• Journal of the Korean Ceramic Society
• /
• v.44 no.5 s.300
• /
• pp.148-150
• /
• 2007

A process to synthesize $La_{0.8}Sr_{0.2}CrO_3$ (LSC), which is a promising material for use as a separator in a soild oxide fuel cell, is investigated in this study. LSC powders without secondary Phases could be synthesized with ultrasonic spray pyrolysis and a heat treatment at $1200^{\circ}C$ for 20 h; however, it showed an average diameter of $0.6{\mu}m$ with a wide particle size distribution. On the other hand, LSC powders synthesized with spray pyrolysis at $800^{\circ}C$, heat-treated at $900^{\circ}C$ for 5 h, ball-milled and finally heat-treated again at $1200^{\circ}C$ for 20 h showed a smaller average diameter of $0.3{\mu}m$ and narrower size distribution. Very few particles above $0.5{\mu}m$ were found. Thus, a proper combination of the heat treatment and milling process after spray pyrolysis it determined to be very important in synthesizing fine and uniform LSC perovskite powders.

• Korean Journal of Materials Research
• /
• v.31 no.3
• /
• pp.172-180
• /
• 2021

In this study, using the plasma spray method, tensile and compression fatigue tests are performed in saline solution to examine the effect of Ti undercoat on corrosion fatigue behavior of alumina-coated specimens. The alumina-coated material using Ti in the undercoat shows better corrosion fatigue strength than the base material in the entire stress amplitude range. Fatigue cracking of UT specimens occurs in the recess formed by grit-blasting treatment and progresses toward the base metal. Subsequently, the undercoat is destroyed at a stage where the deformation of the undercoat cannot follow the crack opening displacement. The residual stress of the UT specimen has a tensile residual stress up to about 100 ㎛ below the surface of the base material; however, when the depth exceeds 100 ㎛, the residual stress becomes a compressive residual stress. In addition, the inside of the spray coating film is compressive residual stress, which contributes to improving the fatigue strength characteristics. A hardened layer due to grit-blasting treatment is formed near the surface of the UT specimen, contributing to the improvement of the fatigue strength characteristics. Since the natural potential of Ti spray coating film is slightly higher than that of the base material, it exhibits excellent corrosion resistance; however, when physiological saline intrudes, a galvanic battery is formed and the base material corrodes preferentially.

• Journal of the Korean Applied Science and Technology
• /
• v.33 no.4
• /
• pp.734-740
• /
• 2016

The micron-sized indium zinc tin oxide (IZTO) particles were prepared by spray pyrolysis from aqueous precursor solution for indium, zinc, and tin and organic additives such as citric acid (CA) and ethylene glycol (EG) were added to aqueous precursor solution for indium, zinc, and tin. The obtained IZTO particles prepared by spray pyrolysis from the aqueous solution without organic additives had spherical and filled morphologies, whereas the IZTO particles obtained with organic additives had more hollow and porous morphologies. The micron-sized IZTO particles with organic additives were changed fully to nano-sized IZTO particles, whereas the micron-sized IZTO particles without organic additives were not changed fully to nano-sized IZTO particle after post-treatment at $700^{\circ}C$ for 2 hours and wet-ball milling for 24 hours. Surface resistances of micron-sized IZTO's before post-heat treatment and wet-ball milling were much higher than those of nano-sized IZTO's after post-heat treatment and wet-ball milling. From IZTO with composition of 80 wt. % $In_2O_3$, 10 wt. % ZnO, and 10 wt. % $SnO_2$ which showed a smallest surface resistance IZTO after post-heat treatment and wet-ball milling, thin films were deposited on glass substrates by pulsed DC magnetron sputtering, and the electrical and optical properties were investigated.

• Proceedings of the Korean Society of Marine Engineers Conference
• /
• 2006.06a
• /
• pp.265-266
• /
• 2006

The chemical conversion coating formed on magnesium alloy investigated for low cost and harmless in environment by using the colloidal silica as the main component. The film formed in 298 K is thick, the film, which was thought combination of Si-O, was formed. The film formed in 313 K is thinner than that in 298 K. The quantity of film formed at high temperature such as 333 K and 353 K is smaller than dissolved quantity. At the anodic polarization experiment, corrosion resistance in sealing by hot water after chemical conversion treatment in basic solution condition get worse than that in comparison with basic solution condition. In salt spray test, the ratio of black rust on specimen that did not conducted chemical conversion treatment was five times or more compared with those of chemical conversion treated specimen. The film thickness of chemical conversion coating produced by alkali treatment process is thinner than in comparison with that of specimen produced in basic chemical conversion treatment solution condition. It is thought, however, that it showed good corrosion resistance during salt spray test because the area of microcracks is small.

• Journal of Korean Society of Water and Wastewater
• /
• v.8 no.3
• /
• pp.26-33
• /
• 1994

To slove the problems by the scum, which causes operational and water quality problems in water treatment plants, several researches were conducted based on the site investigations on twelve large water treatment plants, biological and chemical analysis of scum, analyzing raw water quality data. Two types of scum, which are from scum and floe scum, can be classified based on the analysis and site investigations. The major parameter generating floe scum was indicated as fine bubbles dissolved in the water. The fine bubbles dissolved in the water can be generated by over-saturated air in the water, adding aluminum surface as the coagulant, conducting the break point pre-chlorination and so on. The water spray method, which is one of the physical treatment methods for removing scum, was selected for conducting experiments on the removal efficiency in the flocculation basin of the real water treatment plant. The water spray method was successfully applied for removing scum with the advantages of using spiral nozzles in case of using the raw water rather than the cleaned water.

