• 제목/요약/키워드: Spinning speed

검색결과 159건 처리시간 0.034초

시료의 회전 속도가 함철 비정질 규산염의 고상 NMR 신호에 미치는 영향 (Effect of Spinning Speed on 29Si and 27Al Solid-state MAS NMR Spectra for Iron-bearing Silicate Glasses)

  • 김효임;이성근
    • 한국광물학회지
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    • 제31권4호
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    • pp.295-306
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    • 2018
  • 고상 핵자기공명 분광분석은 비정질의 원자 구조를 제공하는 효과적인 방법론으로 다양한 비정질 규산염의 원자구조를 규명해왔다. 하지만, 함철 비정질 규산염의 경우, 철 함량 증가에 따른 신호의 변화가 상자성 효과와 구조 변동을 모두 반영하고 있기 때문에 분석에 많은 어려움이 있다. 이에 철 함량 증가에 따른 신호 변화가 실제 구조의 변동으로부터 기인한 것인지 확인하기 위해서는 온도변화에 따른 신호의 이동 여부를 관찰하는 것이 필수적이다. 본 연구에서는 철 함량에 따른 함철 비정질 규산염의 신호 변화를 해석하기 위하여 철이 포함된 휘석과 아노르다이트 조성의 비정질의 가변회전 속도 $^{29}Si$$^{27}Al$ NMR 실험을 수행하였다. 이는 온도 상승에 따른 신호의 변화 여부를 확인할 수 있게 하며, 쌍극자 효과에 관한 정보를 제공한다. 함철 휘석 비정질의 $^{29}Si$ NMR과 함철 아노르다이트 비정질의 $^{27}Al$ NMR 결과, 회전 속도 증가에도 불구하고 신호의 형태 및 위치가 달라지지 않았다. 회전 속도의 증가가 신호에 변화를 야기하지 않음을 확인한 본 결과는 철 함량 증가로 인한 신호의 변화가 상자성 이동 기원이 아니라, 철로부터 컷오프 반경 너머의 생존 신호임을 지시한다. 이에 철 함량 증가에 따라 아노르다이트 비정질의 Al 신호가 음의 화학적 차폐 방향으로 이동하는 현상은, 철의 진입에 따른 ${Q^4}_{Al}$(1 또는 2Si) 비율의 상대적 증가와 철과 ${Q^4}_{Al}$(3 또는 4Si) 구조간의 높은 공간적 근접도를 지시한다. 본 결과는 철 함량에 따른 규산염 비정질의 고상 NMR 신호 변화가 실제 구조적 변화를 지시하고 있음을 보여주며, 고상 NMR이 자연계에 존재하는 각종 유리질의 구조 분석에 효과적으로 적용될 수 있음을 제시한다.

마이크로 엑츄에이터용 형상기억 리본 제조 및 제특성 평가 (The Fabrication and Evaluation of SMA Ribbons for Micro Actuator Application)

  • 이영수;장우양
    • 제어로봇시스템학회:학술대회논문집
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    • 제어로봇시스템학회 2000년도 제15차 학술회의논문집
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    • pp.554-554
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    • 2000
  • To improve mechanical properties of Cu-Al-Ni alloy by the grain refinement, Cu-Al-Ni SMA ribbons were fabricated by melt spinning apparatus. The variations of microstructure, mechanical properties and transformation characteristics with the condition of rapid solidification and annealing time-temperature were investigated in Cu-Al-Ni SMA ribbons. The ribbons fabricated by melt spinning obtained around 1.5nm in width and 50-60${\mu}{\textrm}{m}$ in thickness. With increasing wheel speed in order of 10m/s, 15m/s, 20m/s, 30m/s and 3m/s, the grain size was decreased in order of 10${\mu}{\textrm}{m}$, 6.25${\mu}{\textrm}{m}$, 5.5${\mu}{\textrm}{m}$, 3${\mu}{\textrm}{m}$ and 3${\mu}{\textrm}{m}$. $M_{s}$ and $A_{s}$ temperature were decreased with decreasing grain size. By X-ray diffraction test, ordered $\beta$$_1$ phase was observed in all the SMA ribbons and the volume friction of it was increased with increasing wheel speed. With increasing wheel speed, strain was increased from 4.2% to 5.8% and fracture mode has changed from mixture of intergranular and dimple fracture to mixture of fiber structure and dimple fracture. The grain size of ribbon heat-treated at $600^{\circ}C$ was increased with increasing time. In the heat-treated ribbons at 55$0^{\circ}C$, ${\gamma}$$_2$ phases were observed.d.d.

