• Title/Summary/Keyword: Stainless steel electrode

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Further Electrochemical Degradation of Real Textile Effluent Using PbO2 Electrode

  • Wang, Chao;Tian, Penghao
    • Journal of Electrochemical Science and Technology
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    • v.12 no.2
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    • pp.266-271
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    • 2021
  • A commercial PbO2 electrode was adopted as the anode for the electrochemical degradation of the real textile effluent with the initial COD of 56.0 mg L-1 and the stainless steel plate as the cathode. The effect of the initial pH, the electrolyte flow rate and the cell voltage on the COD, the current efficiency and the energy consumption were investigated without the addition of NaCl or Na2SO4. The experimental results illustrated that the PbO2 electrode can reduce the COD of the textile effluent from 56.0 mg L-1 to 26.0 mg L-1 with the current efficiency of 86.1% and the energy consumption of 17.5 kWh kg-1 (per kilogram of degraded COD) under the optimal operating conditions. Therefore PbO2 electrode as the anode was promising to further electrochemically degrade the real textile effluent.

A Study on the Nitriding of Sintered Metallic Components by Hollow Cathode Discharge (할로우 캐소드 방전에 의한 금속소결부품의 질화처리에 관한 연구)

  • Kim, Y.C.;Han, C.S.
    • Journal of the Korean Society for Heat Treatment
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    • v.25 no.2
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    • pp.80-84
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    • 2012
  • An apparatus was constructed to nitrify small metallic sintered components by using a hollow-cathode discharge plasma method. A stainless steel basket, which contains a sintered part to be nitrified, is potentially grounded and serves as hollow-cathode electrode. Hollow-cathode plasma was produced by supplying the positive voltage to the anode. In this study sintered carbon iron and stainless steel were used as testing specimens. It was shown that an effective nitrifying took place by controlling the total pressure of nitrogen and hydrogen gas and applied voltage.

Lean Burn Combustion Characteristics of Propane Premixed Flame in Electric Field (전기장 인가에 따른 프로판 예혼합 화염의 희박연소 특성)

  • Minseok Kim;Junyoung Choi;Taehun Kim;Hyemin Kim
    • Journal of ILASS-Korea
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    • v.28 no.1
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    • pp.24-31
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    • 2023
  • In this study, characteristics of a propane-air premixed flame sin DC electric field was investigated. The stainless steel Bunsen burner and the stainless steel ring were used as electrode, and the high voltage supply was used for applying electric field. Flammability range increased significantly when the positive voltage was applied because of extension of LBO limit, while it shrank when the negative voltage was applied. The reason for this was not much related to the burning velocity, but the induced flow around the burner by electric field. withNOx production slightly increased after positive voltage was applied in identical equivalence ratio. Nevertheless, it was advantageous to apply the positive electric field to reduce the NOx since the extension of LBO limit makes the burner possible to operate in very low equivalence ratio.

Experiment on the Polish Condition of Needle Electrode on the Insulation Properties of Gas Mixtures (침전극 가공상태에 따른 혼합가스의 절연특성에 관한 실험)

  • Go, Yeon-Seong;Yeo, Dong-Goo;Seo, Ho-Joon;Lee, Dong-Hee
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2006.11a
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    • pp.339-340
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    • 2006
  • AC spark discharge voltage of SF6/CO2and SF6/N2 containing various mixed rate in volume percent (1, 5 and 10%) of SF6 in non-uniform fields are investigated. The needle to plane electrode gap spacing was 5 and 10 mm, and the gas pressure was varied within the range of 0.1~0.7 MPa. We have observed a N-characteristic typical for the electronegative gases even in gas mixtures of 1% SF6 with CO2 and N2 as buffer gases. Especially, the materials of the needle electrode affect the insulation properties of the gas mixtures drastically. On the contrary to the case of needle electrodes made by mild steel or high carbon steel, the N-characteristics are hardly perceived in the case of stainless steel needle in this experiment.

