• 공업화학
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• 제10권7호
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• pp.1020-1027
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• 1999

헤테로폴리산(HPW)을 표면적이 서로 다른 담체인 $SiO_2$ MCM-41, MCM-48에 담지농도와 소성온도를 달리하며 담지시켰다. X-선 회절분석, 질소 흡착법, 적외선 흡수 스펙트럼, $^{31}P$ 고체 핵자기 공명을 통해서 이 담지촉매의 특성을 조사하였다. IR과 NMR의 결과로부터 HPW가 담체안에서 케긴 구조를 유지하면서 존재함을 확인할 수 있었다. MCM-41의 경우에는 35 wt %, MCM-48의 경우에는 65 wt %로 담지시킨 경우에도 X-선 회절패턴에서 HPW 고유의 피크가 나타나지 않았으며, 이와 같은 특성을 통해서 HPW가 고분산 되어 있음을 알 수 있었다. Di, bis, tri-pentaerythritol의 가수분해 반응에서 이들 담지 촉매는 높은 촉매 활성을 보였으며 HPW, $HPW/SiO_2$보다 HPW/MCM-41, 48의 촉매 활성이 더 우수하였다.

• 한국학교수학회논문집
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• 제2권1호
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• pp.55-66
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• 1999

In mathematics education, teaching-learning activity can be divided largely into the understanding the mathematical concepts, derivation of principles and laws acquirement of the mathematical abilities. We utilize various media, teaching tools, audio-visual materials, manufacturing materials for understanding mathematical concepts. But sometimes we cannot define or explain correctly the concepts as well as the derivation of principles and laws by these materials. In order to solve the problem we can use the computer. In this paper, ′the process of the length of curve being equal to the sum of the vectors when intervals get smaller′ and ′the process of calculating volume of spinning curve by using definite integral.′ Using the computers is more visible than other educational instruments like blackboards, O.H.Ps., etc. Also it can help students with solving mathematical problems intuitively. Consequently more effective teaching-learning activity can be done. Usage of computers is the best method for improving the mathematical abilities because computers have functions of the immediate reaction, operation, reference and deduction. One of the important characters of mathematics is accuracy, so we use computers for improving mathematical abilities. This paper is about the program focused on the part of "the application of definite integral", which exists in mathematical curriculum the second and third grade of high school. When this study is used for students as assisting materials, it is expected the following educational effect. 1. Students will have precise concepts because they can understand what they learn intuitively. 2. Students will have positive thought by arousing interests of learning because this program is composed of pictures, animations with effectiveness of sound. 3. It is possible to change the teacher-centered instruction into the student-centered instruction. 4. Students will understand the relation between velocity and distance correctly because they can see the process of getting the length of curve by vector through the monitor. For the purpose of increasing the efficiencies and qualities of mathematics education, we have to seek the various learning-teaching methods. But considering that no computer can replace the teacher′s role, teachers have to use the CIA program carefully.

• 대한기계학회논문집A
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• 제35권10호
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• pp.1211-1222
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• 2011

일반적으로 회전체나 초기 하중 하의 구조물 또는 열변형된 파이프 등의 프리스트레스 구조물은 이러한 프리스트레스 효과로 인하여 고유진동수 및 고유진동모드가 변화되기 때문에 정확한 고유진동해석을 위해서는 프리스트레스 고유진동해석을 수행해야 한다. 시스템에 따라서는 그 복잡성으로 인하여 수십만~수백만의 큰 자유도를 갖는 대형 유한요소모델이 요구되어 이러한 대형 모델의 프리스트레스 영향을 파악하기 위한 프리스트레스 고유진동해석을 주어진 설계시간 내에 반복적으로 수행하기에는 여전히 시간적 어려움이 많은 형편이다. 따라서, 본 논문에서는 크리로프 부공간에 근거한 축소기법으로 시스템의 초기 유한요소모델에 대하여 고유진동 특성을 정확하게 나타내면서도 작은 차수의 축소모델로 표현하여 프리스트레스 고유진동해석에서의 계산시간 문제를 감소하였다. 초기 시스템과 축소 시스템의 모멘트를 일치하는 수치계산에는 아놀디 과정을 이용하였다. 적용예제로 휠과 컴프레서 임펠러를 선택하여 제안한 방법을 통한 회전에 따른 프리스트레스 고유진동해석의 정확성과 효율성을 보였다.

