• Proceedings of the Korean Geotechical Society Conference
• /
• 한국지반공학회 2002년도 봄 학술발표회 논문집
• /
• pp.731-738
• /
• 2002

Recently, as large constructions on the coast are performed frequently, surface layer stabilization method which Is one of the improvement methods for dredged soft clay has been applied. However, there have been few studies about the surface layer stabilization method. The purpose of this study is to clarify characteristics of ultra-soft marine clay and hardening agent. Also, optimal mixture ratio of hardening agent was verified through the laboratory tests such as statistical analysis and pilot tests. Laboratory tests were performed with proper hardening agent and test soil and standard mixing tables of hardening agent were determined according to ground conditions through statistical analysis. Also, applicability of surface layer stabilization method to field was verified by pilot tests. From the results of the tests, it was found that hardening agent materials such as cement, slag, fly-ash, inorganic salts, arwin, gypsum etc. affect on the appearing compressive strength. It was defined optimal mixture ratio which satisfies the required compressive strength from the statistical analysis. Also, It was compared the effect of ground improvement by cements and hardening agents through the pilot tests. This study will serve as data for design or construction criteria of stabilization of surface layer on ultra-soft marine clay.

• Carbon letters
• /
• 제15권4호
• /
• pp.290-294
• /
• 2014

New precursors, poly(acrylonitrile-co-crotonic acid) (poly(AN-CA)) and poly(acrylonitrile-co-itaconic acid-co-crotonic acid) (poly(AN-IA-CA)) copolymers, for the preparation of carbon fibers, were explored in this study. The effects of comonomers with acidic groups, such as crotonic acid (CA) and/or itaconic acid (IA), on the stabilization of nanofibrous polyacrylonitrile (PAN) copolymers were studied. The extent of stabilization, evaluated by Fourier transform infrared spectroscopy, revealed that the CA comonomer could retard/control the stabilization rate of PAN, in contrast to the IA comonomer, which accelerated the stabilization process. Moreover, the synthesized PAN copolymers containing CA possessed higher Mv than those of the IA copolymers and also showed outstanding dimension stability of nanofibers during the stabilization, which may be a useful property for improving the dimensional stability of polymer composites during manufacturing.

• Proceedings of the Korean Magnestics Society Conference
• /
• 한국자기학회 2016년도 자성 및 자성재료 국제학술대회
• /
• pp.163-164
• /
• 2016

• Journal of Ocean Engineering and Technology
• /
• 제15권1호
• /
• pp.92-97
• /
• 2001

Hardening agents have been the traditional material for surface soil stabilization of soft ground. This study aims at determining the optimal mixture ratio of the hardening agent in accordance with the required design specifications. Hardening agents which consists of fly ash, gypsum, slag and cement for the ettringite hydrates is effective for early stabilization of unconsolidated soil. The raw ground material is the clay that is widely found in Korea. In this study, preliminary tests were performed to get an optimal mixture ratio of the stabilizer ingredient and marine clay from Jinhae was used to get physical and chemical properties. Laboratory tests of 50 stabilized soils were performed to get an optimal mixture ratio for 16-stabilizer materials of 6 types, and a mixture ratio of the stabilizer ingredient and marine clay was determined.

• Journal of Korean Society on Water Environment
• /
• 제25권2호
• /
• pp.288-294
• /
• 2009

Flow field-flow fractionation (Fl-FFF) device has been widely used to verify the size and molecular weight of various colloids and organics. The Fl-FFF, however, generally uses carrier solutions with only low to moderate ionic strengths to exclude the high affinity of materials to the membrane under high ionic strength conditions. Thus, materials existing in seawaters have not been accurately analysed based on the hydrodynamic size and molecular weight using current Fl-FFF techniques. The highest ionic strength tested was up to 0.1 M, while seawater ionic strength is about 0.6 M. The aim of this study is to accurately measure the hydrodynamic size of particles under carrier solutions close to seawater conditions with the Fl-FFF. By employing various operating conditions during the Fl-FFF analyses, it was demonstrated that the flow conditions, the concentration of surfactants, and stabilization times were key factors in acquiring compatible data. Results have shown that the cross flow was more influential factor than the channel flow. The concentration of the surfactant was to be at least 0.05% and the minimum 15 hr of stabilization was needed for accurate and reproducible data acquisition under seawater condition.

