• Title/Summary/Keyword: Spectroscopic Analysis

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ORIGIN AND STATUS OF LOW-MASS CANDIDATE HYPERVELOCITY STARS

  • Yeom, Bum-Suk;Lee, Young Sun;Koo, Jae-Rim;Beers, Timothy C.;Kim, Young Kwang
    • Journal of The Korean Astronomical Society
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    • v.52 no.3
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    • pp.57-69
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    • 2019
  • We present an analysis of the chemical abundances and kinematics of six low-mass dwarf stars, previously claimed to be candidate hypervelocity stars (HVSs). We obtained moderate-resolution (R ~ 6000) spectra of these stars to estimate the abundances of several chemical elements (Mg, Si, Ca, Ti, Cr, Fe, and Ni), and derived their space velocities and orbital parameters using proper motions from the Gaia Data Release 2. All six stars are shown to be bound to the Milky Way, and in fact are not even considered high-velocity stars with respect to the Galactic rest frame. Nevertheless, we attempt to characterize their parent Galactic stellar components by simultaneously comparing their element abundance patterns and orbital parameters with those expected from various Galactic stellar components. We find that two of our program stars are typical disk stars. For four stars, even though their kinematic probabilistic membership assignment suggests membership in the Galactic disk, based on their distinct orbital properties and chemical characteristics, we cannot rule out exotic origins as follows. Two stars may be runaway stars from the Galactic disk. One star has possibly been accreted from a disrupted dwarf galaxy or dynamically heated from a birthplace in the Galactic bulge. The last object may be either a runaway disk star or has been dynamically heated. Spectroscopic follow-up observations with higher resolution for these curious objects will provide a better understanding of their origin.

Ceramic color differences of dental Ni-Cr alloy by compositional change (치과용 Ni-Cr 합금의 조성에 따른 세라믹의 색차 분석)

  • Kim, Sa-Im;Kim, Tae-Yeon;Kim, Se-Ha;Kang, Jeong-Gyu;Lee, Jung-Hwan
    • Journal of Technologic Dentistry
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    • v.43 no.4
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    • pp.168-174
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    • 2021
  • Purpose: This study was conducted to investigate alloys spectrophotometrically including yttrium of nickel-chromium (Ni-Cr) alloys, which are used as substitutes for the regulation of beryllium and provide helpful improvements in Ni-Cr alloys. Methods: Four groups of specimens (ZN, ZY, SN and EM) were prepared for analysis. Color parameters were measured with a spectrophotometer, and color difference (∆E*) was calculated. The t-test and one-way analysis of variance test were used to determine significant difference, and the Tukey test was used to identify where the differences were. To measure the spectroscopic reflectivity, the spectroscopic reflectance was measured and converted into CIE L*, a*, b* color system. Results: The ∆E* value of each metal ceramic group after opaque firing of Ni-Cr alloy with and without yttrium was <2, and the total group color difference (∆E*) was below 1 in the dentin ceramic all experimental group. However, the a* and b* values of the metal ceramic groups were higher than that in the lithium disilicate all ceramic group, and the chroma was higher than the natural tooth. The brightness of all experimental groups was similar to that of the shade guide sample. Conclusion: Yttrium added to Ni-Cr alloys showed similar CIE L*, a*, b* values to Ni-Cr alloys that did not contain yttrium, indicating that yttrium had no effect on color in metallic ceramic systems.

