• 제목/요약/키워드: Spectroscopic characteristics

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IGRINS observations of a Herbig Be star, MWC 1080

  • Kim, Il-Joong;Oh, Heeyoung;Jeong, Woong-Seob
    • The Bulletin of The Korean Astronomical Society
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    • v.43 no.1
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    • pp.65.2-65.2
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    • 2018
  • Through MIRIS $Pa{\alpha}$ Galactic plane survey, a lot of $Pa{\alpha}$ blobs were detected along the plane. To reveal their characteristics, we are planning to collect NIR high-resolution spectroscopic data for them by using Immersion GRating INfrared Spectrograph (IGRINS). Here, we present the preliminary results of the IGRINS observations for a Herbig Be star, MWC 1080, which is one of the $Pa{\alpha}$ blobs detected in Cepheus. This Herbig Be star is known to possess a lot of young stellar objects (YSOs) and bright MIR ($10-20{\mu}m$) nebulosity in its vicinity. From IPHAS $H{\alpha}$ data, we revealed large extended $H{\alpha}$ features that correlate well with MIR and 13CO morphologies around MWC 1080. A part of the $H{\alpha}$ features shows a bow shock shape to the northeast of the primary star MWC 1080A, which seems to be due to an outflow from MWC 1080A. Through IGRINS observations, we detected faint [Fe II] ${\lambda}1.644{\mu}m$ and H2 1-0 S(1) ${\lambda}2.122{\mu}m$ emission lines around the bow shock feature. Interestingly, to the east region of MWC 1080A, we also detected strong [Fe II] and H2 emission lines with a couple of velocity components, which suggests the detection of a new outflow from another YSO. Broad $Br{\gamma}$ ${\lambda}2.1662{\mu}m$ line and H2 lines with various velocity components were detected around the bright MIR and $H{\alpha}$ nebulosity as well.

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A study on the identification of type IIa natural diamonds treated by the HPHT method (HPHT(고온고압)에 의해 처리된 type IIa 천연 다이아몬드의 감별에 관한 연구)

  • 김영출;최현민
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.14 no.1
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    • pp.21-26
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    • 2004
  • Results from PL and Raman spectroscopic analyses of HPHT (high-pressure high-temperature) treated type IIa diamonds are presented, and these spectral characteristics are compared with those of untreated diamonds of similar color and type. We identify a number of significant changes by 325 nm He/Cd laser excitation. Several peaks are removed completely, including H4, H3 system in HPHT treated diamond. The N3 system, however, increased in emission. Also we can find the behaviour of the nitrogen-vacancy related center N-V centers at 575 and 637.1 nm, as observed with 514 nm Ar ion laser excitation. When these centers are present, the FWHM (full width at half maximum) of 637.1 nm luminescence intensities offers a potential means of separating HPHT-treated from untreated type IIa diamonds. The width of 637.1 nm $(N-V)^-$line measured at the position oi half the peak's height are determine to range from 19.8 to $32.1cm^{-1}$ for HPHT treated diamonds.

Particle Behavior and Properties of Pigment Red 57:1 Synthesized in Various Reaction Conditions (다양한 반응 조건에 따른 적색안료 57:1의 입자거동 및 특성)

  • Yang, Seok Won;Kim, Jae Hwan;Kim, Do Hyun;Jin, Young Eup;Lee, Gun-Dae;Park, Seong Soo
    • Applied Chemistry for Engineering
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    • v.28 no.1
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    • pp.95-100
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    • 2017
  • In this study, various Pigment Red 57:1 samples and also their dispersant were prepared in various synthesis conditions via changing parameters such as synthesis time, pH, derivative content and synthesis temperature in order to analyze the pigment particle behaviors and their spectroscopic and physical properties. Each sample was analyzed using Fourier infrared spectroscopy, UV-Vis spectroscopy, particle size analyzer, color spectrophotometer and X-ray diffractometer and their characteristics were compared. As a result, it was possible to control the size of pigment particles by controlling the synthesis conditions.

SH 2-128, AN H II AND STAR FORMING REGION IN AN UNLIKELY PLACE

  • BOHIGAS JOAQUIN;TAPIA MAURICIO
    • Journal of The Korean Astronomical Society
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    • v.37 no.4
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    • pp.285-288
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    • 2004
  • Near-infrared imaging photometry supplemented by optical spectroscopy and narrow-band imaging of the H II region Sh 2-128 and its environment are presented. This region contains a developed H II region and the neighboring compact H II region S 128N associated with a pair of water maser sources. Midway between these, the core of a CO cloud is located. The principal ionizing source of Sh 2-128 is an 07 star close to its center. A new spectroscopic distance of 9.4 kpc is derived, very similar to the kinematic distance to the nebula. This implies a galactocentric distance of 13.5 kpc and z = 550 pc. The region is optically thin with abundances close to those predicted by galactocentric gradients. The $JHK_s$ images show that S 128N contains several infrared point sources and nebular emission knots with large near-infrared excesses. One of the three red Ks knots coincides with the compact H II region. A few of the infrared-excess objects are close to known mid- and far-infrared emission peaks. Star counts in J and $K_s$ show the presence of a small cluster of B-type stars, mainly associated with S 128N. The $JHK_s$ photometric properties together with the characteristics of the other objects in the vicinity suggest that Sh 2-128 and S 128N constitute a single complex formed from the same molecular cloud, with ages ${\~}10^6$ and < $3 {\times} 10^5$ years respectively. No molecular hydrogen emission was detected at 2.12 ${\mu}m$. The origin of this remote star forming region is an open problem.