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Discharge Characteristics of SF6 Mixture Gases due to Processing Status of needle electrode under Non-Uniform Fields (불평등 전계 하에서의 침전극 가공상태에 따른 SF6혼합가스의 방전특성)

  • Go, Y.S.;Seo, H.J.;Rhie, D.H.
    • Proceedings of the KIEE Conference
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    • 2006.10a
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    • pp.198-199
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    • 2006
  • AC spark discharge voltage of SF6/C02and SF6/N2 containing various mixed rate in volume percent (1, 5 and 10%) of SF6 in non-uniform fields are investigated. The needle to plane electrode gap spacing was 5 and 10 mm, and the gas pressure was varied within the range of 0.1${\sim}$0.7 MPa. We have observed a N-characteristic typical for the electronegative gases even in gas mixtures of 1% SF6 with CO2 and N2 as buffer gases. Especially, the materials of the needle electrode affect the insulation properties of the gas mixtures drastically. On the contrary to the case of needle electrodes made by mild steel or high carbon steel, the N-characteristics are hardly perceived in the case of stainless steel needle in this experiment.

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AN ELECTROCHEMICAL STUDY ON THE CORROSION RESISTANCE OF THE VARIOUS IMPLANT METALS (수종 임플랜트 금속의 내식성에 관한 전기화학적 연구)

  • Jeon Jin-Young;Kim Yung-Soo
    • The Journal of Korean Academy of Prosthodontics
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    • v.31 no.3
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    • pp.423-446
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    • 1993
  • Titanium and its alloys are finding increasing use in medical devices and dental implants. The strong selling point of titanium is its resistance to the highly corrosive body fluids in which an implant must survive. This corrosion resistance is due to a tenacious passive oxide or film which exists on the metal's surface and renders it passive. Potentiodynamic polarization measurement is one of the most commonly used electro-chemical methods that have been applied to measure corrosion rates. And the potentiodynamic polarization test supplies detailed information such as open circuit, rupture, and passivation potential. Furthermore, it indicates the passive range and sensitivity to pitting corrosion. This study was designed to compare the corrosion resistance of the commonly used dental implant materials such as CP Ti, Ti-6A1-4V, Co-Cr-Mo alloy, and 316L stainless steel. And the effects of galvanic couples between titanium and the dental alloys were assessed for their useful-ness-as. materials for superstructure. The working electrode is the specimen , the reference electrode is a saturated calomel electrode (SCE), and the counter electrode is made of carbon. In $N_2-saturated$ 0.9% NaCl solutions, the potential scanning was performed starting from -800mV (SCE) and the scan rate was 1 mV/sec. At least three different polarization measurements were carried out for each material on separate specimen. The galvanic corrosion measurements were conducted in the zero-shunt ammeter with an implant supraconstruction surface ratio of 1:1. The contact current density was recorded over a 24-hour period. The results were as follows : 1. In potential-time curve, all specimens became increasingly more noble after immersion in the test solution and reached between -70mV and 50mV (SCE) respectively after 12 hours. 2. The Ti and Ti alloy in the saline solution were most resistant to corrosion. They showed the typical passive behavior which was exhibited over the entire experimental range. Therefore no breakdown potentials were observed. 3. Comparing the rupture potentials, Ti and Ti alloy had the high(:st value (because their break-down potentials were not observed in this study potential range ) followed by Co-Cr-Mo alloy and stainless steel (316L). So , the corrosion resistance of titanium was cecellent, Co-Cr-Mo alloy slightly inferior and stainless steel (316L) much less. 4. The contact current density sinks faster than any other galvanic couple in the case of Ti/gold alloy. 5. Ag-Pd alloy coupled with Ti yielded high current density in the early stage. Furthermore, Ti became anodic. 6. Ti/Ni-Cr alloy showed a relatively high galvanic current and a tendency to increase.

