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http://dx.doi.org/10.9713/kcer.2016.54.2.206

Phase Equilibria Measurement of Binary Mixture for the Propoxylated Neopentyl Glycol Diacrylate in Supercritical Carbon Dioxide  

Byun, Hun-Soo (Department of Chemical and Biomolecular Engineering, Chonnam National University)
Publication Information
Korean Chemical Engineering Research / v.54, no.2, 2016 , pp. 206-212 More about this Journal
Abstract
Experimental data are reported on the phase equilibrium of propoxylated neopentyl glycol diacrylate in supercritical carbon dioxide. Phase equilibria data were measured in static method at a temperature of (313.2, 333.2, 353.2, 373.2 and 393.2) K and at pressures up to 27.82 MPa. At a constant pressure, the solubility of propoxylated neopentyl glycol diacrylate for the (carbon dioxide + propoxylated neopentyl glycol diacrylate) system increases as temperature increases. The (carbon dioxide + propoxylated neopentyl glycol diacrylate) system exhibits type-I phase behavior. The experimental result for the (carbon dioxide + propoxylated neopentyl glycol diacrylate) system is correlated with Peng-Robinson equation of state using mixing rule. The critical property of propoxylated neopentyl glycol diacrylate is predicted with Joback and Lyderson method.
Keywords
Propoxylated Neopentyl Glycol Diacrylate; Carbon Dioxide; Phase Behavior; Bubble-Point; Pressure-Composition;
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Times Cited By KSCI : 4  (Citation Analysis)
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