• 제목/요약/키워드: Spray Structure

검색결과 429건 처리시간 0.021초

(Ba,Sr)$_2SiO_4:Eu^{2+}$ Phosphor Particles by Spray Pyrolysis Process

  • Kang, Hee-Sang;Kang, Yun-Chan;Park, Hee-Dong;Shul, Yong-Gun
    • 한국정보디스플레이학회:학술대회논문집
    • /
    • 한국정보디스플레이학회 2002년도 International Meeting on Information Display
    • /
    • pp.811-814
    • /
    • 2002
  • $(Ba,Sr)_2SiO_4:Eu^{2+}$ phosphor particles with high brightness were prepared by spray pyrolysis. The changes in the photoluminescence intensity and morphology of $(Ba,Sr)_2SiO_4:Eu^{2+}$ were investigated by changing the posttreatment temperature and the concentration of dopant. The prepared $(Ba,Sr)_2SiO_4:Eu^{2+}$ particles has a dense structure, but irregular shape after the posttreatment. When they were excited by the ultraviolet light of 410 nm, a broad emission band with a peak at 508 nm was observed. The photoluminescence intensity of the prepared $(Ba,Sr)_2SiO_4:Eu^{2+}$ particles was enhanced by increasing the posttreatment temperature up to 1300 $^{\circ}C$ and further improved by adding several rear-earth codopants. The $(Ba,Sr)_2SiO_4:Eu^{2+}$ particles prepared by spray pyrolysis had a good excitation spectrum in the wavelength longer than 350 nm. Therefore, it was concluded that the $(Ba,Sr)_2SiO_4:Eu^{2+}$ prepared by spray pyrolysis is a good green-emitting phosphor for LED application.

  • PDF

가스분무성형 Cu-5Ni-10Sn 합금의 미세조직 및 시효강화 (Microstructural Feature and Aging Characteristics of Spray-Formed Cu-5Ni-10Sn Alloy)

  • 노대균;강희수;백경호
    • 한국분말재료학회지
    • /
    • 제19권4호
    • /
    • pp.317-321
    • /
    • 2012
  • In this study, Cu-5Ni-10Sn(wt%) spinodal alloy was manufactured by gas atomization spray forming, and the microstructural features and mechanical properties of Cu-5Ni-10Sn alloy have been investigated during homogenization, cold working and age-hardening. The spray formed Cu-5Ni-10Sn alloy consisted of an equiaxed microstructure with a mixture of solid solution ${\alpha}$-(CuNiSn) grains and lamellar-structure grains. Homogenization at $800^{\circ}C$ and subsequent rapid quenching formed a uniform solid solution ${\alpha}$-(CuNiSn) phase. Direct aging at $350^{\circ}C$ from the homogenized Cu-5Ni-10Sn alloy promoted the precipitation of finely distributed ${\gamma}$' or ${\gamma}-(Cu,Ni)_3Sn$ phase throughout the matrix, resulting in a significant increase in microhardness and tensile strength. Cold working prior to aging was effective in strengthening Cu-5Ni-10Sn alloy, which gave rise to a maximum tensile strength of 1165 MPa. Subsequent aging treatment slightly reduced the tensile strength to 1000-1100 MPa due to annealing effects.

Application of Spray Pyrolysis Process for the Preparation of Nano Sized Cobalt Oxide Powder

  • Kim, Dong Hee;Seo, Dong Jun;Yu, Jae Keun
    • 한국재료학회지
    • /
    • 제24권1호
    • /
    • pp.25-32
    • /
    • 2014
  • In this study, nano-sized cobalt oxide powder with an average particle size below 50 nm was prepared from a cobalt chloride solution by the spray pyrolysis process. The influences of reaction temperature on the properties of the generated powder were examined. The average particle size of the particles formed based on the spray pyrolysis process at a reaction temperature of $700^{\circ}C$ is roughly 20 nm. Moreover, most of these particles cannot appear with an independent type, thereby coexisting in a droplet type. When the reaction temperature increases to $800^{\circ}C$, the average particle size not only increases to roughly 40 nm but also shows a more dense structure while the ratio of particles which shows a polygonal form significantly increases. As the reaction temperature increases to $900^{\circ}C$, the distribution of the particles is from roughly 70 nm to 100 nm, while most of the particle surface is more intricately close and forms a polygonal shape. When the reaction temperature increases to $1000^{\circ}C$, the particle size distribution of the powder shows an existing form from 80 nm to at least 150 nm in an uneven form. As the reaction temperature increases, the XRD peak intensity gradually increases, yet the specific surface area gradually decreases.

