• Title/Summary/Keyword: Sr Ferrite

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Preparation of Sr-Ferrite Powders by Hydrothermal (수열합성법에 의한 Sr-Ferrite 분말합성)

  • 이경희;이병하;김상규
    • Journal of the Korean Ceramic Society
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    • v.24 no.1
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    • pp.17-22
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    • 1987
  • This study is to detect the synthetic condition for the formation of Sr-Ferrite(SrFe12O19) by hydrothermally reaction. Mixed suspension of SrCl26H2O and FeCl3 6H2O were fixed on pH and were subjected to autoclavings at various temperature(150∼300$^{\circ}C$), reaction time(2hrs.∼48hrs.). The Sr-Ferrite powders were synthesized at 150$^{\circ}C$ for 36hrs, 200$^{\circ}C$ for 4hrs and 250$^{\circ}C$ for 2hrs. Synthesized powders were increased particle sizes at longer reaction time and higher reaction temperature. It has hexagonal ferrite M-type structure and has high purity of SrO.5.6 Fe2O3 composition.

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Effect of the Powder Characteristics of Iron Oxides on the Magnetic Properties of Sr-ferrite (산화철의 분체특성이 Sr-ferrite의 자기특성에 미치는 영향)

  • 조태식;김효준;최승덕;남효덕;염충진
    • Resources Recycling
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    • v.7 no.4
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    • pp.43-49
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    • 1998
  • We investigated the effects of the powder characteristics of various domestic iron oxides (${\alpha}Fe_2O_3$) on the magnetic properties of Sr-ferrites The particle size and the distribution of iron oxides were classified hy three different rerinning methods, and greatly a affected on the magn$\xi$tic prope$\pi$ies and the mmphology of Sr-ferntes. The agglomeration of Ruthner iron oxides and the large particles of Chemirite (CY) above $0.80{\mu}\textrm{m}$ were degraded the prope며es of Sr-fcrrites. The optimal magnetic prope$\pi$ies of Srt territes, showing 68.2 emu/g of saturation magnetization and 4300 Oe of intrinsic coerClvity, were achieved at the following c conditions; Chemirite (P2EP) iron oxides of $0.14{\mu}\textrm{m}$ molar ratio of 5.8. and calcination of $1150^{\circ}C$/1 hr.

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Development of Composite Sr Ferrite EM Wave Absorbers for GHz Frequency (GHz 대역용 복합형 Sr 페라이트 전파 흡수체의 개발)

  • Kim, Dong-Il;Moon, Sang-Hyun;Shin, Sung-Jae;Song, Jae-Man;Kim, Ki-Man
    • Journal of Navigation and Port Research
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    • v.28 no.6
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    • pp.503-507
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    • 2004
  • We prepared EM wave absorbers by using recycled Sr ferrite for GHz frequency, and investigated the effects of carbon additions and preparation temperatures on their EM wave absorption properties. A Sr ferrite EM wave absorber with the ratio of Sr ferrite: silicon rubber: carbon = 80 : 13.6: 6.4 wt% prepared at 7$0^{\circ}C$ showed -24 dB at 9.4 GHz and -23 dB at 5.5 GHz for 2 mm and 3 mm thickness, respectively.

The Effect of CuO and SiO2 on the Magnetic Properties of Sr-Ferrite (CuO와 SiO2가 Sr-페라이트의 자기적 특성에 미치는 영향)

  • 김동식;김동엽;정원용;오재현
    • Journal of the Korean Ceramic Society
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    • v.26 no.6
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    • pp.747-754
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    • 1989
  • The effects of CuO and SiO2 on the sintered density, grain growth and magnetic properties of Sr-ferrite were investigated. The sintered density of Sr-ferrite is increased with increasing the amount of CuO or SiO2 addition. The grain of Sr-ferrite grow uniformly with the addition of CuO, so remanence increases and coercivity decreases. The addition of SiO2 increase coercivity but does not affect remanence prominently. The sintering temperature above 125$0^{\circ}C$ and SiO2 addition above 0.8wt% causes abnormal grain growth in Sr-ferrite. When CuO and SiO2 are added simultaneouly, remanence does not decrease but coercivity shows low value.

