• Title/Summary/Keyword: Spray structure

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Thermal degradation properties of blue emitting phosphor particles prepared by the spray pyrolysis for PDP (분무열분해공정에서 제조된 PDP용 청색형광체의 열화특성)

  • Kang, Yun-Chan;Lee, Dong-Youl;Park, Hee-Dong
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.07b
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    • pp.1060-1062
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    • 2002
  • Spherical and dense BAM phosphor particles were prepared by spray pyrolysis. The key idea of dense BAM particles is to lead gelation in droplets, which was successfully achieved by using the aluminum polycation as the precursor solution for the spray pyrolysis. The BAM phosphor particles prepared by spraying the aluminum polycation solution have completely spherical shape and dense structure. When directly applied to make phosphor film on the glass by the screen-printing method, the prepared spherical BAM phosphor particles showed better packing density and surface morphology than that of commercial one, which has irregular shape and large particle size. It was also found that the thermal degradation in the photoluminescence intensity for dense and spherical BAM particles was less than that of commercial one.

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Application of Fluorescence/Scattering Technique to the Measurement of Spray Droplet Size in GDI Injector (직접 분사식 가솔린 인젝터 분무의 입경 측정에 형광/산란광법의 적용)

  • Kwak, Soo-Min;Ryu, Kyeong-Hun;Choi, Bong-Seok;Kim, Duck-Jool
    • Proceedings of the KSME Conference
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    • 2000.11b
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    • pp.353-358
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    • 2000
  • To achieve the requirement for high fuel economy and low emissions, the research for GDI engines is recently very brisk in the whole world. This study was performed to measure distribution of average particle size in non-evaporating spray. The 2-D fluorescence/scattering images of fuel spray were captured simultaneously by visualization system composed of a laser sheet, a doubling prism, optical filters, and an ICCD camera. Using the ratio of the two light intensities, particle size distribution was obtained. The SMD measured by fluorescence/scattering technique was compared with it obtained by PDA. The experimental results show that the spray structure of GDI injector and temporal SMD distribution.

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Spray pyrolysis synthesis of mesoporous TiO2 microspheres and their post modification for improved photocatalytic activity

  • Choi, Jaehyung;Yoo, Kye Sang;Kim, Jinsoo
    • Korean Journal of Chemical Engineering
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    • v.35 no.12
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    • pp.2480-2486
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    • 2018
  • Mesoporous $TiO_2$ microspheres were prepared by spray pyrolysis for photocatalysis. Post modification of $TiO_2$ by heat treatment was performed to optimize its photocatalytic performance. First, spherical $TiO_2$ particles with mesoporous structure were synthesized at pyrolysis temperatures of 500, 600, and $700^{\circ}C$. After characterization by XRD, SEM, and $N_2$ adsorption, a sample prepared at $500^{\circ}C$ was found to possess desirable properties for photocatalytic performance through post-modification. In methylene blue degradation, mesoporous $TiO_2$ microspheres synthesized at $500^{\circ}C$ outperformed other microspheres. Furthermore, samples obtained by spray pyrolysis at $500^{\circ}C$ were calcined at various temperatures as a post-modification process. The sample calcined at $350^{\circ}C$ showed improved photocatalytic activity due to optimal anatase crystallinity and surface area.

Transition of Gd2O3:Eu Phosphor to GdBO3:Eu Phosphor with Boron Concentration in the Spray Pyrolysis (분무열분해 공정에서 붕소 농도에 따른 Gd2O3:Eu 형광체의 GdBO3:Eu 형광체로의 전환)

  • Koo, Hye-Young;Jung, Dae-Soo;Ju, Seo-Hee;Hong, Seung-Kwon;Kang, Yun-Chan
    • Korean Journal of Materials Research
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    • v.16 no.3
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    • pp.163-167
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    • 2006
  • The transition of europium-doped gadolinium oxide phosphor to gadolinium borate phosphor with the concentration of boron in the spray pyrolysis was investigated. The particles prepared from spray solution below 10 wt% boric acid of prepared phosphor had crystal structure of $Gd_2O_3:Eu$ phosphor, in which the crystallinity of the particles decreased with increasing the boron concentration. A single phase $GdBO_3:Eu$ phosphor particles were prepared from spray solution above 50 wt% boric acid of prepared phosphor. The phosphor particles prepared from spray solution with 20 wt% boric acid of prepared phosphor had no XRD peaks of $Gd_2O_3:Eu$ and $GdBO_3:Eu$ Therefore the phosphor particles prepared from spray solution with 20 wt% boric acid of prepared phosphor had the lowest photoluminescence intensity under ultraviolet and vacuum ultraviolet. $GdBO_3:Eu$ and $Gd_2O_3:Eu$ phosphor particles prepared from spray solutions with proper concentrations of boric acid had good photoluminescence intensity under vacuum ultraviolet. The morphology of the phosphor particles were strongly affected by the concentrations of boric acid added into spray solution.

