• Title/Summary/Keyword: Stabilization materials

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Study of Stabilization Process of PAN Precursor and its Characteristics Change by Plasma Treatment (플라즈마 처리 방법을 이용한 PAN 전구체 특성 변화 연구)

  • Kang, Hyo-Kyoung;Kim, Jung-Yeon;Kim, Hak-Yong;Choi, Yeong-Og
    • Composites Research
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    • v.34 no.1
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    • pp.23-29
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    • 2021
  • Commercialized carbon fiber obtained from polyacrylonitrile(PAN) precursor is subjected to oxidation stabilization at 180 to 300℃ in air atmosphere and carbonization process at 1600℃ or lower in inert gas atmosphere. Both of these processes use a lot of time and high energy, but are essential and important for producing high-performance carbon fibers. Therefore, in recent years, an alternative stabilization technology by being assisted with various other energy sources such as plasma, electron beam and microwave which can shorten the process time and lower energy consumption has been studied. In this study, the PAN precursor was stabilized by using plasma treatment and heat treatment continuously. The morphology, structural changes, thermal and physical properties were analyzed using Field emission scanning electron microscopy(FE-SEM), X-ray diffraction(XRD), Fourier transform infrared(FT-IR), Thermogravimetric analysis(TGA) and Favimat.

Elucidation of Intergranular Corrosion of UNS N08810 alloys (UNS N08810 합금의 입계부식손상과 원인 분석)

  • Kim, Youngsik;Hwangbo, Deok
    • Corrosion Science and Technology
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    • v.11 no.5
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    • pp.196-204
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    • 2012
  • Corrosion failure of petrochemical facilities is one of the difficulties in maintenance, since operating conditions of crude oil production, storage, and refinement are very aggressive. UNS N08810, which has been used for crude oil transportation pipes and storage tanks in petrochemical industries, shows good resistance to general corrosion and localized corrosion in several environments. Among its environments, UNS N08810 showed better corrosion resistance in fuel gas containing sulfuric acid and phosphoric acid and sulfur. However, ductility and toughness at high temperature over about $500^{\circ}C$ were greatly reduced due to microstructural change. In general, welding process is the representative method to join the parts in industrial components. Because the alloy by welding can be sensitized and corroded, the manufacturing process should be controlled. In this work, UNS N08810 was used and heat treatment conditions including solution and stabilization treatments were controlled. Oxalic acid etch test by ASTM A262 Practice A was done to evaluate the qualitative sensitization in room temperature. Huey test by ASTM A262 Practice C was done to evaluate the intergranular corrosion rate in boiling 65% $HNO_3$ solution. Also, the microstructure by thermal history was analyzed. Experimental alloy showed high intergranular corrosion rate and its corrosion mechanism was elucidated.

A Hybrid Audio ${\Delta}{\Sigma}$ Modulator with dB-Linear Gain Control Function

  • Kim, Yi-Gyeong;Cho, Min-Hyung;Kim, Bong-Chan;Kwon, Jong-Kee
    • ETRI Journal
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    • v.33 no.6
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    • pp.897-903
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    • 2011
  • A hybrid ${\Delta}{\Sigma}$ modulator for audio applications is presented in this paper. The pulse generator for digital-to-analog converter alleviates the requirement of the external clock jitter and calibrates the coefficient variation due to a process shift and temperature changes. The input resistor network in the first integrator offers a gain control function in a dB-linear fashion. Also, careful chopper stabilization implementation using return-to-zero scheme in the first continuous-time integrator minimizes both the influence of flicker noise and inflow noise due to chopping. The chip is implemented in a 0.13 ${\mu}m$ CMOS technology (I/O devices) and occupies an active area of 0.37 $mm^2$. The ${\Delta}{\Sigma}$ modulator achieves a dynamic range (A-weighted) of 97.8 dB and a peak signal-to-noise-plus-distortion ratio of 90.0 dB over an audio bandwidth of 20 kHz with a 4.4 mW power consumption from 3.3 V. Also, the gain of the modulator is controlled from -9.5 dB to 8.5 dB, and the performance of the modulator is maintained up to 5 nsRMS external clock jitter.