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Microstructure Control of Sr-Ferrite by Seed Addition (Seed 첨가에 의한 Sr-Ferrite의 미세구조 제어)

  • 박준홍;신효순;이병교
    • Journal of the Korean Ceramic Society
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    • v.32 no.1
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    • pp.90-94
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    • 1995
  • In Sr-ferrite system, it has been attempted to inhibit the abnormal grian growth using Sr-ferrite powders synthesized by molten salt method as the matrix and the seeds, respectively. At each sintering temperature, the addition of seed more than 15% suppressed the abnormal grain growth, and the uniform microstructure resulted. Particularly, at 12$25^{\circ}C$, it was observed that the maximum number of the abnormal grain growth nuclei was achieved since the abnormal grain growth was suppressed even by the addition of 10% seed.

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First-principles study of the magnetic properties of the strontium hexaferrite $SrFe_{12}O_{19}$ (제일원리 계산을 이용한 스트론튬 페라이트의 자기적 특성 전산모사)

  • Yook, Young-Jin;Chung, Yong-Chae;Lee, Young-Jin;Im, Jong-In
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2006.11a
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    • pp.201-201
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    • 2006
  • 영구자석은 크게 Hard ferrite와 희토류계 자석, 그리고 Alnico 주조자석으로 구별되어진다. 그동안 Hard ferrite는 산업적으로 전자기 응용제품 또는 각종 구동 모터에 응용되어 왔지만, 최근 Nd계 희토류 자것이 고성능 모터의 소재로 급격히 대체되고 있다. 하지만, 희토류계 원료에 비해 동일 중량 대비 40~60배 가량 저렴한 Hard ferrite의 사용은 현재까지도 꾸준히 유지되고 있으며, 최근 자동차 고성능 모터용 Sr ferrite의 개발이 연구 중이다.[2] 본 연구에서는 제일원리 전산모사를 통하여 HCP 구조의 기본 Unit Cell 64개 원자를 가진 Sr-ferrite의 격자상수를 계산하여 기존 연구결과와 비교하였으며, 자화에너지와 자기모멘트를 계산하였다. 또한 향후 각종 첨가물의 영향에 대한 연구를 위해 기본 구조 및 치환 구조에 대해 고찰하였다. 그 결과 가장 안정한 에너지를 갖는 격자상수는 a=5.88, b=23.03으로 계산되어 Kimura et al의 측정 결과와 유사한 결과를 얻을 수 있었으며, $E_F$가 3.9171, $M_B$는 46.6481로 계산되었다. 항후 Sr-ferrite의 구조에서 Fe atom의 일부를 동일주기 원소인 Cr, Mn, Co, Ni, Cu로 치환하여 자기적 특성을 계산하여 본 연구결과와 비교하고자 한다.

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Mu7i-pole anisotropic Sr-ferrite sintered magnets fabricated by powder injection molding (분말사출성형으로 제조된 다극 이방성 SF-폐라이트 소결자석)

  • 조태식
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.11a
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    • pp.284-287
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    • 2001
  • Multi-pole anisotropic Sr-fertile sintered magnets has been studied by powder injection molding under applied magnetic field. The orientation of anisotropic Sr-ferrite powders higher than 80% during injection molding is achieved at the following conditions; apparent viscosity lower then 2500 poise in 1000 sec$\^$-1/ shear rate and applied magnetic field higher then 4 kOe. For the high fluidity and strength of injection molded compact, and the effective binder removal without defects during solvent extraction and thermal debinding, the optimum multi-binder composition is paraffin wax(PW)/carnauba wax(CW)/HDPE = 50/25/25 wt%. The rate of binder removal is proportional to the mean particle size of Sr-ferrite powders whereas it is inversely proportional to the content of Sr-ferrite powders and the sample thickness. The high magnetic properties of Sr-ferrite sintered magnets are; 3.8 kG of remanent flux density, 3.4 kOe of intrinsic coercivity, and 1.2 kG of surface flux density (1-mm-thick) in the direction of applied magnetic field.