• Carbon letters
• /
• 제14권2호
• /
• pp.94-98
• /
• 2013

Isotropic pitch fibers were stabilized and carbonized for preparing carbon fibers. To optimize the duration and temperature during the stabilization process, a thermogravimetric analysis was conducted. Stabilized fibers were carbonized at 1000, 1500, and $2000^{\circ}C$ in a furnace under a nitrogen atmosphere. An elemental analysis confirmed that the carbon content increased with an increase in the carbonization temperature. Although short graphitic-like layers were observed with carbon fibers heat-treated at 1500 and $2000^{\circ}C$, Raman spectroscopy and X-ray diffraction revealed no significant effect of the carbonization temperature on the crystalline structure of the carbon fibers, indicating the limit of developing an ordered structure of isotropic pitch-based carbon fibers. The electrical conductivity of the carbonized fiber reached $3.9{\times}10^4$ S/m with the carbonization temperature increasing to $2000^{\circ}C$ using a four-point method.

• Journal of the Korean Society for Heat Treatment
• /
• 제13권2호
• /
• pp.98-102
• /
• 2000

The effect of vacuum heat treatment in the thermal sprayed ceramics coating on a capstan by either high velocity oxygen fuel(HVOF) or plasma thermal spray process was investigated. The coating materials applied on the capstan were tungsten and chrome carbides. In order to characterize the interface between coating layer and bare materials, hardness, adhesion strength, X-ray diffraction(XRD) and microstructural analysis are conducted. The adhesion strength of the carbide coated materials by HVOF process is over 500MPa compared to those of plasma coating process is 230MPa. In case of the carbide coated materials by HVOF process, the adhesion strength is increased to 15MPa and the porosity is reduced under 5% by vacuum heat treatment for 5 hrs at $1000^{\circ}C$. The XRD results reveal that the increasement is believed due to the phase stabilization of metastable $Cr_3C_2$ phase to stable $Cr_{23}C_6$ phase.

• Proceedings of the Korean Geotechical Society Conference
• /
• 한국지반공학회 2000년도 가을 학술발표회 논문집
• /
• pp.657-664
• /
• 2000

Weak and soft compressible clay deposits are commonly found in natural subgrade soils. These Soils need to be stabilized for using the subbase materials of highway constructions. This paper presents that a chemical treatment using chemical additives comprised of sulfate(SO$_4$) and chloride(Cl) is evaluated for stabilizing soft clay deposits and lime. The physical and mechanical characteristics of soil-lime and additives are described by means of a laboratory study. The study results indicate that the presence of chlorides encouraged the efficiency of lime stabilization, and the use of calcium chloride with quicklime is the best additive for improving soil behavior. The treated soil with lime-calcium chloride can have the adaptability to the subbase materials of highway constructions.

• Proceedings of the Korean Geotechical Society Conference
• /
• 한국지반공학회 2008년도 춘계 학술발표회 초청강연 및 논문집
• /
• pp.920-925
• /
• 2008

In this presentation, a leaching experiment which is followed the pH changes(pH=4, pH=7) and the mixing rates(1%, 3%, 5%, 7%) was carried out to examine the arsenic reduction effects and the leaching characteristics on arsenic contaminated soil after stabilization treatment in which 5 materials were used as stabilization agencies, i.e. ZVI(zero valent iron), blast furnace slag, steel refining slag, quick lime, and oyster shell meal. Except for blast furnace slag, the arsenic removal rate increased as the mixing rate increases of stabilization agencies. Arsenic leaching concentration was indicated that pH=7 condition is higher than pH=4 condition. This result shows because arsenic immobilization reaction increases as pH decreases, and arsenic adsorption takes place as pH decreases.

• The Journal of Engineering Research
• /
• 제3권1호
• /
• pp.215-222
• /
• 1998

The effect of La and Si addition of the thermal stabilization of $\gamma-alumina$ powers have been studied. Reagent grade $La(NO_3)_3{\cdot}6H_2O$ and $Si(OC_2H_5)_4$ were used as starting materials. These additives were introduced by wet impregnation method. Both La and Si additives suppressed the sintering of alumina and were found to be good thermal stabilizers of $\gamma-alumina$. Especially, Si drastically suppressed the phase transition of alumina at high temperatures. The major mechanisms for the thermal stabilization of alumina were seemed to be new phase formation and retardation of surface diffusion by addition of La or Si into alumina matrix.