide. Phase equilibria data were measured in static method at a temperature of (313.2, 333.2, 353.2, 373.2 and 393.2) K and at pressures up to 27.82 MPa. At a constant pressure, the solubility of propoxylated neopentyl glycol diacrylate for the (carbon dioxide + propoxylated neopentyl glycol diacrylate) system increases as temperature increases. The (carbon dioxide + propoxylated neopentyl glycol diacrylate) system exhibits type-I phase behavior. The experimental result for the (carbon dioxide + propoxylated neopentyl glycol diacrylate) system is correlated with Peng-Robinson equation of state using mixing rule. The critical property of propoxylated neopentyl glycol diacrylate is predicted with Joback and Lyderson method.

Blue Laser Generated by Sum Frequency (합주파에 의한 청색레이저 발생)

  • Lee Young-Woo
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.10 no.2
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    • pp.224-227
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    • 2006
  • We have chained 459nm blue laser radiation generated by intracavity sum frequency generation( SFG ) due to the mixing of the 1064 nm laser output of a Nd:YVO4 pumped by diode and the 809nm radiation from higg-power semiconductor laser(500mW). The maximum blue output power of 0.95 mW was obtained using 400 mW input power of semiconductor laser at the type II phase matching condition (${\psi}=90^{\circ}\;{\theta}=90^{\circ}$). The threshold input power of blue laser generation was 120 mW.

A Study on Rheological Behavior of Cordierite Honeycomb Extrusion Paste (코디어라이트 허니컴 압출용 혼합체의 점성거동에 관한 연구)

  • Song, Yong-Ik;Kim, Hyung-Tae;Lee, Jin-Gu;Yoon, Won-Jung;Ryu, Sung-Soo
    • Journal of Powder Materials
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    • v.17 no.1
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    • pp.44-51
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    • 2010
  • The rheological behavior of a cordierite honeycomb extrusion paste was investigated by measuring torque values in a Brabender plastograph. The extrusion pastes were formulated using binder (methy cellulose, MC), solvent (water), plasticizer (ploy ethylene glycol, PEG) and lubricants (oleic acid, OA). The mixing sequence and optimum organic binder, at least for homogeneous mixed state, can be determined from the rheological point of view. 3%MC-30%$H_2O$-1.5%PEG-1.0%OA with respect to the cordierite powder was chosen as a binder composition for the extrusion process of cordierite powder.

Bubble-Point Measurement of Binary Mixture for the CO2 + Caprolactone Acrylate System in High Pressure

  • Jeong, Jong-Dae;Byun, Hun-Soo
    • Korean Chemical Engineering Research
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    • v.57 no.6
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    • pp.826-831
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    • 2019
  • Experimental data of phase equilibrium is reported for caprolactone acrylate in supercritical carbon dioxide. Bubble-point data was measured by synthetic method at temperatures ranging from (313.2 to 393.2) K and pressures up to 55.93 MPa. In this research, the solubility of carbon dioxide for the (carbon dioxide + caprolactone acrylate) system decreases as temperature increases at a constant pressure. The (carbon dioxide + caprolactone acrylate) system exhibits type-I phase behavior. The experimental result for the (carbon dioxide + caprolactone acrylate) system was correlated with Peng-Robinson equation of state using mixing rule. The critical property of caprolactone acrylate was predicted with the Joback and Lyderson method.

Analyses of Two Different Versions of HETCOR Techniques for Solids

  • Kim, Se-Hun;Han, Doug-Young
    • Journal of the Korean Magnetic Resonance Society
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    • v.12 no.2
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    • pp.81-88
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    • 2008
  • Solid HETCOR (Hetero-Correlation) requires homo-dipolar decoupling between proton spins during the evolution and the mixing period in 2D-NMR. There are two different ways of achieving it with pulse sequences. One is based on the multiple pulse (MP) sequence where thousands of intense radio frequency (rf) pulses are used to remove the homo-dipolar interaction between protons. The other is utilizing the so-called Lee-Goldburg (LG) off-resonance scheme where a continuous rf-irradiation is used. In this report, the advantage of one technique to the other, is analyzed. LG version is evaluated better in S/N and easier in setup procedure with the same experimental time.