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Synthesis of TCO-less Solar Cell using Metal Mesh Type Electrode and its Photovoltaic Characteristics (금속 메쉬 전극을 이용한 TCO-less 광전변환소자 제작 및 광전변환 특성)

  • Park, Min-Woo;Sung, Youl-Moon
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.25 no.2
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    • pp.126-130
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    • 2011
  • Transparent conductive oxide (TCO) is an important part in the construction of dye-sensitized solar cells (DSCs) because of its low sheet resistance, sufficient light transparent ability and high photoelectrical response as a porous photo-electrode material of DSCs. However, the use of TCO for the two DSC electrodes can result in significant cost increase for the less effective DSCs compared to Si based solar cell. Therefore, the replacement of TCO is required for the commercial production of DSCs. In this study, TCO electrodes are replaced by stainless steel mesh. The 3.44[%] efficiency of the prepared TCO-less DSCs sample was obtained.

characteristic of breakdown voltage of electrode gap in vacuum (진공에서 극간 gap에 따른 절연파괴 전압 특성 파악)

  • Yoon, Jae-Hun;Kim, Byung-Chul;Lee, Sueng-Su;Lim, Kee-Jo;Kang, Seong-Hwa
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.11a
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    • pp.366-367
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    • 2008
  • SF6 widely used as insulating gas is rising as the environment problem. For decreasing this greenhouse gas, electrical breakdown characteristics of vacuum with air are studied in non-uniform field. The gap of needle to plane was 0.5mm, 0.8mm. The pressure of vacuum the range of 10^-4-10^-5torr. The diameter of a plane made of the stainless steel is150mm. As a result of the experiment, the breakdown voltage is increased about electrode gap distance increased. The electrode material influenced breakdown voltage in vacuum.

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The Effect of Electrode Surface Condition on Prebreakdown Current and Breakdown Voltage (진공중에시 전극표면상태가 전구전류 및 절연파괴전압에 미치는 영향)

  • Kim, Du-Sik;Lee, Dong-In;Lee, Kwang-Sik;Kim, In-Sik
    • Proceedings of the KIEE Conference
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    • 1987.11a
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    • pp.286-289
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    • 1987
  • The measurements of prebreakdown currents and breakdown voltages have been made for smooth rough, protrusion plane parallel stainless steel electrodes in vacuum ($10^{-5}$ torr), as a function of electrode separation, in the range $0.4{\sim}2.4mm$ using DC source($0{\sim}200KV$). Thee prebreakdwon currents of a each condition are found to be consistent with the Fouler-Nondheim field emission theory. The effect of the electrode surface condition on the local field enhancement factors, prebreakdown currents, and on the breakdown voltages are shown. The breakdown mechanism of a small vacuum gap was ascertained as the field emission corresponding the F-N theory. Therefore, these results suggest that the field emission currents following the electrode surface condition play a major role for initiation of DC breakdown.

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A Study on the Electrochemical Impedance Spectroscopy and the Electrical Circuit Model for the Electrode/Electrolyte Interface (전극/전해질 계면의 전기화학적 임피던스 측정 및 전기회로 모델 연구)

  • Chang, Jong-Hyeon;Hong, Jang-Won;Pak, Jung-Ho
    • Proceedings of the KIEE Conference
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    • 2007.07a
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    • pp.274-275
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    • 2007
  • The investigation of the equivalent circuit models for the electrode/electrolyte interface has been pursued for a long time by several researchers. Previous circuit models fit the experimental results in limited conditions such as frequency range, type of electrode, or electrolyte. This paper describes a new electrical circuit model and its capability of fitting the experimental results. Electrochemical impedance spectroscopy was used to characterize the interface for Au, Pt, and stainless steel electrode in 0.9% NaCl solution. Both the proposed model and the previous model were applied to fit the measured impedance results for comparison. The proposed model fits the experimental data more accurately than other models especially at the low frequency range, and it enables us to predict the impedance at very low frequency range, including DC, using the proposed model.

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