• 한국자기학회지
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• 제3권3호
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• pp.179-184
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• 1993

비정질 합금 $Fe_{78}Si_{9}B_{13}$의 구조를 X-선 회절상을 분석하여 구하였다. 계산된 동경분포함수(RDF)의 첫번째 peak는 최인접 원자의 분포를 나타내는 것으로 Gaussian 함수형태를 나타낸다. 구조분석에서 본 시료의 최인접 원자배위수는 13.5이고, 최인접 원자간 평균거리 $r_{0}$는 $2.595{\AA}$, 인접원자들의 분포를 나타내는 Gaussian 함수의 변수 ${\delta}r$은 $0.27{\AA}$이다. 저온에서의 포화자화의 온도 의존성은 spin 파로 설명할 수 있으며, 이 때에 계산된 spin파 stiffness 상수는 $117.8\;meV\;{\AA}^2$ 이다. 또한, 포화자화의 온도 의존성을 Handrich의 분자장 이론식과 맞추어 얻은 변수는 각각 S=1/2 일때 ${\Delta}=0.32$이고, S=1 일때 ${\Delta}=0.23$으로 이론식과 실험결과가 전체적으로 잘 일치한다. 구조분석 결과와 분자장 이론식에서 구한 변수를 활용하여 spin파 stiffness 상수를 계산할 수 있으며, 이로써 구한 값은 S=1/2일때 $149\;meV\;{\AA}^2$ 이고, S=1 일 때 $138\;meV\;{\AA}^2$ 이다. 또한, 평균 교환결합상수 J($r_{0}$)는 S=1/2일때 17.9 meV이고, S=1일때는 J($r_{0}$)는 6.7 meV 으로 추정된다.

• 한국자기학회지
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• 제11권3호
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• pp.104-108
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• 2001

NiO 스핀밸브 박막을 제작하고 이를 공기중에서 80 일간 자연산화시킨후, 형성된 산화층에 의한 NiO 스핀밸브 박막의 자기저항 특성을 연구하였다. NiO(600 $\AA$)Ni$_{81}$$Fe_{19}$(50$\AA$)/Co(7 $\AA$)/Cu(20 $\AA$)/Co(7 $\AA$)Ni$_{81}$$Fe_{19}$(70 $\AA$)의 구조를 갖는 스핀밸브박막을 공기중에서 약 80일 간 자연산화시켰을 때, 자기저항비와 교환결합력( $H_{ex}$)이 각각 4.9%와 110 Oe에서 7.3%와 170 Oe로 증가하였다. 이때, 스핀밸브박막의 비저항($\rho$)값은 28$\mu$$\Omega$m에서 17$\mu$$\Omega$m로 감소하였지만 박막의 비저항값의 변화량($\Delta$$\rho$)는 크기변화가 거의 없는 것을 알 수 있었다. 그러므로, 자기저항비의 증가는 자연산화에 따른 비저항값의 감소에 기인한 것으로 생각되며, 저항의 감소는 specular 효과 때문인 것으로 판단된다. 스핀밸브박막의 표면에 형성된 NiFe 산화층의 두께는 약 20 $\AA$인 것으로 추정되며, Auger electron spectroscopy(AES)를 이용하여 분석하였다.하였다.다.

• Journal of Magnetics
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• 제11권2호
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• pp.61-65
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• 2006

The physical origin of complex dynamic domain configuration in nonequilibrium magnetic systems with mesoscopic length scales has been studied. An increasing complexity in the spatial feature of the evolution is found to accompany the increasing reversal speed, when a ferromagnetic element is driven by progressively faster switching fields applied antiparallel to the initial magnetization direction. As reversal rates approach the characteristic precession frequencies of spin fluctuations, the thermal energy can boost the magnetization into local configurations which are completely different from those experienced during quasistatic reversal. The sensitive dependence of the spatial pattern on switching speed can be understood in terms of a dynamic exchange interaction of thermally excited spins; the coherent modulation of the spins is strongly dependent on the rise time of switching pulses.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2011년도 제40회 동계학술대회 초록집
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• pp.303-303
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• 2011

Orderings and electronic structures of organic molecules on metal substrates have been studied due to possible applications in electronic devices. In molecular systems, delocalized pi-electrons play important roles in the adsorption behaviors and electronic structures. We studied the adsorption and electronic structures of Co-Porphyrin molecules on Au(111) using scanning tunneling microscopy (STM) and spectroscopy (STS) at low temperature. Molecules form closely packed two-dimensional islands on Au(111) surface with two different types, having different shape evolutions in our energy-dependent STM observations. The Kondo resonance state, occurred by spin exchange interaction between the Co center atom and conduction electrons in the metal substrate, was observed in one type, while it was absent in the other type in scanning tunneling spectroscopy measurements. Possible origins of two molecular shapes will be discussed.