대형 고속 선박용 러더의 내침식, 부식 특성 향상을 위한 용사 코팅막 (Thermal Spray Coating Layer for Improvement of Erosion and Corrosion Resistance Applicable to Large Sized High Speed Ship's Rudder)

  • 이유송;허성현;김진홍;김여중;배일용;이명훈
    • 한국표면공학회:학술대회논문집
    • /
    • 한국표면공학회 2011년도 춘계학술대회 및 Fine pattern PCB 표면 처리 기술 워크샵
    • /
    • pp.196-197
    • /
    • 2011
  • Rudder, one of the most important component in the marine vessel, is now being decreased life time to serve due to cavitation erosion, vortex current, high flow speed suffer from ship speed going up dramatically. In this study, 10 kinds of thermal spray coating materials(2 of Zn alloy series, 3 of Al alloy series, 3 of Cu alloy series, 2 of STS alloy series) are chosen to apply on specimens and analyze micro structure, metallic composition, properties(porosity, oxidation) by using visual observation, XRD, EDX etc.. Additionally, to refine the characteristic of corrosion endurance for thermal spray coating layer, compared with thermal spray process and 5 kinds of heavy duty painting and AC paint (Anti-Corrosion Paint). Based on above mentioned experimental results, a priority of all coated specimens on corrosion-erosion endurances finalized and summarized there by desirable composition and process of thermal sprayed material properly.

  • PDF

초음파 분무 열분해법에 의한 산화물 환원 공정의 구형 Bi2Te3 분말 합성 (Spherical Bi2Te3 Powder Synthesized by Oxide-Reduction Process via Ultrasonic Spray Pyrolysis)

  • 송철한;장대환;진연호;공만식
    • 한국표면공학회지
    • /
    • 제50권2호
    • /
    • pp.114-118
    • /
    • 2017
  • Bismuth telluride ($Bi_2Te_3$) and its alloys are well-known thermoelectric materials for ambient temperature applications. In this study, the dissolved Bi-Te precursor solution was used to synthesis metallic $Bi_2Te_3$ powder via ultrasonic spray pyrolysis and reduction process. The droplets of the Bi-Te precursor solution were decomposed to Bi-Te oxide powders by ultrasonic spray pyrolysis. The spherical $Bi_2Te_3$ powders were synthesized by reduction reaction in atmosphere of hydrogen gas at the temperature above $375^{\circ}C$ for 6h. The reduced $Bi_2Te_3$ powders have a mean particle size of $1.5{\mu}m$. The crystal structure of the powder was evaluated by X-Ray diffraction(XRD), and the microstructure with size and shape powders was observed by fieldemission scanning electron microscope(FE-SEM) and transmission electron microscope(TEM).

Effect of Transparency of CNT counter electrodes on the Efficiency of DSSCs

  • Lee, Won-Jae;Ramasamy, Easwaramoorthi;Lee, Dong-Yun;Song, Jae-Sung
    • 한국전기전자재료학회:학술대회논문집
    • /
    • 한국전기전자재료학회 2005년도 하계학술대회 논문집 Vol.6
    • /
    • pp.615-616
    • /
    • 2005
  • Carbon Nanotubes (CNT) on flexible indium tin oxide (ITO) PET films were prepared for dye-sensitized solar cell (DSSC). These CNTs were prepared by spray coating method for various amount of light transparency. Also, Pt counter electrode was prepared by electro deposition method. All $TiO_2$ electrodes were deposited on ITO-PET films by spray coating method. Micro structural images show that CNT counter electrodes prepared by spray-coating have more dense structure with increasing spraying time (0 to 60 seconds). DSSC consisting of $TiO_2$ electrode and CNT counter electrode was fabricated with various amount of light absorption. DSSC have higher light energy conversion efficiency with increasing the thickness of CNT counter electrode. CNT counter electrode is at least compatible to that of CNT counter electrode.

  • PDF

콘크리트 표면 처리 방법 및 용사면에 따른 Zn-Al 금속 용사 피막의 물리적 특성 평가 (Evaluation of physical properties of Zn-Al metal spray coating according to concrete surface and treatment method)

  • 장종민;양현민;이한승
    • 한국건축시공학회:학술대회논문집
    • /
    • 한국건축시공학회 2022년도 봄 학술논문 발표대회
    • /
    • pp.59-60
    • /
    • 2022
  • When a metal sprayed film of several hundred ㎛ on the concrete surface is possible to 80 dB of shielding effect electromagnetic waves (ElectroMagnetic Pulse, EMP). Therefore, in this study, as a way to secure EMP shielding performance by applying a metal spray coating showing excellent EMP shielding performance to a concrete structure, the metal spray welding efficiency and thin film adhesion performance according to the concrete spray direction and surface treatment method were evaluated. Metal sprayed efficieny according to the metal spraying direction and method was confirmed that the difference was insignificant by applying the roughening agent. However, the method of strengthening the concrete surface and applying the sealing agent show maximum adhesion strength of 3.98 MPa compared to other methods, and it is judged that this method can be utilized for the metal spraying method for concrete EMP shielding.

