• 제목/요약/키워드: Spin on-Glass

검색결과 208건 처리시간 0.029초

스핀코팅으로 금속물질을 도핑한 TiO2박막의 광학적 특성 (Optical properties of metal doped TiO2 thin films prepared by spin coating-pyrolysis process)

  • 황규석;김재민;정주현
    • 한국안광학회지
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    • 제12권1호
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    • pp.17-22
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    • 2007
  • Ti-나프텐산염과 금속을 출발원료로 사용하고, 스핀코팅-열분해법을 이용하여 실리카 유리위에 박막을 제조하였다. 도포된 박막은 $500^{\circ}C$ 공기에서 10min동안 열처리하였다. 이를 5회 코팅한 박막은 마지막으로 공기에서 $600^{\circ}C$에서 30min으로 하였다. 박막의 특성을 분석하기 위하여 X-선 회절 분석, 전자현미경, UV스펙트럼을 이용하여 분석하였다. 밴드갭에서 가장 큰 장파장 쪽으로 이동은 Fe을 도핑한 $TiO_2$ 박막이었다.

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스핀코팅법으로 제작한 산화구리 박막의 일산화질소 가스 감지 특성 (Nitrogen Monoxide Gas Sensing Properties of Copper Oxide Thin Films Fabricated by a Spin Coating Method)

  • 황현정;김효진;김도진
    • 한국재료학회지
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    • 제25권4호
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    • pp.171-176
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    • 2015
  • We present the detection characteristics of nitrogen monoxide(NO) gas using p-type copper oxide(CuO) thin film gas sensors. The CuO thin films were fabricated on glass substrates by a sol-gel spin coating method using copper acetate hydrate and diethanolamine as precursors. Structural characterizations revealed that we prepared the pure CuO thin films having a monoclinic crystalline structure without any obvious formation of secondary phase. It was found from the NO gas sensing measurements that the p-type CuO thin film gas sensors exhibited a maximum sensitivity to NO gas in dry air at an operating temperature as low as $100^{\circ}C$. Additionally, these CuO thin film gas sensors were found to show reversible and reliable electrical response to NO gas in a range of operating temperatures from $60^{\circ}C$ to $200^{\circ}C$. It is supposed from these results that the p-type oxide semiconductor CuO thin film could have significant potential for use in future gas sensors and other oxide electronics applications using oxide p-n heterojunction structures.

THE LOW TEMPERATURE DEPENDENCE OF MAGNETIZATION AND AC SUSCEPTIBILITY OF GLASSY $Fe_{91-x}Zr_{7}B_{2}Ni_{x}$ (x=0,5,10,15) ALLOYS

  • Strom, V.;Kim, K.S.;Jonsson, B.J.;Yu, S.C.;Inoue, A.;Rao, K.V.
    • 한국자기학회지
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    • 제5권5호
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    • pp.515-518
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    • 1995
  • We have studied the magnetization in fields up to 1T at 5K, the saturation magnetization dependence on temperature and the temperature dependence of AC-susceptibility at very low fields (5mOe to 50mOe) of glassy $Fe_{91-x}Zr_{7}B_{2}Ni_{x}$ (x = 0, 5, 10, 15) alloys. The temperature dependence of the magnetization follows the predictions of spin wave excitations with long wavelengths. At zero Ni concentration there is a clear competition between ferromagnetic and antiferromagnetic interactions giving rise to spin-glass behaviour. The addition of Ni drastically modifies the magnetic properties: the antiferromagnetic exchange coupling is reduced and finally disappears, the spin wave stiffness increases from 39.5 to $87.3\;meV{\AA}^{2}$ and To increases from 230 K to 478 K. We develop a simple model to quantify the competing interactions and to relate the antiferromagnetically coupled Fe moments to the Ni concentration. We find that the initial susceptibility increases with increasing Ni content along with a decrease of the temperature dependence.