• Journal of Magnetics
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• 제9권4호
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• pp.101-104
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• 2004

The crystallization behaviours of nanocomposite made by a function of quenching rate (roller speed) were studied. The results showed that there was one step c$\mathbb{r}$ystallization process for the alloy quenched at roller speed of 32 m/s, which could be shown as, Am (amorphouse) + ${\alpha}-Fe/Nd_2Fe_{14}B$ ${\rightarrow}$ ${\alpha}-Fe/Nd_2Fe_{14}B$ . For the alloy quenched at roller speed of 40 m/s, there was steps crystallization process taking place at different temperatures, which could be shown as, Am ${\rightarrow}$ ${\alpha}-Fe/Nd_2Fe_{23}B_3+Nd_2Fe_{14}B+Am`$ ${\rightarrow}$ ${\alpha}-Fe/Nd_2Fe_{14}B$. The presence of transition phase ($Nd_2Fe_{23}B_3$) was harmful to get fine and uniform grain size during crystallization process. Uniform microstructures and high magnetic properties could be attained for the as-quenched alloy containing less amorphous phase and no presence of transition phase during annealing treatment. For the alloy prepared at roller speed of 32 m/s, the following properties were obtained, $B_r= 0.904 T,_iH_c = 801 kA/m, (BH)_{max} = 122 kJ/m^3 and M_r/M_s = 0.6$.

• 폴리머
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• 제30권2호
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• pp.175-181
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• 2006

본 연구에서는 폴리프로필렌을 소재로 열유도 상분리 공정과 연신공정을 적용한 복합공정을 통하여 중공사막을 제조하였다. 희석제로는 soybean oil을 사용하였고 구정의 조절을 위하여 benzoic acid를 기핵제로 사용하여 연신용 전구체를 제조하였고 이를 연신하여 다공성 중공사막을 제조하였다. 연신공정에서 연신율과 변형속도의 영향을 조사하였는데 연신율이 높을 때는 미세공의 크기가 커지면서 불균일한 미세공이 생성되었고 변형속도가 높을 때는 균일한 크기의 미세공 분포도를 보이며 미세공의 크기가 커졌다. 연신율이 증가할수록 고분자 사슬의 배향도가 높아지면서 인장강도가 향상되었고 변형속도가 높아지면서 결정성 영역의 고분자 사슬의 배향도는 변하지 않았으나, 무정형 영역의 고분자 사슬 배향도가 낮아지면서 전체적인 중공사막의 인장강도는 저하되었으며 상대적으로 약한 spherulite를 연결하는 micro-fibril이 끊어지면서 미세공의 병합이 이루어져 원형의 기공이 형성되었다.

• 한국분말야금학회:학술대회논문집
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• 한국분말야금학회 2006년도 Extended Abstracts of 2006 POWDER METALLURGY World Congress Part2
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• pp.936-936
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• 2006

Bulk amorphous materials have been intensively studied to apply for various advanced industry fields due to their high mechanical, chemical and electrical properties. These materials have been produced by several techniques such as mechanical alloying, melt spinning and gas atomization, etc. Among them, the atomization is the most potential technique for commercialization due to high cooling rate during solidification of the melt and mass productivity. However, the amorphous powders still have some limitations because of their low ductility and toughness. Therefore, intensive efforts have to be carried out to increase the ductility and toughness. In this study, the Ni-based amorphous powder was produced by the gas atomization process. And in order to increase the ductile toughness, ductile Cu phase was coated on the Ni amorphous powder by spray drying process. The characteristics of the as-synthesis powders have been examined and briefly mentioned. The master alloy with $Ni_{57}Zr_{20}Ti_{16}Si_2Sn_3$ was prepared by vacuum induction melting furnace with graphite crucible and mold. The atomization was conducted at $1450^{\circ}C$ under the vacuum of $10^{-2}$ torr. The gas pressure during atomization was varied from 35 to 50 bars. After making the Ni amorphous powders, the spray drying was processed to produce the Cu -coated Ni amorphous composite powder. The amorphous powder and Cu nitrate solution were mixed together with a small amount of binder and then it was sprayed at temperature of $130^{\circ}C$ and rotating speed of 15,000 R.P.M.