Cellular-uptake Behavior of Polymer Nanoparticles into Consideration of Biosafety

  • Do, Jeong-Hoe;An, Jeong-Ho;Joun, Yong-Seung;Chung, Dong-June;Kim, Ji-Heung
    • Macromolecular Research
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    • v.16 no.8
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    • pp.695-703
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    • 2008
  • Nanoparticles have tremendous potential in cancer prevention, detection and augmenting existing treatments. They can target tumors, carry imaging capability to document the presence of tumors, sense pathophysiological defects in tumor cells, deliver therapeutic genes or drugs based on the tumor characteristics, respond to external triggers to release an appropriate agent, document the tumor response, and identify the residual tumor cells. Nanoparticles < 30 nanometers in diameter show unexpected and unique properties. Furthermore, particles < 5 nanometers in size can easily penetrate cells as well as living tissues and organs. This study evaluated the safety of nano materials in a living body and the relationship between the living tissue and synthetic nano materials by examining the in-vitro cytotoxicity of poly(lactic-co-glycolic) acid (PLGA) nano-spheres and fluorescein isothiocynate(FITC)-labeled dendrimers as polymer nanoparticles. PLGA was chosen because it has been used extensively for biodegradable nanoparticles on account of its outstanding bio-compatibility and its acceptance as an FDA approved material. The dendrimer was chosen because it can carry a molecule that recognizes cancer cells, a therapeutic agent that can kill those cells, and a molecule that recognizes the signals of cell death. Cytotoxicity in L929 mouse fibroblasts was monitored using MTT assay. Microscopic observations were also carried out to observe cell growth. All assays yielded meaningful results and the PLGA nanoparticles showed less cytotoxicity than the dendrimer. These nano-particles ranged in size from 10 to 100 nm according to microscopy and spectroscopic methods.

Pyridoxatin, an Inhibitor of Gelatinase A with Cytotoxic Activity

  • Lee, Ho-Jae;Chung, Myung-Chul;Lee, Choong-Hwan;Chun, Hyo-Kon;Kim, Hwan-Mook;Kho, Yung-Hee
    • Journal of Microbiology and Biotechnology
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    • v.6 no.6
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    • pp.445-450
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    • 1996
  • Gelatinase A is a member of the matrix metalloproteinases that play an important role in cancer invasion and metastasis. In the course of screening gelatinase A inhibitors from microbial sources, a fungal strain PT-262 showed a strong inhibitory activity. The strain was identified as Chaunopycnis alba on the basis of its morphological characteristics. The inhibitor was isolated from acetone extract of mycelial cake by sequential chromatographies on MCI-gel, Sephadex LH-20, and a reverse-phase HPLC column. The purified inhibitor was identified as pyridoxatin by its physico-chemical properties and spectroscopic analysis. Pyridoxatin is not a peptide analog and has cyclic hydroxamic acid moiety. It inhibited activated gelatinase A with an $IC_{50}$ value of 15.2 ${\mu}M$ using fluorescent synthetic peptide. It also had a strong cytotoxicity against human cancer cell lines in vitro. Furthermore, this compound inhibited DNA synthesis with an $IC_{50}$ value of 2.92 ${\mu}M$ in PC-3 prostate cancer cells by [$^3H$]thymidine incorporation assay.

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A Polarimetric Study of Long-Period Comet C/2013 US10 (Catalina) and Estimation of Its Gas Contamination in Optical and Near-Infrared Wavelengths

  • Kwon, Yuna Grace;Ishiguro, Masateru;Kuroda, Daisuke;Hanayama, Hidekazu;Kawabata, Koji S.;Akitaya, Hiroshi;Itoh, Ryosuke;Nakaoka, Tatsuya
    • The Bulletin of The Korean Astronomical Society
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    • v.41 no.1
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    • pp.48.1-48.1
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    • 2016
  • Polarimetric study of light scattering from cometary dust particles can provide us opportunity to decipher their characteristics, such as sizes, structures, compositions of dust grains, etc. Herein, we present the results of our polarimetric study of long-period comet, C/2013 US10 (Catalina), in optical and near-infrared wavelengths which appeared at large phase angle (52.7 degrees) around the mid-December, 2015. We performed polarimetric and spectroscopic observations with HONIR, attached to the 1.5-m telescope at Higashi-Hiroshima Observatory, on UT 2015 December 17-18 and also obtained optical imaging data sets by the Ishigakijima Astronomical Observatory (IAO) and Okayama Astrophysical Observatory (OAO) taken between 2014-2015. By measuring the intensities of gas emission lines with respect to dust continuum and considering transmittance of each filter, we estimated that the percentages of gas contamination are approximately 10 percents in $R_C$-band and 3 percents in $I_C$-band. With these results, we derive the degree of linear polarization scattered solely from dust components in the coma. At this presentation, we will compare the phase-angle dependence of the degree of linear polarization with those of previous archive data in a wide coverage of wavelengths from $R_C$-band to $K_S$-band. Finally, we are supposed to discuss the spatial variations in polarization within the coma.