Performance Test Method on the Influence Waterproofing as Behavior of Concrete Structure (지하 콘크리트 구조물의 거동에 대한 방수층의 대응성 평가에 관한 실험적 연구)

  • Noh Jong-Soo;Kwon Shi-Won;Kwak Kyu-Sung;Kwon Kee-Joo;Oh Sang-Keun
    • Proceedings of the Korean Institute of Building Construction Conference
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    • v.y2004m10
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    • pp.77-81
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    • 2004
  • The massive structures are not free to move with vibration, differential settlement, thermal stresses because, construction and expansion joint, crack etc., can be large enough to cause leakage as deformation of waterproofing. It has been depended on the test method of tensile/tear strength which is waterproofing performance as behavior of concrete structure crack. However, not to practically confirm the creep applied to concrete surface, even waterproofing membrane have more performance than definite strength and elasticity. Therefore, in this study will focus on the test method to consider a resistance performance about loose adhesion and deformation of waterproofing and behavior of concrete structure as construction/expansion joint, crack. Performance test method on the influence as behavior of concrete structure crack is to choose waterproofing materials and construction method which possible to confront with behavior of 50mm crack in the atmosphere and low temperature. Examine the deformation of waterproofing membrane and loose adhesion which can occur to structure in general job site, suggest standard testing method to analyze correlation waterproofing membrane and structure with 5-types of materials used in this study, such as Adhesion membrane and sheet complex, sheet and urethane complex, self-adhesive sheet, spray poly-urea, spray membrane of rubberized Asphalt.

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An Experimental Study on the Bond Strength of the Metal Sprayed Coating According to the Shape and Size of the Attachment (어태치먼트의 형상 및 크기가 금속용사 방식피막의 부착강도에 미치는 영향에 관한 실험적 연구)

  • Park, Seungi-Gi;Park, Jin-Ho;Ryu, Hua-Sung;Lee, Han-Seung
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2016.05a
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    • pp.109-110
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    • 2016
  • The recent introduction of Metal spraying method apply to construction and civil steel structure is increasing. In applying the metal spraying lining process of construction and civil steel structure to secure the adhesion strength between the metal thermal spray coating and the steel structure and the highest priority requirements are required bond strength test reliable measurement accordingly. In this study, by calculating the deposition intensity and the standard deviation, coefficient of variation corresponding to the bonding area, unlike the shape of the attachment we compared the results.

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Analysis of Macroscopic Spray Characteristics of Diesel Injectors with Three Different Needle Driving Type in Common Rail Direct Injection System (3가지 니들구동방식별 CRDi 디젤엔진용 고압 인젝터의 거시적 분무특성 비교해석)

  • Lee, Jin-Wook;Min, Kyoung-Doug
    • Journal of Advanced Marine Engineering and Technology
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    • v.30 no.3
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    • pp.351-358
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    • 2006
  • The capability of high pressure injection with small fuel quantify at all engine operating conditions is one of the main feature in common rail fuel injection system, which is used in small and light-duty Diesel engine. The key parameter for the better atomized fuel sprays and multiple injections of this common rail fuel injection control, that can be freely selected irrespective of the engine speed and load is the mechanism controlling the needle energizing and movement in high pressure Diesel injector. In the electro-hydraulic injector, the injection nozzle is being opened and closed by movement of the injector's needle which is balanced by pressure between the nozzle seat and the needle control chamber. This study describes the macroscopic spray structure characteristics of the common rail Diesel injectors with different electric driving method i.e. the solenoid-driven and piezo-driven type. The macroscopic spray characteristics such as spray tip speed. spray tip penetration and spray cone angle were investigated by the high speed spray, which is measured by the back diffusion light illumination method with optical system for the high speed temporal photography in a constant volume chamber pressurized by nitrogen gas. As the results, the prototype piezo-driven injector system was designed and fabricated for the first time in domestic case and the effect of injector's needle response driven by different drive type was compared between the solenoid and piezo-driven injector It was found therefore. that the piezo-driven injector showed faster needle response and had better needle control capability by altering the electric input value than the solenoid-driven injector.