• 대한전기학회:학술대회논문집
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• 대한전기학회 1998년도 하계학술대회 논문집 G
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• pp.2541-2543
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• 1998

This paper describes the fabrication process to fabricate metallic structure of high aspect ratio using LlGA-like process. SU-8 is used as an electroplating mold. SU-8 is an epoxy-based photoresist, designed for ultrathick PR structure with single layer coating [1,2]. We can get more than $100{\mu}m$ thick layer by single coating with conventional spin coater, and applying multiple coating can make thicker layers. In the experiments, we used different kinds of SU-8, having different viscosity. To optimize the conditions for mold fabrication process, experiments are performed varying spinning time and speed, soft-bake, develop and PEB (Post Expose Bake) condition. With the optimized condition, minimum line and space of $3{\mu}m$ pattern with a thickness of $40{\mu}m$ and $4{\mu}m$ pattern with a thickness of $130{\mu}m$ were obtained. Using the patterned PR as a plating mold, metallic structure was fabricated by electroplating. We have fabricated a electroplated nickel comb actuator using SU-8 as plating mold. The thickness of PR mold is $45{\mu}m$ and that of plated nickel is$40{\mu}m$. Minimum line of the mold is $5{\mu}m$. Patterned metallic layer or polymer layer, which has selectivity with the structural plated metallic layer, can be used as sacrificial layer for fabrication of free-standing structure.

• Animal cells and systems
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• 제2권1호
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• pp.145-152
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• 1998

The spinning apparatus and production of secretory silk from silk gland of the black widow spider, Latrodectus mactans were studied with scanning and transmission electron microscopes. The silk glands were located in seven groups on the spinnerets including each pair of major and minor ampullate, 3 pairs of tubuliform, 1 pair of flagelliform, 2 pairs of aggregate, about 50 pairs of pyriform and over 250 pairs of aciniform glands, respect- ively. Each group of silk gland feeds silk into one of the three spinneret pairs. Secretory silk is synthesized from rough endoplasmic reticulum (rER) of glandular epithelial cells. The secretory silk is transported from toe rER into the secretory vacuoles which are grown up by fusion with the surrounding small vesicles including the secretory silk. The secretory vacuoles, which show a gradual increase in electron density with the process of maturity, are formed without involvement of the Golgi complex, suggesting that they do not play an important role in the processing of the secretory silk. The secretory silk products are released by the mechanism of apocrine secretion, losing part of their cytoplasm. Moreover, another type of silk precursor, possibly protein, appears as granular material, and is also discharged to the luminal cavity.

• 한국재료학회지
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• 제21권2호
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• pp.125-132
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• 2011

Fibrous chitosan membranes were fabricated as a substrate for skin applications using an electro-spinning process with different solvents and varying concentrations. Scanning electron microscopy (SEM) images confirmed that the formation of the chitosan fibrous membrane in trifluoroacetic acid was better than that in acetic acid. Fourier transform infrared spectroscopy showed that the chitosan fibers were cross-linked with glutaraldehyde, and that the cytotoxicity of the aldehyde groups was reduced by glycine and washing by NaOH and DI water. Chitosan cross-linked fibrous membranes were insoluble in water and could be washed thoroughly to wash away glycine and excess NaOH and prevent the infiltration of other water soluble bio-toxic agents using DI water. MTT assay method was employed to test the cytotoxicity of chitosan membranes during fabricating, treating and washing processes. After the dehydration of cell cultured chitosan membranes, cell attachment behavior on the material was evaluated using SEM method. Effect of the treatment processes on the biocompatibility of the chitosan membranes was shown by comparing of filopodium and lamellipodium of fibroblast cells on grown washed and unwashed chitosan fibrous membrane. The MTT assay and SEM morphology confirmed that the washed chitosan fibrous membrane increased cell attachment and cell growth, and decreased toxicity compared to results for the unwashed chitosan fibrous membrane.

• 한국염색가공학회지
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• 제17권4호
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• pp.7-14
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• 2005

The purpose of this study was to develop the color matching program with the excellent camouflage capacity in the near infrared range($\~$1100nm) including the visible light range for cotton fabrics. It was measured IR spectral reflectance in the range of $380\~1,100nm$ after dyed with vat dyes, and we made database for reflectance with various concentration on vat dyes which have a low reflectance value in the infrared range. The color matching algorithm that could be simulated in both the human visible light and the near infrared range was constructed by numerical analysis method using the database. In this study we also developed the dyeing conditions and dyeing process through the continuous-dyeing experiment with the vat dyes for cotton fabrics.