  • PDF

분사각 및 분공 직경이 예혼합 압축착화 엔진 연소에 미치는 영향 (The Effect of Injection Angle and Nozzle Diameter on HCCI Combustion)

  • 국상훈;공장식;박세익;배충식;김장헌
    • 한국자동차공학회논문집
    • /
    • 제15권2호
    • /
    • pp.1-7
    • /
    • 2007
  • The effect of injector geometries including the injection angle and number of nozzle holes on homogeneous charge compression ignition (HCCI) engine combustion has been investigated in an automotive-size single-cylinder diesel engine. The HCCI engine has advantages of simultaneous reduction of PM and NOx emissions by achieving the spatially homogenous distribution of diesel fuel and air mixture, which results in no fuel-rich zones and low combustion temperature. To make homogeneous mixture in a direct-injection diesel engine, the fuel is injected at early timing. The early injection guarantees long ignition delay period resulting in long mixing period to form a homogeneous mixture. The wall-impingement of the diesel spray is a serious problem in this type of application. The impingement occurs due to the low in-cylinder density and temperature as the spray penetrates too deep into the combustion chamber. A hole-type injector (5 holes) with smaller angle ($100^{\circ}$) than the conventional one ($150^{\circ}$) was applied to resolve this problem. The multi-hole injector (14 holes) was also tested to maximize the atomization of diesel fuel. The macroscopic spray structure was visualized in a spray chamber, and the spray penetration was analyzed. Moreover, the effect of injector geometries on the power output and exhaust gases was tested in a single-cylinder diesel engine. Results showed that the small injection angle minimizes the wall-impingement of diesel fuel that results in high power output and low PM emission. The multi-hole injector could not decrease the spray penetration at low in-cylinder pressure and temperature, but still showed the advantages in atomization and premixing.

Water-Gel 모사 추진제의 충돌 분무 특성 연구 (Spray Characteristics of Water-Gel Propellant by Impinging Injector)

  • 황태진;이인철;김상선;구자예
    • 한국추진공학회:학술대회논문집
    • /
    • 한국추진공학회 2009년도 제33회 추계학술대회논문집
    • /
    • pp.11-14
    • /
    • 2009
  • 젤(gel) 추진제는 고체 및 액체 추진 시스템의 장점 중 높은 비추력, 저장성, 추력 제어, 비독성, 누설 방지와 같은 특성으로 고성능 추진 시스템에 활용되어 지능형 전략 미사일 또는 발사체의 부스터 및 여러 추진 시스템에 사용될 수 있다. 젤 모사 추진제는 물, Carbopol 941, NaOH 농축액을 혼합하여 제작되었으며, 물과 젤 모사 추진제를 충돌형 인젝터에서 분사시켜 분무 특성을 고찰하였다. 젤 모사 추진제의 충돌 분무에 의해 나타난 긴 액막(liquid sheet)은 강한 상호 분자력에 관련한 중합(polymeric)효과를 나타낸다. 물 분사와 비교했을 때 젤 모사 추진제의 미립화 억제와 난류 천이 지연에 관련된 높은 점도로 인하여 저조한 미립화 특성과 좁은 범위의 분무각을 나타내었다.

  • PDF

Urea-SCR시스템 액막형 선회분사기의 분사압력변화에 따른 무특성에 관한 연구 (Effect of injection pressure on the atomization characteristics of a liquid sheet-type swirl injector for Urea-SCR system)

  • 김덕진;양동욱;이지근
    • Journal of Advanced Marine Engineering and Technology
    • /
    • 제37권5호
    • /
    • pp.510-519
    • /
    • 2013
  • Urea-SCR시스템에 적용하기 위한 액막형 선회분사기의 분사압력변화에 따른 분무특성이 실험적으로 조사되었다. 실험에 사용된 노즐은 형상비 3.1을 갖는 단공 압력식 액막형 선회노즐이며, 노즐선단에 분사되는 유체에 선회류를 형성하기 위한 선회기가 설치되어 있다. 노즐의 분사량 조절은 PWM(pulse width modulation)기법에 의해 제어되었다. 분무의 발달과정은 2차원 PIV에 의해 가시화되었으며, 분무각 변화가 조사되었다. 분무액적의 속도 및 크기는 2차원 PDPA에 의해 상온 대기압 조건에서 측정되었다. 분무구조는 분사압력에 큰 영향을 받으며, SMD는 분사압력 증가에 따라 감소하며 선행연구자의 반실험적 결과와 유사한 경향을 보임을 알 수 있었다.