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Computational Study on Unsteady Mechanism of Spinning Detonations

  • Matsuo, Akiko;Sugiyama, Yuta
    • 한국전산유체공학회:학술대회논문집
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    • 한국전산유체공학회 2008년도 학술대회
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    • pp.367-373
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    • 2008
  • Spinning detonations propagating in a circular tube were numerically investigated with a one-step irreversible reaction model governed by Arrhenius kinetics. Activation energy is used as parameter as 10, 20, 27 and 35, and the specific heat ratio and the heat release are fixed as 1.2 and 50. The time evolution of the simulation results was utilized to reveal the propagation mechanism of single-headed spinning detonation. The track angle of soot record on the tube wall was numerically reproduced with various levels of activation energy, and the simulated unique angle was the same as that of the previous reports. The maximum pressure histories of the shock front on the tube wall showed stable pitch at Ea=10, periodical unstable pitch at Ea=20 and 27 and unstable pitch consisting of stable, periodical unstable and weak modes at Ea=35, respectively. In the weak mode, there is no Mach leg on the shock front, where the pressure level is much lower than the other modes. The shock front shapes and the pressure profiles on the tube wall clarified the mechanisms of these stable and unstable modes. In the stable pitch at Ea=10, the maximum pressure history on the tube wall remained nearly constant, and the steady single Mach leg on the shock front rotated at a constant speed. The high and low frequency pressure oscillations appeared in the periodical unstable pitch at Ea=20 and 27 of the maximum pressure history. The high frequency was one cycle of a self-induced oscillation by generation and decay in complex Mach interaction due to the variation in intensity of the transverse wave behind the shock front. Eventually, sequential high frequency oscillations formed the low frequency behavior because the frequency behavior was not always the same for each cycle. In unstable pitch at Ea=35, there are stable, periodical unstable and weak modes in one cycle of the low frequency oscillation in the maximum pressure history, and the pressure amplitude of low frequency was much larger than the others. The pressure peak appeared after weak mode, and the stable, periodical unstable and weak modes were sequentially observed with pressure decay. A series of simulations of spinning detonations clarified that the unsteady mechanism behind the shock front depending on the activation energy.

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Computational Study on Unsteady Mechanism of Spinning Detonations

  • Matsuo, Akiko;Sugiyama, Yuta
    • 한국전산유체공학회:학술대회논문집
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    • 한국전산유체공학회 2008년 추계학술대회논문집
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    • pp.367-373
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    • 2008
  • Spinning detonations propagating in a circular tube were numerically investigated with a one-step irreversible reaction model governed by Arrhenius kinetics. Activation energy is used as parameter as 10, 20, 27 and 35, and the specific heat ratio and the heat release are fixed as 1.2 and 50. The time evolution of the simulation results was utilized to reveal the propagation mechanism of single-headed spinning detonation. The track angle of soot record on the tube wall was numerically reproduced with various levels of activation energy, and the simulated unique angle was the same as that of the previous reports. The maximum pressure histories of the shock front on the tube wall showed stable pitch at Ea=10, periodical unstable pitch at Ea=20 and 27 and unstable pitch consisting of stable, periodical unstable and weak modes at Ea=35, respectively. In the weak mode, there is no Mach leg on the shock front, where the pressure level is much lower than the other modes. The shock front shapes and the pressure profiles on the tube wall clarified the mechanisms of these stable and unstable modes. In the stable pitch at Ea=10, the maximum pressure history on the tube wall remained nearly constant, and the steady single Mach leg on the shock front rotated at a constant speed. The high and low frequency pressure oscillations appeared in the periodical unstable pitch at Ea=20 and 27 of the maximum pressure history. The high frequency was one cycle of a self-induced oscillation by generation and decay in complex Mach interaction due to the variation in intensity of the transverse wave behind the shock front. Eventually, sequential high frequency oscillations formed the low frequency behavior because the frequency behavior was not always the same for each cycle. In unstable pitch at Ea=35, there are stable, periodical unstable and weak modes in one cycle of the low frequency oscillation in the maximum pressure history, and the pressure amplitude of low frequency was much larger than the others. The pressure peak appeared after weak mode, and the stable, periodical unstable and weak modes were sequentially observed with pressure decay. A series of simulations of spinning detonations clarified that the unsteady mechanism behind the shock front depending on the activation energy.