Integration of virtual screening and proteomics reveals potential targets and pathways for ginsenoside Rg1 against myocardial ischemia

  • Rongfang Xie;Chenlu Li;Chenhui Zhong;Zuan Lin;Shaoguang Li;Bing Chen;Youjia Wu;Fen Hu;Peiying Shi;Hong Yao
    • Journal of Ginseng Research
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    • v.48 no.4
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    • pp.395-404
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    • 2024
  • Background: Ginsenoside Rg1 (Rg1) is one of the main active components in Chinese medicines, Panax ginseng and Panax notoginseng. Research has shown that Rg1 has a protective effect on the cardiovascular system, including anti-myocardial ischemia-reperfusion injury, anti-apoptosis, and promotion of myocardial angiogenesis, suggesting it a potential cardiovascular agent. However, the protective mechanism involved is still not fully understood. Methods: Based on network pharmacology, ligand-based protein docking, proteomics, Western blot, protein recombination and spectroscopic analysis (UV-Vis and fluorescence spectra) techniques, potential targets and pathways for Rg1 against myocardial ischemia (MI) were screened and explored. Results: An important target set containing 19 proteins was constructed. Two target proteins with more favorable binding activity for Rg1 against MI were further identified by molecular docking, including mitogen-activated protein kinase 1 (MAPK1) and adenosine kinase (ADK). Meanwhile, Rg1 intervention on H9c2 cells injured by H2O2 showed an inhibitory oxidative phosphorylation (OXPHOS) pathway. The inhibition of Rg1 on MAPK1 and OXPHOS pathway was confirmed by Western blot assay. By protein recombination and spectroscopic analysis, the binding reaction between ADK and Rg1 was also evaluated. Conclusion: Rg1 can effectively alleviate cardiomyocytes oxidative stress injury via targeting MAPK1 and ADK, and inhibiting oxidative phosphorylation (OXPHOS) pathway. The present study provides scientific basis for the clinical application of the natural active ingredient, Rg1, and also gives rise to a methodological reference to the searching of action targets and pathways of other natural active ingredients.

Phytochemical Analysis of Viticis Fructus (만형자의 성분분석)

  • Kang, Sam-Sik;Kim, Ju-Sun;Kim, Hae-Jung;Jung, Young-Ran;Shin, Seung-Won
    • Korean Journal of Pharmacognosy
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    • v.25 no.3
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    • pp.214-220
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    • 1994
  • From the Viticis Fructus n-hydrocarbons, ${\beta}-sitosterol$ $3-O-{\beta}-_D-glucoside$ and hesperidin along with the known polyoxygenated flavonoids such as vitexicarpin, artemetin and luteolin, and vanillic acid were isolated and identified by means of spectroscopic methods. HPLC analysis of the flavonoid components from the MeOH extract was established. Phytochemical analyses of the domestic plant sample and the imported ones were conducted and the flavonoid compositions of the domestic samples were greatly different from those of the imported ones.

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Quantitative analysis of 5-HMF produced from fructose (과당에서 전환된 5-HMF(5-hydroxymethylfurfural)의 정량적 분석)

  • Sim, Jaehoon;Shin, Soo-Jeong
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.45 no.1
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    • pp.27-34
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    • 2013
  • Quantitative analysis of 5-hydroxymethylfufural (5-HMF) conversion from fructose by dehydration and rearrangement was investigated by $^1H$-NMR spectroscopic method. Fructose was converted to 5-HMF in dimethylsulfoxide (DMSO)-$d^6$ or acidic deuterium hydroxide at controlled reaction temperature and time. With addition of internal standards (biphenyl for DMSO-$d^6$ solvent, and 2,5-dihydroxybenzoic acid for deuterium oxide solvent), conversion from fructose to 5-HMF was analyzed by $^1H$-NMR spectroscopy. Quantitative analysis was run by comparison with peak area integration between of 5-HMF and internal standard. In DMSO solvent, 5-HMF was stable end product but part of 5-HMF was converted to formic and levulinic acid at acidic aqueous medium.

Isolation and Quantitative Analysis of Icariin from Epimedii Herba (음양곽으로부터 Icariin의 분리 및 함량분석)

  • Lee, Hye-Won;Hwang, Seong-Won;Ko, Byoung-Seob;Kim, Ho-Kyoung
    • Korean Journal of Pharmacognosy
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    • v.32 no.1 s.124
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    • pp.43-48
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    • 2001
  • Epimedii Herba has been used for tonic, cardiotonic, impotency, amnestic and diuretic. Icariin, a main component was isolated from the Epimedii Herba and identified by the spectroscopic methods. In order to evaluate the quality of Epimedii Herba purchased from various regions of Korea, quantitative determination of icariin in Epimedii Herba using HPLC method has been conducted. Quantitative analysis showed the average amount of icariin in commercial 42 samples was 0.34% on the dry weight basis.