Application of Soil Stabilization Technique for Shoulder Construction in Sri Lanka (스리랑카 길어깨 적용을 위한 안정처리 재료의 적용성 평가 연구)

  • Park, Ki Soo;Park, Hee Mun
    • International Journal of Highway Engineering
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    • v.20 no.4
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    • pp.21-26
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    • 2018
  • PURPOSES : The objective of this study is to evaluate the application of soil stabilization method for soft shoulder construction in the iRoad Project of Sri Lanka. METHODS : Firstly, the quantitative analysis of soil strength improvement due to soil stabilization was done for soil samples collected from iRoad construction sites. Two types of soils were selected from iRoad Project sites and prepared for soil stabilization testing by the Road Development Authority. Secondly, the appropriate stabilizer was selected at given soil type based on test results. Two different stabilizers, ST-1 and ST-2, produced in Korea were used for estimating soil strength improvements. Finally, the optimum stabilizer content was determined for improving shoulder performance. The uniaxial compressive strength (UCS) test was conducted to evaluate the strength of stabilized soil samples in accordance with ASTM D 1633. The use of bottom ash as a stabilizer produced from power plant in Sri Lanka was also reviewed in this task. RESULTS : It is found from the UCS testing that a 3% use of soil stabilizer can improve the strength up to 2~5 times in stabilized soft shoulder soils with respect to unstabilized soils. It is also observed from UCS testing that the ST-1 shows high strength improvement in 3% of stabilizer content but the strength improvement rate with increase of stabilizer content is relatively low compared with ST-2. The ST-2 shows a low UCS value at 3% of content but the UCS values increase significantly with increase of stabilizer content. When using the ST-2 as stabilizing agent, the 5% is recommended as minimum content based on UCS testing results. Based on the testing results for bottom ash replacement, the stabilized sample with bottom ash shows the low strength value. CONCLUSIONS : This paper is intended to check the feasibility for use the soil stabilization technique for shoulder construction in Sri Lanka. The use of soil stabilizer enables to improve the durability and strength in soft shoulder materials. When applying the bottom ash as a soil stabilizer, various testings should be conducted to satisfy the specification criteria.

Solidification/stabilization of Hazardous Wastes Using Cementitious Materials(III) (특수시멘트 고형화재를 이용한 지정폐기물의 고형화/안정화(III))

  • Lim, Chae-Yong;Ku, Ki-Dae;Um, Tae-Sun;Lee, Jong-Ryul;Choi, Long;Oh, Byoung-Hwan
    • Proceedings of the Korea Concrete Institute Conference
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    • 2001.05a
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    • pp.289-294
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    • 2001
  • This study concerns the cement-solidification/stabilization of the waste with high concentration heavy metals. Compressive strength and leaching test of heavy metals were evaluated for ing types of cements and the effect of the additives of Hauyne clinker and slag were also cussed. Using ordinary portland cement, rapid hardening portland cement and the cement with additives solidification materials, it shows that the strength and stability of concrete is satisfactory and superiority is in the order of rapid hardening portland cement > the cement with additives > nary portland cements.

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Enhancement of the efficiency stabilization and the color coordinates in blue organic light-emitting devices with double emitting layers

  • Bang, H.S.;Han, S.M.;Lee, D.U.;Kim, T.W.;Kim, J.H.;Seo, J.H.;Kim, Y.K.
    • 한국정보디스플레이학회:학술대회논문집
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    • 2006.08a
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    • pp.1030-1033
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    • 2006
  • The efficiency stabilization and the color coordinates in blue organic light-emitting devices (OLEDs) with a double emitting layer (DEL) consisting of 4,4'-Bis(carbazol-9-yl)biphenyl (CBP) and 4,4'-Bis(2,2-diphenyl-ethen-1-yl)diphenyl were investigated. The efficiency of the OLEDs with a DEL did not significantly change with an increase in current density. The Commission Internationale de l'Eclairage coordinates of the OLEDs with a DEL 11 V were (0.150, 0.137), indicative of a deep blue color.

