• Title/Summary/Keyword: Sr 동위원소

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REE and Sr-Nd Isotopic Composition of the Shelf Sediments around Jeju Island, Korea (제주도 주변 대륙붕 퇴적물의 REE와 Sr-Nd 동위원소 조성)

  • Kim, Tae-Joung;Youn, Jeungsu
    • Journal of the Korean earth science society
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    • v.33 no.6
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    • pp.481-496
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    • 2012
  • REE, major and trace elements, and Sr-Nd isotopic ratios of surface sediments around Jeju Island were analyzed for identifying the origin of the sediments. The Chemical Index of Alteration (CIA) between 44.2 to 68.9 (av. 59.4) shows a similarity with the Huanghe sediment. The most sediments found within the study areas show a very similar chondrite-normalized REE pattern that has enriched LREE ($La_{(N)}/Sm_{(N)}$ >3) and small negative Eu anomaly, typically of average shales. The UCC-nornalized REE patterns of the southwestern offshore sediment samples show a very similar pattem with the Changjiang sediment with enriched in most REE and more convex REE pattern than those of the Huanghe and Keum rivers sediments, which indicates that the Changjiang River's suspended sediments have been transported into the western part of Jeju Island. The $^{87}Sr/^{86}Sr$ isotopic ratios vs ${\varepsilon}_{Nd}(0)$ values were thus used as a tracer to discriminate the provenance of sediments in the study area. Based on the discriminated diagram, it clearly showed that most sediments in the western and northwestern part were closely plotted with sediments of the Huanghe River. However, the sediments in the southwestern part near the Changjianf estuary were closely plotted with submerged delta sediments of the Changjiang River. In contrast, the sediment samples of the northeastern part showed discriminative figures from those of the Chinese rivers. It suggests that sediments around Jeju Island must be originated from diverse sources.

Rb-Sr Isotope Geochemistry in Seokmodo Granitoids and Hot Spring, Gangwha: An Application of Sr Isotope for Clarifying the Source of Hot Spring (강화 석모도 화강암류와 온천수의 지구화학: 온천수의 기원규명을 위한 Sr 동위원소의 응용)

  • Lee Seung-Gu;Kim Tong-Kwon;Lee Jin-Soo;Song Yoon-Ho
    • The Journal of the Petrological Society of Korea
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    • v.15 no.2 s.44
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    • pp.60-71
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    • 2006
  • The Seokmodo consists mainly of biotite granite and granodiorite. The biotite granite is divided into the south and the north part by granodiorite. There occurs high temperature hot spring of which temperature is up to $72^{\circ}C$. The Rb-Sr isotopic data for the biotite granite define whole-rock isochron ages of $207{\pm}70$ Ma with initial Sr isotopic ratio of 0.7132 in north part and $132{\pm}50$ Ma with initial Sr isotopic ratio of 0.7125 in south part, suggesting that the magma be derived from the crustal source material. The geochemical characteristics of the biotite granite and hornblende granodiorite indicate that they were crystallized from calc-alkaline under syn-collisional tectonic environment. The samples of hot spring were collected at March 2005 and March 2006. The $^{87}Sr/^{86}Sr$ ratios of hot spring are 0.714507 and 0.714518, respectively and correspond to those oi the granite being occurred at the south part. The similarity of $^{87}Sr/^{86}Sr$ ratios between the granite and hot spring strongly suggests that the hot spring might be derived from the Seokmodo biotite granite.

Geochemical Application for Clarifying the Source Material of the Earthenware: A Preliminary Study for Archaeological Application of Geochemical Tool (도토기의 태토(기원물질)산지를 추적하기 위한 지구화학적 응용연구: 지구화학연구기법의 고고학적 응용을 위한 기초연구)

  • Lee, Seung-Gu;Lee, Kil-Yong;Yoon, Yoon-Yeol;Yang, Myeong-Kwon;Kim, Kyu-Ho;Lee, Sung-Joo;Ahn, Sang-Doo
    • The Journal of the Petrological Society of Korea
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    • v.19 no.3
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    • pp.181-197
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    • 2010
  • This study is for finding a geoscientific factor for clarifying the source soil of the ancient earthenware finding. The used samples were the earthenware, soil and rocks, which were collected at the Gyeongju, Gyeongsan and Haman area. The chemical and mineralogical study for the samples were carried out for understanding the change of mineralogical and chemical composition among them. The mineralogical compositions of the earthenware are different from those of the soils from the surrounding area, which suggests that the mineralogical approach for clarifying the source soil of the earthenware should be difficult. Major element compositions of the earthenware also are different from those of the surrounding soils, which suggests that the comparison of the chemical composition using the major elements might be difficult for deducing the source soil of the earthenware. However, PAAS-normalized rare earth element (REE) patterns and Nd model ages among the rock, soils and earthenware from the same sampling sites show similar characteristics one another compared to those of the major element compositions. Nd-Sr isotopic systematics among the earthenware, soils and rocks also show a close relationship. Our results suggest that REE and Nd-Sr isotope geochemistry might be more useful than the other geochemical technique in clarifying the source soils of the ancient earthenware.