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In-situ Raman Spectroscopic Study of Nickel-base Alloys in Nuclear Power Plants and Its Implications to SCC

  • Kim, Ji Hyun;Bahn, Chi Bum;Hwang, Il Soon
    • Corrosion Science and Technology
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    • v.3 no.5
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    • pp.198-208
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    • 2004
  • Although there has been no general agreement on the mechanism of primary water stress corrosion cracking (PWSCC) as one of major degradation modes of Ni-base alloys in pressurized water reactors (PWR's), common postulation derived from previous studies is that the damage to the alloy substrate can be related to mass transport characteristics and/or repair properties of overlaid oxide film. Recently, it was shown that the oxide film structure and PWSCC initiation time as well as crack growth rate were systematically varied as a function of dissolved hydrogen concentration in high temperature water, supporting the postulation. In order to understand how the oxide film composition can vary with water chemistry, this study was conducted to characterize oxide films on Alloy 600 by an in-situ Raman spectroscopy. Based on both experimental and thermodynamic prediction results, Ni/NiO thermodynamic equilibrium condition was defined as a function of electrochemical potential and temperature. The results agree well with Attanasio et al.'s data by contact electrical resistance measurements. The anomalously high PWSCC growth rate consistently observed in the vicinity of Ni/NiO equilibrium is then attributed to weak thermodynamic stability of NiO. Redox-induced phase transition between Ni metal and NiO may undermine the integrity of NiO and enhance presumably the percolation of oxidizing environment through the oxide film, especially along grain boundaries. The redox-induced grain boundary oxide degradation mechanism has been postulated and will be tested by using the in-situ Raman facility.

Effect of ethanol concentration on the infrared spectroscopic characteristics of silk beads (알코올의 농도에 따른 실크 비드의 적외선 분광 특성)

  • Kim, Sung-Kuk;Jo, You-Young;Lee, Kwang-Gill;Kim, Kee-Young;Kim, Hyun-bok;Kweon, HaeYong
    • Journal of Sericultural and Entomological Science
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    • v.53 no.2
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    • pp.118-123
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    • 2015
  • The structural transition of silk protein has been induced by various method including alcohol treatment. To know the effect of alcohol concentration on silk beads conformation, silk beads were prepared in different alcohol concentration (100%, 70%, and 50%) and then examined the infrared spectra of silk beads. Silk beads prepared in 100% alcohol showed at $1265cm^{-1}$ attributed ${\beta}-sheet$ conformation and did not showed a characteristic absorption peak from model drug. However, silk beads in 70% and 50% alcohol showed some peaks originated from model drug including $2933cm^{-1}$, $1069cm^{-1}$, and $973cm^{-1}$. These results means that the micro-environment of silk beads was affected by alcohol concentration.

Effect of extrusion of soybean meal on feed spectroscopic molecular structures and on performance, blood metabolites and nutrient digestibility of Holstein dairy calves

  • Berenti, Ammar Mollaei;Yari, Mojtaba;Khalaji, Saeed;Hedayati, Mahdi;Akbarian, Amin;Yu, Peiqiang
    • Animal Bioscience
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    • v.34 no.5
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    • pp.855-866
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    • 2021
  • Objective: Performance and physiological responses of dairy calves may change by using extruded soybean meal (ESBM) instead of common soybean meal (SBM) in starter feed. The aims of the current study were i) to determine the effect of extrusion processing of SBM on protein electrophoretic size, fourier transform infrared spectroscopy (FTIR) structures and Cornell Net Carbohydrate and Protein System (CNCPS) protein subfractions and ii) to determine the effect of substitution of SBM with ESBM in starter feed of Holstein heifer calves during pre and post-weaning on performance, nutrient digestibility, and blood metabolites. Methods: The SBM was substituted with ESBM at the level of 0%, 25%, 50%, 75%, and 100% (dry matter [DM] basis). Fifty heifer calves (initial body weight 40.3±0.63 kg) were used for the study. After birth, animals were fed colostrum for 3 days and then they were fed whole milk until weaning. Animals had free access to starter feed and water during the study. Results: Extrusion of SBM decreased electrophoretic protein size and increased rapidly degradable true protein fraction, changed FTIR protein and amide II region. With increasing level of ESBM in the diet, starter intake increased quadratically during the pre-weaning period (p<0.05) and body weight, DM intake and average daily gain increased linearly during the post-weaning and the whole study period (p<0.05). Tbe DM and crude protein digestibilities at week 14 and blood glucose and beta hydroxybutyric acid increased linearly in calves as the level of ESBM increased in the diet (p<0.05). Conclusion: Dairy calves performance and physiological responses were sensitive to SBM protein characteristics including electrophoretic size, FTIR structures and CNCPS protein fractions.