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Influence of oxidative atmosphere of the electron beam irradiation on cyclization of PAN-based fibers

  • Shin, Hye Kyoung;Park, Mira;Kim, Hak-Yong;Park, Soo-Jin
    • Carbon letters
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    • v.16 no.3
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    • pp.219-221
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    • 2015
  • In order to study the impact of atmosphere during electron beam irradiation (EBI) of polyacrylonitrile (PAN) precursor fibers, the latter were stabilized by EBI in both air and oxygen atmospheres. Gel-fraction determination indicated that EBI-stabilization under an oxygen atmosphere leads to an enhanced cyclization in the PAN fibers. In the Fourier-transform infrared spectroscopy analysis, the PAN fibers stabilized by EBI under an oxygen atmosphere exhibited a greater decrease in the peak intensity at 2244 cm−1 (C≡N vibration) and a greater increase in the peak intensity at 1628 cm−1 (C=N absorption) than the corresponding PAN fibers stabilized under an air atmosphere. From the X-ray diffraction analysis it was found that oxygen uptake in PAN fibers leads to an increase in the amorphous region, produced by cyclization.

A Study on the Stabilization Scheme of Optical Source for Precision Measurement (정밀측정을 위한 안정된 광원에 관한 연구)

  • 김지대;서호성;이동주
    • Proceedings of the Korean Society of Machine Tool Engineers Conference
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    • 2003.04a
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    • pp.265-271
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    • 2003
  • This study is for the stable optical source in order to get the precision measurement, which contributes to help the laser frequency and the output to be settled. The laser optical frequency is changed by the length of resonance cavity. The length variation of the laser resonance amplitude is affected by the thermal expansion of that system. So, we try not only to adjust the temperature of the laser tube using the heater for fine length of resonance cavity, but also to maintain the fixed temperature of the resonance cavity for outputting the safe laser optical frequency. Therefore, we must take materials with the thermal expansion of the supporting system, which is closer to it of the laser resonance cavity. Using the materials, we can promote to stabilize the temperature of it. In advance, we also plan to get the settlement of the laser frequency and the output in the long km, optimizing and stabilizing the system.

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Development of Remediation and Stabilization Technique for Low-Permeable Contaminated Soil Using Waste Materials (폐기물을 활용한 저투수성 오염토양의 정화 및 안정화 기술 개발)

  • 박상규;이기호;박준범
    • Proceedings of the Korean Geotechical Society Conference
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    • 2002.10a
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    • pp.681-688
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    • 2002
  • Study was peformed to develop the‘environmental double pile’for the remediation of low-permeable contaminated soil. This technique is similar in function to‘sand drain pile’But this applies recyclable oyster shell treated as waste materials to a drain material and the pile is consisted of two layers. Inner metal pile is located in center and oyster shells are filled around it. By this technology, contaminated ground water is pumped out through the oyster shell and purified by drainage, adsorption, and reaction processes. Afterwards, the grout material is injected through the inner pile for the effect of the solidification / stabilization. As a result, the concept of this technique is a development of one-step process technology. Through the test, a consolidation characteristic by radial drain is going to be evaluated and the optimum standard of this technology will be calculated.

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Effect of slag on stabilization of sewage sludge and organic soil

  • Kaya, Zulkuf
    • Geomechanics and Engineering
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    • v.10 no.5
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    • pp.689-707
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    • 2016
  • Soil stabilization is one of the useful method of ground improvement for soil with low bearing capacity and high settlement and unrequired swelling potential. Generally, the stabilization is carried out by adding some solid materials. The main objective of this research was to investigate the feasibility of stabilization of organic soils and sewage sludge to obtain low cost alternative embankment material by the addition of two different slags. Slags were used as a replacement for weak soil at ratios of 0%, 25%, 50%, 75% and 100%, where sewage sludge and organic soil were blended with slags separately. The maximum dry unit weights and the optimum water contents for all soil mixtures were determined. In order to investigate the influence of the slags on the strength of sewage sludge and organic soil, and to obtain the optimal mix design; compaction tests, the California bearing ratio (CBR) test, unconfined compressive strength (UCS) test, hydraulic conductivity test (HCT) and pH tests were carried out on slag-soil specimens. Unconfined compressive tests were performed on non-cured samples and those cured at 7 days. The test results obtained from untreated specimens were compared to tests results obtained from soil samples treated with slag. Laboratory tests results indicated that blending slags with organic soil or sewage sludge improved the engineering properties of organic or sewage sludge. Therefore, it is concluded that slag can be potentially used as a stabilizer to improve the properties of organic soils and sewage sludge.