The Sr and Pb Isotopic and Geochemical Properties of the Atmospheric Bulk Deposition of Jeonju, Gunsan, and Namweon Areas (전주, 군산, 남원지역 강수의 Sr, Pb동위원소 지화학)

  • Jeon Seo-Ryeong;Chung Jae-il
    • Economic and Environmental Geology
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    • v.38 no.4 s.173
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    • pp.463-479
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    • 2005
  • The Sr and Pb isotopic ratios and chemical composition were measured for atmospheric bulk deposition samples collected in the Jeonju, Gunsan and Namweon areas over a period of one year. Acidity of deposition ranged pH $4\~7$ with little higher in dry season, and around pH 5.0 in rainy season. The EC and TDS of rainy season was low showing dilution effect, and increased during dry season. Sulfate $(SO_4)\;and\;NO_3$ are atmospheric aerosols largely of anthropogenic origin in winter. Sodium was concentrated in winter deposition, Ca was concentrated in spring to summer deposition. Namweon has lower EC and TDS than those of other, and Jeonju has higher. Namweon was concentrated in $HCO_3$ and Cunsan was concentrated in Cl. Aluminium, Cu, and Zn show good correlation index with TDS, indicating of their origin atmospheric. $^{87}Sr/^{86}Sr$ ratios of bulk deposition ranged from 0.7109 to 0.7128. The isotopic variations are correlated with mixing of isotopic compositions of local soils, road deposit and biogenic aerosol. In order to constrain further the origin of aerosols in rainwater, it will be necessary to collect additional Sr isotopic data for aerosols. Lead isotope ratios for all areas were similar and belonged to Pb isotope ratios of Seoul's aerosols, but little different with Beijing's aerosols. It showing that Pb in the Korea mainly derived from the gasoline combustion, not exclusively from the Beijing.

SHRIMP Zircon U-Pb Geochronology, Geochemistry and Sr-Nd Isotopic Study of the Cheongju granitoid rocks (청주 화강암의 SHRIMP 저어콘 U-Pb 연대, 지구화학 및 Sr-Nd 동위원소 연구)

  • Cheong, Won-Seok;Kim, Yoon-Sup;Na, Ki-Chang
    • The Journal of the Petrological Society of Korea
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    • v.20 no.4
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    • pp.191-206
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    • 2011
  • The emplacement ages, whole-rock geochemistry and Sr-Nd isotopic compositions of granitoid rocks from Cheongju area, South Korea, were investigated for delineating their petrogenetic link to the Jurassic Daebo granitoid rocks. Zircon crystals were collected from the diorite, biotite granite and acidic dyke samples in a single outcrop. Cross-cutting relationships show that the emplacement of diorite was postdated by the intrusion of biotite granite. Both rocks have been subsequently intruded by acidic dyke. The U-Pb isotopic compositions of zircon from the diorite, biotite granite, and acidic dyke were measured using a SHRIMP-II ion microprobe, yielding the crystallization ages of $174{\pm}2Ma$, $170{\pm}2Ma$, and $170{\pm}5Ma$, respectively, with 95% confidence limits ($t{\sigma}$). The emplacement ages are consistent with those determined from the above relative ages. The major and trace element patterns of the rocks are consistent with those of the Jurassic Daebo granitoid rocks, possibly suggesting a subduction-related I-type granite. The geochemical signature is, however, betrayed by the Sr and Nd isotopic compositions of these rocks. The isotopic signatures suggest that the rocks were produced either by the partial melting of lower-crust or by the mantle-derived magma contaminated by the basement rocks during its ascent and/or emplacement. In addition, the inherited ages of zircons of the rocks (ca. 2.1, 1.8, 0.8 and 0.4 Ga) suggest a possible assimilation with crustal rocks from the Gyeonggi massif and Ogcheon metamorphic belt.

AC Stark 이동이 선택적 공명 이온화에 미치는 영향

  • 남백일
    • Proceedings of the Optical Society of Korea Conference
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    • 1990.02a
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    • pp.145-149
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    • 1990
  • 선택적 2광자공명 3광자 이온화과정을 Li와 Sr의 동위원소들에 적용시켰을 때, 공명준위의 AC Track 이동으로 인하여 분리효율과 이온화율은 레이저 파장과 세기에 예민한 함수가 됨을 보이고 동위원소분리의 최적 조건을 검토하였다.

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Principles of Re-Os Isotopic System and Dating the Age of the Subcontinental Lithospheric Mantle Beneath Korean Peninsula (Re-Os 동위원소 시스템의 원리와 한반도 하부지각맨틀의 연령)

  • Lee Seung-Ryeol
    • The Journal of the Petrological Society of Korea
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    • v.15 no.2 s.44
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    • pp.106-117
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    • 2006
  • Re-Os isotopic system, based on the long-lived $\beta^-$ transition of $^{187}Os(\lambda=1.67\times10^{-11}year^{-1})$ is being widely used in cosmochemistry and geochemistry. Along with the development of elemental separation and mass-spectrometric technique, the Re-Os isotopic system, like Sm-Nd, Rb-Sr, U-Th-Pb isotopic system, is now conventionally applied as a useful tool for absolute dating and isotoptc tracers. This paper introduces brief principles of Re-Os isotopic system and presents the general methodology fur dating the formation age of the subcontinental lithospheric mantle, based on the Re-Os isotopic data of the mantle xeonliths from South Korea.