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The Utilization of the steel converter dust (철강전노 dust의 활용에 관한 연구)

  • 김미성;김민석;김성원;오재현
    • Resources Recycling
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    • v.2 no.2
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    • pp.9-15
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    • 1993
  • In this study, magnetite($Fe_3$$O_4$) from the converter dust of the Kwangyang steel making factory has been recove-red by means of the magnetic separation and the sedimentation column. The magnetite recovered from the dust is used for the preparation of Sr-ferrite instead of hematite. The results obtained in this study as follows : 1. The converter EP dust of the Kwangyang steel making factory are composed of $\alpha$-Fe, ($Fe_3$$O_4$) wustite etc. Magnetite in the converter EP dust is recovered by using sedimentation column and plastic bonding magnet. 2. It was confirmed that Sr-ferrite synthesis could be possible without oxidizing roasting of the magnetite. The steps of Sr-ferrite formation are proposed as follows : I$SrCO_3$ $+Fe_3$O$_4$+1/2(1-X)$O_2$longrightarrow$\alpha$ $-Fe _2$$O_3$ $+SrFeO _3$\ulcorner+$CO_2$II. $5.5\alpha$ $-Fe_2$$O_3$ $+SrFeO_3$\ulcornerlongrightarrowSrFe\ulcornerO\ulcorner+1/2(1/2-X)$O_2$3. By using magnetite from the dust insted of hematite, the hard Sr-ferrite magnet of (B.H)\ulcorner=2.64MGOe in the magnetic characteristics was succesfully prepared.

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Characteristic of Iron Oxide and the Magnetic Properties of Sr-ferrite by Roasting Temperature of Iron Oxide (산화철 배소에 따른 분체 특성 및 Sr-ferrite 자석의 소결 특성)

  • Jang Se-Dong
    • Resources Recycling
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    • v.12 no.6
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    • pp.19-25
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    • 2003
  • This experiment was carried out to examine the effect of iron oxide roasting for Sr-ferrite magnet. Chloride content was decreased with raising the 2 nd roasting temperature of iron oxide for ruthner process iron oxide. The optimization temperature for roasting of ruthner process iron oxide was around $800^{\circ}C$ as average particle size 1.5∼1.9 $\mu\textrm{m}$, apparent bulk density 1.4 g/$m\ell$ and chloride content 0.05%. The relation between Br and HcJ by sintering temperature for Sr-ferrite magnet was found to be Br≒-0.258HcJ+494. In case of having a vibrating disk mill for the ruthner process iron oxide, the magnetic properties were Br 421 mT and HcJ 251 kA/m.

Development of the Magnetic Abrasive Using Sr-Ferrite and GC (Sr-Ferrite와 GC를 이용한 자기연마재 개발)

  • Yun, Yeo-Kwon;Kim, Sang-Baek;Kim, Hee-Nam
    • Journal of the Korean Society of Safety
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    • v.26 no.2
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    • pp.13-19
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    • 2011
  • The magnetic polishing is the useful method to finish using magnetic power of magnet. That method is one of precision polishing techniques and has an aim of the clean technology using for the pure of gas and inside of the clean pipe. The magnetic abrasive polishing method is not so common for machine that it is not spreaded widely. There are rarely researcher in this field because of non-effectiveness of magnetic abrasive. Therefore, in this paper deals with development of the magnetic abrasive using Sr-Ferrite. In this development, abrasive grain GC used to resin bond fabricated low temperature. And Sr-Ferrite of magnetic abrasive powder fabricated that Sr-Ferrite was crused into 200 mesh. The XRD analysis result show that only GC abrasive and Sr-Ferrite crystal peaks detected which explains resin bond was not any more chemical reaction. From SEM analysis it is found that GC abrasive and Sr-Ferrite were strong bonding with each other by bond. The magnetic polishing is performed by polishing the surface of pipe by attracting magnetic abrasives with magnetic fields. This can be widely applied for finishing machinery fabrications such as various pipes and for other safety processes. In this paper, we could have investigated in to the changes of the movement of magnetic abrasive grain. In reference to this result, we could have made the experiment which is set under the condition of the magnetic flux density, polishing velocity according to the form of magnetic brush.