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Novel Synthesis and Characterization of Pt-graphene/TiO2 Composite Designed for High Photonic Effect and Photocatalytic Activity under Visible Light

  • Ye, Shu;Oh, Won-Chun
    • Journal of the Korean Ceramic Society
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    • v.54 no.1
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    • pp.28-32
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    • 2017
  • The degradation of methyl blue (MB) catalyzed by platinum (Pt)-graphene/$TiO_2$ in dark ambiance was studied. Pt-graphene/$TiO_2$ composites were prepared by simple hydrothermal method. Characterizations of composites were studied by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), specific surface area (BET) analysis, and energy dispersive X-ray (EDX) analysis. UV-spectroscopic analysis of the dyes was performed by measuring the change in absorbance. The degradation of the organic dyes was calculated based on the decrease in concentration of the dyes with respect to regular time intervals. Rate coefficients for the catalytic process were successfully established and reusability tests were performed to test the stability of the used catalysts.

Isolation and Quantitative Analysis of Kalopanax-Saponin B from Kalopanacis Cortex (해동피로부터 Kalopanax-saponin B의 분리 및 함량분석)

  • Hong, Seong-Su;Hwang, Ji-Sang;Huh, Jae-Doo;Lee, Kyong-Soon;Ro, Jai-Seup
    • Korean Journal of Pharmacognosy
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    • v.33 no.4 s.131
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    • pp.277-284
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    • 2002
  • For the quality control of Kalopanacis Cortex, saponin compound, kalopanax-saponin B was isolated from the MeOH extract of Kalopanacis Cortex, and identified by the spectroscopic evidences. A quantitative analysis of kalopanaxsapo-nits B using HPLC method showed that the average contents was $1.010{\pm}0.212%$, respectively, in 22 samples collected through-out the regions of Korea.

Quantitative Analysis of Lignans from Fruits of Schizandra chinensis (오미자 리그난 성분의 정량분석)

  • Kim, Kwan-Su;Ryu, Su-Noh;Kang, Sam-Sik
    • Korean Journal of Pharmacognosy
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    • v.33 no.4 s.131
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    • pp.272-276
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    • 2002
  • This study was carried out to establish the quantitative analysis of lignans for the quality evaluation of fruit from Schizandra chinensis. Five lignans, gomisin N, schizandrin, gomisin C, schisantherin C, and gomisin A were isolated from the fruits of S. chinensis and identified by the spectroscopic methods. Quantitative determination of three lignans, schizandrin, gomisin A, gomisin N, was conducted using HPLC. Average contents of three lignans in collected lines were 0.70% of schizandrin, 0.20% of gomisin A, 0.57% of gomisin N, and 1.47% of total lignans.

Quantitative Analysis of Ziyuglycoside I from Sanguisorbae Radix (지유로부터 Ziyuglycoside I의 함량분석)

  • Kim, Young-A;Hwang, Seong-Won;Ko, Byoung-Seob;Kim, Ho-Kyoung
    • Korean Journal of Pharmacognosy
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    • v.33 no.2 s.129
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    • pp.100-104
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    • 2002
  • Sanguisorbae Radix has hemostatic, analgesic and astrigent properties and it has been used for the treatment of burns, scalds and internal hemorrhage. Ziyuglycoside I was isolated from Sanguisorbae Radix and identified by the spectroscopic methods. In order to evaluate the quality of it, quantitative determination of Ziyuglycoside I in Sanguisorbae Radix using HPLC method has been conducted. Quantitative analysis of Ziyuglycoside I showed average 3.005% in 30 samples collected throughout the regions of Korea.