• Transactions of the Korean Society of Mechanical Engineers B
• /
• v.31 no.4
• /
• pp.335-340
• /
• 2007

A new correlation between the Nusselt number based on modified heat transfer coefficient and Reynold number based on droplet-flow-rate was developed for the experimental data. The modified heat transfer coefficient was defined as ratio of wall heat flux to droplet subcooling. In the previous reports, the local heat flux of spray cooling in the film boiling region was experimentally investigated for the water spray region of $D_{max} = 0.0007{\sim}0.03m^3/(m^2s)$ . In the region near the stagnation point of spray flow, a new heat transfer correlation is recommended which shows good predictions for the water spray region of $D_x{\le}0.01m^3/(m^2s)$.

• Journal of Bio-Environment Control
• /
• v.5 no.1
• /
• pp.50-56
• /
• 1996

This experiment was carried out to investigate the effects of new material, bioceramic powder in the nutrient solution(0.02%) and foliar spray(0.2%) on the growth and fruit quality of aeroponically grown tomato(Lycopersicon esculentum MILL. cv. Seokwang). Plant height was lowered, but root growth was increased both treatment of bioceramic powder into the nutrient solution and foliar spray. Cluster growth of tomato plants increased up to 14% over than that of control in the plot of foliar spray with bioceramic powder. Total plant dry weight also increased when bioceramic powder was treated both into the nutrient solution and foliar spray. T/R ratio was reduced by the treatment of bioceramic powder, but NAR and RGR showed the highest in the plot of foliar spray treated with 0.2% bioceramic powder than that of the other plots. Cumulative fruit fresh and dry weight were reduced when bioceramic powder was treated into nutrient solution but foliar spray produced more cumulative fruit fresh and dry weight than that of control. It was shown that treatment of bioceramic powder into the nutrient solution and foliar spray could be improved sugar degree without reducing fruit yields.

• Journal of Powder Materials
• /
• v.21 no.5
• /
• pp.349-354
• /
• 2014

This study is a basic research for repair material production which manufactured a Cu repair coating layer on the base material of a Cu plate using kinetic spray process. Furthermore, the manufactured material underwent an annealing heat treatment, and the changes of microstructure and macroscopic properties in the Cu repair coating layer and base material were examined. The powder feedstocks were sphere-shaped pure Cu powders with an average size of $27.7{\mu}m$. The produced repair coating material featured $600{\mu}m$ thickness and 0.8% porosity, and it had an identical ${\alpha}$-Cu single phase as the early powder. The produced Cu repair coating material and base material displayed extremely high adhesion characteristics that produced a boundary difficult to identify. Composition analysis confirmed that the impurities in the base material and repair coating material had no significant differences. Microstructure observation after a $500^{\circ}C/1hr$. heat treatment (vacuum condition) identified recovery, recrystallization and grain growth in the repair coating material and featured a more homogeneous microstructure. The hardness difference (${\Delta}H_v$) between the repair coating material and base material significantly reduced from 87 to 34 after undergoing heat treatment.

• Journal of Powder Materials
• /
• v.21 no.3
• /
• pp.229-234
• /
• 2014

This study manufactured a CIG-based composite coating layer utilizing a new warm spray process, and a mixed powder of Cu-20at.%Ga and Cu-20at.%In. In order to obtain the mixed powder with desired composition, the Cu-20at.%Ga and Cu-20at.%In powders were mixed with a 7:1 ratio. The mixed powder had an average particle size of $35.4{\mu}m$. Through the utilization of a warm spray process, a CIG-based composite coating layer of $180{\mu}m$ thickness could be manufactured on a pure Al matrix. To analyze the microstructure and phase, the warm sprayed coating layer underwent XRD, SEM/EDS and EMPA analyses. In addition, to improve the physical properties of the coating layer, an annealing heat treatment was conducted at temperatures of $200^{\circ}C$, $400^{\circ}C$ and $600^{\circ}C$ for 1 hour each. The microstructure analysis identified ${\alpha}$-Cu, $Cu_4In$ and $Cu_3Ga$ phases in the early mixed powder, while $Cu_4In$ disappeared, and additional $Cu_9In_4$ and $Cu_9Ga_4$ phases were identified in the warm sprayed coating layer. Porosity after annealing heat treatment reduced from 0.75% (warm sprayed coating layer) to 0.6% (after $600^{\circ}C/1hr$. heat treatment), and hardness reduced from 288 Hv to 190 Hv. No significant phase changes were found after annealing heat treatment.

• Transactions of the Korean Society of Mechanical Engineers B
• /
• v.29 no.2 s.233
• /
• pp.279-286
• /
• 2005

This study presents experimental results on the heat transfer coefficients in the film boiling region of spray cooling for actual metallurgical process. In this study, the heat flux distributions of a two dimensional dilute spray impinging on a hot plate were experimentally investigated. A stainless steel block was cooled down from intial temperature of about $800^{\circ}C$ by twin fluid (air-water) flat spray. It was found from the experimental results that the heat transfer area was classified into the stagnation region and wall-flow region. In the stagnation region, the experimental data of local heat transfer coefficient was closely correlated with the local droplet-flow-rate supplied from the spray nozzle directly. Thus, the local heat transfer coefficients are in good agreement with the predicted values from the correlations proposed by our previous study. In wall-flow region, however, remarkable differences are observed between experimental data and predicted values because the number of rebound droplets increase with increasing the distance from the stagnation point.