• Journal of Magnetics
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• 제18권2호
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• pp.81-85
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• 2013

We investigate the electronic and magnetic properties in Cu-doped InN with the N vacancy ($V_N$) from first principles calculations. There is the long-range ferromagnetic order between two Cu atoms, attributed to the hole-mediated double exchange through the strong p-d interaction between the Cu atom and neighboring N atom. The system of $V_N$ defect in Cu-doped InN has the lowest formation energy. Due to the hybridization between the Cu-3d and $V_N$ states, the spin-polarization on the Cu atoms in the InN lattice is reduced by $V_N$ defect. So, it shows a weak ferromagnetic behavior.

• Journal of Magnetics
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• 제16권4호
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• pp.332-336
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• 2011

We studied the effect on the electronic and magnetic properties of the N defect in clean and Cu-doped wurtzite III-nitrides by using the first-principles calculations. When it is doped two Cu atoms in the nearest neighboring sites, the system of AlN, GaN, or InN with the N vacancy is energetically more favorable than that without the N vacancy site. When the Cu concentration increases, the total magnetic moment of a supercell becomes small. The ferromagnetism of Cu atom is very low due to the weak 3d-3d coupling. It is noticeable that the spin-exchange interaction between the Cu-3d and N defect states is important.

• Journal of Magnetics
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• 제2권4호
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• pp.135-137
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• 1997

We report the salient features of the magnetic properties of amorphous TM70Cr5Si10B15(TM=Fe, Co, Ni) alloys. The temperature dependence of magnetization for amorphous ribbons were measured by a SQUID and a VSM from 5 K to 700 K under an external field of 10 kOe. Except TM70Cr5Si10B15 that shows a paramagnetic behaviour, both Fe and Co based amorphous alloys show a typical ferromagnetic thermo-magnetization curves. For these two ferromagnetic alloys, the saturation magnetization in the temperature range from 5 K to about 0.4 Tc can be descrived by the Bloch relation, Ms (T)=Ms(0) [1-BT3/2-CT5/2]. The spin wave stiffness constants and the range of exchange interaction were analyzed from the magnetization behaviour. The variation of the magnetic properties are discussed and compared with the composition of the alloys.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2003년도 춘계학술대회 논문집 초전도 자성체 연구회
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• pp.13-16
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• 2003

Magnetic and magneto-optical properties of Fe/Pt/Fe, Co/Pd/Co trilayers and also the sandwiches with wedge-shaped magnetic (Fe, Co) and nonmagnetic (Pt, Pd) layers were investigated. The oscillatory behavior of the saturation field $H_{s}$ of the studied trilayers with changing the thickness of the nonmagnetic layer (NML) $t_{NML}$ was revealed. That was explained by the exchange coupling between ferromagnetic layers (FML) through the nonmagnetic spacer. For the first time, oscillations of the transverse Kerr effect (TKE) with changing the Pt- and Pd-wedge thickness were discovered. Period of these oscillations was found to depend on the FML thickness and the photon energy of the incident light. TKE spectra of the examined samples were discovered to modify very strongly with increasing $t_{NML}$. The discovered peculiarities of magneto-optical properties of thin-film systems were explained by a concept of the spin-polarized quantum well states in the pt and Pd layers.

• 한국진공학회지
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• 제12권S1호
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• pp.60-62
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• 2003

In this study we report the results of ab initio first-principles calculations to investigate the possibility of metamagnetic behavior in Fe$_3$Al alloy. We used the WIEN2k package of full-potential linearized-augmented- plane-wave method within the local-spin-density approximation to the density-functional theory. The exchange-correlation functional is the generalized-gradient approximation of Perdew-Burke-Ernzerhof. The theoretical lattice constant, which is about 0.5% smaller than the experimental one, is obtained by minimizing the total energy. If the volume decreases about 9 % from the equilibrium, the total magnetic moment decreases abruptly from 4.6 $\mu_{B}$/f.u. to 4.0 $\mu_{B}$/f.u. Since this change is considerably large (∼14%), it is possible to measure by a simple high-pressure experiment at about 180 kbar.

• Bulletin of the Korean Chemical Society
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• 제13권4호
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• pp.419-425
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• 1992

Conducting polypyrrole doped with iron (Ⅱ,Ⅲ) hexacyanate Fe$(CN)_6^{z-}$ ions was studied for its physical and electrochemical properties. The polymer exhibited two pairs of waves in the cyclic voltammogram, one for the reversible oxidation/reduction of the incorporated iron hexacyanate ions and the other for the near-reversible oxidation/reduction of the polypyrrole moiety. The exchange of ions incorporated in the polymer and other ions present in solutions were examined by following the decrease of the reversible redox peaks of Fe$(CN)_6^{z-}$, and by EDX analysis. The spin density of this highly conducting polymer as probed by ESR spectroscopy was extremely low compared to polypyrrole doped with common anions.