Chemical Properties of Co(II) Compound Containing Endocrine Disrupter, Bis-Phenol A

  • Park, Chil-Nam
    • Journal of Environmental Science International
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    • v.11 no.2
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    • pp.131-137
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    • 2002
  • The chemical behavior and properties on the redox state of environmental pollutant has been investigated by electrochemical methods. We carried out to measure the variations in the redox reaction of differential pulse polarogram and cyclic voltammogram. The results observed the influences on redox potential and current of various factors with temperature and pH. These were established factors as the effect of the redox reaction. It can be clearly recognized that the electrode reaction are from qusi-reversible to irreversible processes. Also, it was mixing with reaction current controlled. The bits-phenol A in the waste water was made to compound with cobalt ion and it take away from the separation into compound. The $Co(BPA)_2$ compound was not found to be dissociation in waste water. However, this compound is avery unstable(K=1.02) and for a while, it was to be a dissociation. Therefore, we believed that it was likely to a toxic substance.

Full Color Reflective Cholesteric Liquid Crystal using Photosensitive Chiral Dopant (감광성 도판트를 이용한 풀컬러 구현 가능 반사형 콜레스테릭 액정)

  • Park, Seo-Kyu;Kim, Jeong-Soo;Cho, Hee-Suck;Kwon, Soon-Bum;Reznikov, Yuri
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.21 no.5
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    • pp.474-480
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    • 2008
  • In order to make full color cholesteric displays, color filter-less R, G, B sub-pixel structured cholesteric LC cells have been studied. To make R, G, B colors, UV induced pitch variant chiral dopant was added to cholesteric LC mixtures. The concentration of the photo-sensitive chiral dopant was adjusted so that the initial state showed blue color and the color was changed from blue to green and red with increase of UV irradiation to the cholesteric cells. To prevent the mixing of R, G, B reflective sub-pixel liquid crystals, separation walls were formed using negative photo resister in boundary area between sub-pixels, Through the optimization of the material concentrations and UV irradiation condition, vivid R, G, B colors were achieved.

Unsteady Transient Flowfield in an Integrated Rocket Ramjet Engine (램제트 엔진의 비정상 천이 유동에 관한 연구)

  • H.K. Sung;Vigor Yang
    • Journal of the Korean Society of Propulsion Engineers
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    • v.4 no.1
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    • pp.74-92
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    • 2000
  • A numerical analysis has been conducted to study the transient flowfield during the transition from the booster to sustainer phase in an integrated rocket ramjet (IRR) propulsion system. Emphasis is placed on the unsteady inlet aerodynamics, fuel/air mixing in an entire ramjet engine during the flow transient phase. The computational geometry consists of the entire IRR engine, including the inlet, the combustion chamber, and the exhaust nozzle. Turbulence closure is achieved using a low-Reynolds-number two-equation model. The governing equations are solved numerically by means of a finite-volume, preconditioned flux-differencing scheme over a wide range of Mach umber. Various important physical processes are investigated systemically, including terminal shock train.

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Ligand Field Approach to $4d^{1}$ Magnetism Based on Intermediate Field Coupling Scheme

  • 최진호;김종영
    • Bulletin of the Korean Chemical Society
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    • v.18 no.9
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    • pp.976-981
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    • 1997
  • The magnetic susceptibilities of molybdenum ions with 4d1 electronic configuration in the octahedral crystal field were calculated on the basis of ligand field theory. The experimental magnetic susceptibilities for molybdenum ions, which are stabilized at the octahedral site in the perovskite lattice of Ba2ScMoⅤO6 and Sr2YMoⅤO6, were compared with the theoretical ones. We have tried to fit their temperature dependence of magnetic susceptibility with ligand field parameters, spin-orbit coupling constant ζSO, and orbital reduction parameter κ according to intermediate field coupling and strong field theory. Strong field coupling theory could not explain experimental curves without unrealistically large axial ligand field, since it ignores the mixing up between different state via spin-orbit interaction and ligand field. On the other hand, the intermediate field coupling theory could successfully reproduce experimental data in octahedral and trigonal ligand field. The fitting result demonstrates not only the fact that spin-orbit interaction is primarily responsible for the variation of magnetic behavior but also the fact that effective orbital overlap, enhanced by cubic crystal structure, reduces significantly orbital angular momentum as indicated by κ parameter.

Adaptive Regression by Mixing for Fixed Design

  • Oh, Jong-Chul;Lu, Yun;Yang, Yuhong
    • Communications for Statistical Applications and Methods
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    • v.12 no.3
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    • pp.713-727
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    • 2005
  • Among different regression approaches, nonparametric procedures perform well under different conditions. In practice it is very hard to identify which is the best procedure for the data at hand, thus model combination is of practical importance. In this paper, we focus on one dimensional regression with fixed design. Polynomial regression, local regression, and smoothing spline are considered. The data are split into two parts, one part is used for estimation and the other part is used for prediction. Prediction performances are used to assign weights to different regression procedures. Simulation results show that the combined estimator performs better or similarly compared with the estimator chosen by cross validation. The combined estimator generates a similar risk to the best candidate procedure for the data.