Characteristics of BaMgAl10O17:Eu Phosphor Powders Prepared from Spray Solution with Organic Additives and NH4Cl Flux (유기 첨가제 및 NH4Cl 융제를 함유하는 분무용액으로부터 합성된 BaMgAl10O17:Eu 형광체의 특성)

  • Lee, Sang Ho;Koo, Hye Young;Ko, Da Rae;Lee, Su Min;Kang, Yun Chan
    • Korean Chemical Engineering Research
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    • v.48 no.1
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    • pp.75-79
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    • 2010
  • The precursor powders with thin wall structure were prepared by spray pyrolysis from the spray solution with ethylenediaminetetraacetic acid, citric acid and $NH_4Cl$ flux. The $BaMgAl_{10}O_{17}:Eu$ phosphor powders formed from the spray solution without organic additives and flux material had sizes of $1{\sim}5{\mu}m$ and hollow structure with high thickness at post-treatment temperature of $1,200^{\circ}C$. However, $BaMgAl_{10}O_{17}:Eu$ phosphor powders formed from the spray solution with ethylenediaminetetraacetic acid, citric acid and $NH_4Cl$ flux had fine size and plate-like shape. The mean crystallite sizes of the phosphor powders with fine sizes were 23, 35, and 33 nm when the content of $NH_4Cl$ flux were 0, 6, 35 wt% of phosphor. The photoluminescence intensity of the phosphor powders formed from the spray solution with the optimum amount of $NH_4Cl$ flux as 35 wt% was 215% of that of the phosphor powders formed from the spray solution without flux material.

Spray Structures and Vaporizing Characteristics of a GDI Fuel Spray

  • Park, Dong-Seok;Park, Gyung-Min;Kim, Duck-Jool
    • Journal of Mechanical Science and Technology
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    • v.16 no.7
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    • pp.999-1008
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    • 2002
  • The spray structures and distribution characteristics of liquid and vapor phases in non-evaporating and evaporating Gasoline Direct Injection (GDI) fuel sprays were investigated using Laser Induced Exciplex Fluorescence (LIEF) technique. Dopants were 2% fluorobenzene and 9% DEMA (diethyl-methyl-amine) in 89% solution of hexane by volume. In order to study internal structure of the spray, droplet size and velocity under non-evaporating condition were measured by Phase Doppler Anemometry (PDA). Liquid and vapor phases were visualized at different moments after the start of injection. Experimental results showed that the spray could be divided into two regions by the fluorescence intensity of liquid phase: cone and mixing regions. Moreover, vortex flow of vapor phase was found in the mixing region. About 5㎛ diameter droplets were mostly distributed in the vortex flow region. Higher concentration of vapor phase due to vaporization of these droplets was distributed in this region. Particularly, higher concentration of vapor phase and lower one were balanced within the measurement area at 2ms after the start of injection.

A study on the structure of a diesel spray and the Improvement of the Injection System by the Exciplex Method (EXCIPLEX법에 의한 디젤분무의 구조와 분사계 개선에 관한 연구)

  • 김덕줄;차건종
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.19 no.9
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    • pp.2373-2385
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    • 1995
  • The goals of this study are to apply exciplex method to the visualization of the fuel spray of a diesel engine and to investigate the liquid phase of fuel spray that injected at the various tips of a fuel injector. This study provides the informations for the improvement of the diesel injection system and the structures of diesel spry with the boiling of fuel droplets in combustion chamber by the exciplex method. Hexame was used as fuel for approximation to injection condition of the engine. And naphthalene and TMDP were added to the fuel for the visualization by exciplex method. Experimental injectors were 4hole, 8hole, and 1hole impinging injectors. In the injection condition of actual engine the exciplex was sufficient to catch the liquid phase signal. The spray penetration of impinging injector was small than that of actual 4 and 8hole injector but atomization was better. The upper bound of impinging injector was determined by the geometry of a cylinder head and the lower bound was determined by spray angle. On impinging injector the atomization was better at the edge of disk than at center of disk and also the mixing with environmental gas was better.