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Synthesis and Properties of Carbon Nanotube Paste with Different Inorganic Binders for Field Emission Display

  • Park, Jae-Hong;Moon, Jin-San;Nam, Joong-Woo;Park, Jong-Hwan;Berdinsky, A.S.;Yoo, Ji-Beom;Lee, C.G.;Park, Chong-Yun
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2004년도 Asia Display / IMID 04
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    • pp.468-470
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    • 2004
  • CNT pastes with different inorganic binder such as glass frit and spin on glass (SOG) were synthesized by using multi-walled nanotube (MWNT) grown by CVD. The uniformity of cathode layer after firing was enhanced and the emission current density at an applied field of 7.95V/${\mu}m$ increased from 133${\mu}A$/$cm^2$ to 265${\mu}A$/$cm^2$ when inorganic binder changed from glass frit to SOG. The emission properties of CNT pastes with SOG were stable and uniform although firing was carried out at relatively high temperature of 450$^{\circ}C$ under air. It is concluded that SOG is more suitable inorganic binder than glass frit for field emission application.

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Unfolded Histidine-Tagged Protein is Immobilized to Nitrilotriacetic Acid-Nickel Beads, But Not the Nickel-Coated Glass Slide

  • Cho Min-Ho;Ahn Sun-Young;Park Heon-Yong
    • Genomics & Informatics
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    • 제4권3호
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    • pp.133-136
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    • 2006
  • The adsorption of proteins on the surface of glass slides is essential for construction of protein chips. Previously, we prepared a nickel-coated plate by the spin-coating method for immobilization of His-tagged proteins. In order to know whether the structural factor is responsible for the immobilization of His-tagged proteins to the nickel-coated glass slide, we executed a series of experiments. First we purified a His-tagged protein after expressing the vector in E. coli BL21 (DE3). Then we obtained the unfolding curve for the His-tagged protein by using guanidine hydrochloride. Fractions unfolded were monitored by internal fluorescence spectroscopy. The ${\Delta}G_{H20}$ for unfolding was $2.27kcal/mol{/pm}0.52$. Then we tested if unfolded His-tagged proteins can be adsorbed to the nickel-coated plate, comparing with $Ni^{2+}-NTA$ (nitrilotriacetic acid) beads. Whereas unfolded His-tagged proteins were adsorbed to $Ni^{2+}-NTA$ beads, they did not bind to the nickel-coated plate. In conclusion, a structural factor is likely to be an important factor for constructing the protein chips, when His-tagged proteins will immobilize to the nickel-coated slides.

Strain induced/enhanced ferromagnetism in $Mn_3Ge_2$thinfilms

  • ;;;신유리미;조성래
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2009년도 제38회 동계학술대회 초록집
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    • pp.135-135
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    • 2010
  • In Mn-Ge equilibrium phase diagram, many Mn-Ge intermetallic phases can be formed with difference structures and magnetic properties. The MnGe has the cubic structure and antiferromagnetic(AFM) with Neel temperature of 197 K. The calculation predicted that the $MnGe_2$ with $Al_2Cu$-type is hard to separate between the paramagnetic(PM) states and the AFM states because this compound displays PM and AFM configuration swith similar energy. Mn-doped Ge showed the FM with Currie temperature of 285 K for bulk samples and 116 K for thin films. In addition, the $Mn_5Ge_3$ compound has hexagonal structure and FM with Curie temperature around 296K. The $Mn_{11}Ge_8$ compound has the orthorhombic structure and Tc is low at 274 K and spin flopping transition is near to 140 K. While the bulk $Mn_3Ge_2$ exhibited tetragonal structure ($a=5.745{\AA}$;$c=13.89{\AA}$) with the FM near to 300K and AFM below 150K. However, amorphous $Mn_3Ge_2$ ($a-Mn_3Ge_2$) was reported to show spin glass behavior with spin-glass transition temperature (Tg) of 53 K. In addition, the transition of crystalline $Mn_3Ge_2$ shifts under high pressure. At the atmospheric pressure, $Mn_3Ge_2$ undergoes the magnetic phase transition from AFM to FM at 158 K. The pressure dependence of the phase transition in $Mn_3Ge_2$ has been determined up to 1 GPa. The transition was found to occur at 1 GPa and 155 K with dT/dP=-0.3K/0.1 GPa. Here report that Ferromagnetic $Mn_3Ge_2$ thin films were successfully grown on GaAs(001) and GaSb(001) substrates using molecular beam epitaxy. Our result revealed that the substrate facilitates to modify magnetic and electrical properties due to tensile/compressive strain effect. The spin-flopping transition around 145 K remained for samples grown on GaSb(001) while it completely disappeared for samples grown on GaAs(001). The antiferromagnetism below 145K changed to ferromagnetism and remained upto 327K. The saturation magnetization was found to be 1.32 and $0.23\;{\mu}B/Mn$ at 5 K for samples grown on GaAs(001) and GaSb(001), respectively.