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부정정 베어링-축계의 해석 및 볼베어링의 거동예측 (Analysis of Statically Indeterminate Bearing-Shaft System Prediction of the Behavior of Ball Bearing)

  • 김완두;한동철
    • Tribology and Lubricants
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    • 제10권1호
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    • pp.62-68
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    • 1994
  • The analysis of statically indeterminate bearing-shaft system was investigated. The moment loads and misalignment angles which were induced in the ball bearings were determined, and the influence of span length of this system on the moment loads and fatigue lives was identified. The sliding and spinning speeds between balls and raceways which affected the performance of ball bearing evaluated. The equation to estimate the cage speed of ball bearing under moment loads was proposed. This equation had been verified by the test results of measuring of cage speed, which was useful to the prediction of ball bearing under moment loads.

Poly(butylene Terephthalate) 섬유의 고속방사에 따른 섬유구조형성(I) - 복굴절률의 온라인 게측과 섬유구조성형 - (Formation of Fiber Structure During High-speed Spinning of Poly(butylene terephthalate)(I) - On-line Measurement of Birefringence and Formation of Fiber Structure -)

  • 김경효;조현혹;일본명
    • 한국섬유공학회:학술대회논문집
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    • 한국섬유공학회 2000년도 봄 한국섬유공학회 학술발표회 논문집(Proceedings of the Korean Textile Conference)
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    • pp.61-64
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    • 2000
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Influence of "Historical Effects" on the Rheological Properties of a Polyacrylonitrile Copolymer Solution

  • Cheng, Yumin;Zhang, Huibo;Zhang, Shuangkun;Liu, Weiwei;Wang, Jing;Cheng, Run;Ryu, SeungKon;Jin, Riguang
    • Carbon letters
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    • 제14권1호
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    • pp.45-50
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    • 2013
  • Polyacrylonitrile (PAN) copolymers of different molecular weights were synthesized by a suspension polymerization and precipitation polymerization method. The rheology behaviors of the synthesized PAN copolymers were investigated in relation to their molecular weight, solid content and melting temperature. The influence of "historical effects" on the spinning solution of PAN was studied by analyzing the laws of viscosity considering the diversification time and temperature. The viscosity disciplines of each spinning solution conformed well to the rheological universal laws in a comparison of the suspension polymerization product with that of precipitation polymerization. Viscosity changes in the swelling process of dissolution were gentler in the suspension polymerization product; a small amount of water will quickly debase the solution viscosity, and high-speed mixing can greatly shorten the time required by the spinning solution to reach the final viscosity.

지지구조와 헤드-서스펜션-액츄에이터의 유연성을 고려한 HDD 유연 회전 디스크-스핀들 시스템의 유한 요소 고유 진동 해석 (Finite Element Modal Analysis of a Spinning Flexible Disk-Spindle System Considering the Flexibility of Supporting Structures and an Head-Suspension-Actuator in a HDD)

  • 서찬희;이호성;장건희
    • 한국소음진동공학회:학술대회논문집
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    • 한국소음진동공학회 2006년도 추계학술대회논문집
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    • pp.128-135
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    • 2006
  • This paper presents a finite element method to analyze the free vibration of a flexible HDD composed of the spinning disk-spindle system with fluid dynamic bearings(FDBs), the head-suspension-actuator with pivot bearings, and the base plate with complicated geometry. Experimental modal testing shows that the proposed method well predicts tue vibration characteristics of a HDD. This research also shows that even the vibration motion of the spinning disk corresponding to half-speed whirl and the pure disk mode are transferred to a head-suspension-actuator and base plate through the air bearing and the pivot bearing consecutively. The proposed method can be effectively extended to investigate the forced vibration of a HDD and to design a robust HDD against shock.

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