A Distinctive Chemical Composition of the Tektites from Thailand and Vietnam, and Its Geochemical Significance (타이와 베트남에서 수집된 텍타이트의 화학조성과 지구화학적 의의)

  • Lee, Seung-Gu;Tanaka, Tsuyoshi;Asahara, Yoshihiro;Minami, Masayo
    • The Journal of the Petrological Society of Korea
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    • v.26 no.3
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    • pp.281-295
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    • 2017
  • We determined chemical compositions like abundance of major and trace elements, Sr and Nd isotope compositions for two tektites from the Thailand and Vietnam. Their chemical compositions are similar to each other, and seem to be similar to those of PAAS (Post Archean Australian Shale) rather than upper continental crust. In particular, primitive mantle-normalized spider diagrams and chondrite-normalized REE patterns for two tektites are the same, suggesting that they might be derived from the same source material. The $^{87}Sr/^{86}Sr$ and $^{143}Nd/^{144}Nd$ ratios from Thailand tektite are $0.718870{\pm}0.000008(2{\sigma}_m)$ and $0.512024{\pm}0.000012(2{\sigma}_m)$, respectively, and those from Vietnam are $0.717022{\pm}0.000008(2{\sigma}_m)$ and $0.511986{\pm}0.000013(2{\sigma}_m)$, respectively. The $^{87}Sr/^{86}Sr$ and $^{143}Nd/^{144}Nd$ ratios from Thailand tektite are slightly enriched than those of Vietnam tektite. $^{87}Sr/^{86}Sr$ ratios from the Vietnam and Thai tektites were plotted on the range of Australasian tektites reported previously. $^{143}Nd/^{144}Nd$ ratio of Vietnam tektite from this study was lower than the range of $^{143}Nd/^{144}Nd$ ratio from the Australasian tektite reported previously whereas that of Thai tektite was included in the range of $^{143}Nd/^{144}Nd$ ratio from the Australasian tektite. The geochemical characteristics from two tektites in this study indicate that they may be derived from the very similar source materials.

Enriched Geochemical and Sr-Nd isotopic characteristics of Middle Triassic Plutonic Rocks in Hudongri, Chuncheon: Derivation from Enriched Mantle (춘천 후동리 일대에 분포하는 중기 트라이아스기 관입암의 부화된 지화학 및 Sr-Nd 동위원소 특성: 부화된 맨틀로부터 기원)

  • Park, Young-Rok
    • The Journal of the Petrological Society of Korea
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    • v.18 no.3
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    • pp.255-267
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    • 2009
  • The intrusive rocks in the Hudongri area, Chuncheon located in central Gyeonggi Massif consist of gabbroic diorite and diorite. K-Ar age of biotite separated from diorite sample records middle Triassic age of 228 Ma. The intrusives are characterized by enrichment of MgO, Ni and Cr as well as large ion lithophile elements such as Sa and Sr, which is indicative of derivation of magma from enriched mantle. The intrusives also have enriched Sr-Nd isotopic compositions, which appear to result from a long-term incompatible element enriched mantle source with an effect of crustal contamination. Occurrence of abundant hydrous minerals such as amphiboles and biotite rather than anhydrous minerals of pyroxene and olivine in mafic intrusive as well as being plotted in volcanic arc field in tectonic environment discrimination diagram indicate the mafic-intermediate intrusives in the Hudongri area, Chuncheon were derived from mantle material enriched by subduction.

Air Density Correction of Ionization Chamber using $^{90}Sr$ Radioactive Check Device ($^{90}Sr$ 방사성 동위원소를 이용한 전리함의 대기 보정계수 측정)

  • Park, Sung-Y.;Kim, Woo-C.;Shin, Dong-O.;Ji, Young-H.;Kwon, Soo-I.;Lee, Kil-D.;Cho, Young-K.;Loh, John-J.
    • Journal of Radiation Protection and Research
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    • v.23 no.4
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    • pp.267-271
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    • 1998
  • It is required to measure air density correction factor at the time of absorbed dose calibration or measurement. In general, thermometer and barometer are widely used for air density correction. However, this can be done using the radioactive check device with better accuracy. The measurements of air density correction were performed by using the radioactive check device, Unidos electrometer, and 0.6 cc Farmer-type ion chamber of PTW under the different environmental conditions. Above experiments were repeated with thermometer and barometer. By comparing the two methods, they were within the difference of 0.2 %. The overall uncertainty for the dose found in thermometer and barometer was 1.2 - 1.6 %, depending upon either one step or two, whereas the overall uncertainty for the radioactive check device was 1.02 %. This method may reduce the possible error which could occur when thermometer and barometer are not calibrated at regular basis.

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