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집적광학용 격자구조의 제작과 응용 (Fabrication of Grating Structures and Their Applications in Integrated Optics)

  • 이성재;송재원;신상영
    • 대한전자공학회논문지
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    • 제21권3호
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    • pp.39-45
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    • 1984
  • Submicron gratings are fabricated holographically on thin film single mode and multimode waveguides. Thin film waveguides are made by spin-coating polyurethane solution on the substrates of microscope slide glass and Corning 7059 glass. In order to characterize thin film waveguides, the refract사e index and the thickness of thin films are measured by using the m-line spectroscopy. The fabricated gratings are tested as a grating coupler, a mode converter, and a beam splitter. Also chirped gratings are fabricated to observe beam expansion phenomena and thus the possibility of the wavelength demultiplexing.

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Field Emission properties of photosensitive carbon nanotube paste with different inorganic binders

  • Park, Jae-Hong;Moon, Jin-San;Jeong, Jin-Soo;Yoo, Ji-Beom;Park, Chong-Yun;Nam, Joong- Woo;Park, Jong-Hwan;Choe, Deok-Hyeon
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2005년도 International Meeting on Information Displayvol.II
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    • pp.1451-1454
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    • 2005
  • We report effects of inorganic binder on the emission properties of CNT paste for low cost and high low-cost and large area field emission devices or displays. Two types of photosensitive carbon nanotube (CNT) paste were formulated by using of glass frit and spin on glass (SOG) as an inorganic binder and investigated their emission properties according to inorganic binders and firing conditions.

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Blocking Layers Deposited on TCO Substrate and Their Effects on Photovoltaic Properties in Dye-Sensitized Solar Cells

  • Yoo, Beom-Hin;Kim, Kyung-Kon;Lee, Doh-Kwon;Kim, Hong-Gon;Kim, Bong-Soo;Park, Nam-Gyu;Ko, Min-Jae
    • Journal of Electrochemical Science and Technology
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    • 제2권2호
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    • pp.68-75
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    • 2011
  • In this review, we have investigated the effect of $TiO_2$-based blocking layers (t-BLs), deposited on a transparent conductive oxide (TCO)-coated glass substrate, on the photovoltaic performance of dye-sensitized solar cells (DSSCs). The t-BL was deposited using spin-coating or sputtering technique, and its thicknesses were varied to study the influence of the thin $TiO_2$ layer in between transparent conducting glass and nanocrystalline $TiO_2$ (nc-$TiO_2$). The DSSC with the t-BL showed the improved adhesion and the suppressed charge recombination at a TCO glass substrate than those without the t-BL, which led to the higher conversion efficiency.

Sol-Gel법으로 제조한 (Ba,Sr)$TiO_3$ 박막의 구조 및 유전특성 (Structural and Dielectric Properties of the (Ba,Sr)$TiO_3$Thin Films Prepared by Sol-Gel Method)

  • 이문기;정장호;이성갑;이영희
    • 한국전기전자재료학회논문지
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    • 제11권9호
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    • pp.711-717
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    • 1998
  • BST(70/30) and BST(50/50) thin films were prepared by Sol-Gel method and studied about the microstructural and dielectric properties with Pt and ITO bottom electrodes. The stock solution was synthesized and spin coated on the Pt/Ti$SiO_2$/Si and Indium Tin Oxide(ITO)/ glass substrate. the coated films were dries at 350$^{\circ}C$ for 10 minutes and annealed at $750^{\circ}C$ for 1 hour for the crystallization. The thin films coated on ITO substrate were crystallized easily and the packing density and roughness of surface were better that those of films coated on Pt substrates. In the BST(50/50) composition the structural properties were similar to the BST(70/30) composition and grain size were decreased with increasing the contents of Sr. The dielectric constant was higher in the BST(50/50) composition compared with the BST(70/30) composition. Using the ITO substrate, the dielectric constant was higher than the Pt substrate while the dielectric loss was showed a reverse trend. The dielectric constant with and increase of temperature was decreased slowly.

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