• Bulletin of the Korean Chemical Society
• /
• v.33 no.11
• /
• pp.3581-3588
• /
• 2012

A new series of acyclic mononuclear gadolinium(III) complexes have been prepared by Schiff-base condensation derived from 5-methylsalicylaldehyde, diethylenetriamine, tris(2-aminoethyl) amine, triethylenetetramine, N,N-bis(3-aminopropyl)ethylene diamine, N,N-bis(aminopropyl) piperazine, and gadolinium nitrate. All the complexes were characterized by elemental and spectral analyses. Electronic spectra of the complexes show azomethine (CH=N) within the range of 410-420 nm. The fluorescence efficiency of Gd(III) ion in the cavity was completely quenched by the higher chain length ligands. Electrochemical studies of the complexes show irreversible one electron reduction process around -2.15 to -1.60 V The reduction potential of gadolinium(III) complexes shifts towards anodic directions respectively upon increasing the chain length. The catalytic activity of the gadolinium(III) complexes on the hydrolysis of 4-nitrophenylphosphate was determined. All gadolinium(III) complexes were screened for antibacterial activity.

• Bulletin of the Korean Chemical Society
• /
• v.31 no.5
• /
• pp.1135-1142
• /
• 2010

A series of N(2)-benzothiazolyl substituted tetrahydroindazoles has been synthesized via cyclic ${\beta}$ keto esters. Optimum reaction condition was found as acidic toluene and effect of higher acidity towards substituted hydrazines in situ was described. Synthesized compounds have been achieved as single isomer and characterized by using 1D and 2D NMR spectral reports. Antimicrobial screening was carried out for the synthesized compounds along with a series of N(2)-pyridyl tetrahydroindazoles.1 The results of the in vitro antimicrobial screening studies revealed that compounds 13, 16 against Staphylococcus aureus, 11 against Escherichia coli, 10-12, 16 against Pseudomonas aeruginosa and 12 against Klebsiella pneumoniae recorded almost two-fold better activity compared to the standard drug used.

• Proceedings of the Optical Society of Korea Conference
• /
• 2000.02a
• /
• pp.18-19
• /
• 2000

Recently, coherent control of exciton populations has been demonstrated through terahertz, reflection, and four-wave-mixing experiments. However, the most direct probe of exciton population control is the absorption, which has been lacking in previous studies. In this report, we probe the time evolution of exciton population directly through a transmission experiment. In particular, using upconversion technique with both narrow (spectrally broad) and long (spectrally narrow) pulses, we can obtain both the temporal and the spectral information. The main thrust of our report is that when phase controlled, the second pulse can be either greatly enhanced or completely destroyed by gaining energy from exciton (thus destroying the exciton population) or giving all of its energy to the system (thus greatly increasing the exciton population), respectively. (omitted)

• Mycobiology
• /
• v.34 no.4
• /
• pp.214-218
• /
• 2006

Four copper(II) complexes have been prepared using macrocyclic ligands. The macrocyclic ligands have been synthesized by the condensation reaction of diethyl phthalate with Schiff bases derived from o-phenylene diamine and Knoevenagel condensed ${\beta}-ketoanilides$ (obtained by the condensation of acetoacetanilide and substituted benzaldehydes). The ligands and copper complexes have been characterized on the basis of Microanalytical, Mass, UV-Vis., IR and CV spectral studies, as well as conductivity data. On the basis of spectral studies, a square-planar geometry for the copper complexes has been proposed. The in vitro antifungal activities of the compounds were tested against fungi such as Aspergillus niger, Rhizopus stolonifer, Aspergillus flavus, Rhizoctonia bataicola and Candida albicans. All the synthesized copper complexes showed stronger antifungal activities than free ligands. The minimum inhibitory concentrations (MIC) of the copper complexes were found in the range of $8{\sim}28\;{\mu}g/ml$. These compounds represent a novel class of metal-based antifungal agents which provide opportunities for a large number of synthetic variations for modulation of the activities.

• Journal of the Korean Chemical Society
• /
• v.57 no.3
• /
• pp.341-351
• /
• 2013

Zn(II), Cd(II) and Hg(II) complexes with a general composition[$M(L)_2(X)_2$], where L=4-aminopyridine (4AP) and $X=NO_2{^-}$ were prepared under microwave irradiation. The metal complexes were characterized by elemental analyses, molar conductance, IR, Far-IR, electronic, NMR ($^1H$, $^{13}C$), XPS spectral and thermal studies. The spectroscopic studies reveal the composition, different modes of bonding, electronic transition, different chemical environment of C and H atoms and the electronic state of the metal atoms. On the basis of the characterization data, tetrahedral geometry is suggested for all the complexes. The free ligand (4-aminopyridine) and their metal complexes were screened against phytopathogenic fungi and bacteria in vitro and the activities were compared.

• Journal of the Korean Geophysical Society
• /
• v.9 no.3
• /
• pp.171-179
• /
• 2006

Predictive equations of ground motions are one of the most important factors in the seismic hazard analysis. Unfortunately, studies on predictive equations of ground motions in Korea had been hampered due to the lack of seismic data. To overcome the lack of data, seismologists adopted the stochastic method based on the seismological model. Korean predictive equations developed by the stochastic method show large differences in their predictions. It was turned out through the analysis of the existing studies that the main sources of the differences are the uncertainties in the (Brune) stress drop and spectral decay rate . Therefore, it is necessary to focus the future research on the reduction of the uncertainties in the two parameters.

• Natural Product Sciences
• /
• v.4 no.4
• /
• pp.253-256
• /
• 1998

Chemical investigation of hot hexane extract of the stem bark of Gordonia ceylanica afforded a new triterpenoid, $3{\beta}-acetoxy-28-hydroxyolean-12-ene$ (1) and three other oleanane triterpenoids, $3{\beta}-hydroxyolean-12-ene$ (2), $3{\beta}-acetoxyolean-12-ene$ (3), and $3{\beta}-acetoxyolean-12-en-11-one$ (4) which are new to the species. Structure of compound 1 was suggested by $^1H\;NMR,\;^{13}C\;NMR$ and MS spectral data and confirmed by converting to previously reported compound, erythrodiol diacetate (5). Structures of 2, 3 and 4 were established by comparison of the spectral data with the previously reported compounds. Further the acid hydrolysate of 4 was identical with $3{\beta}-hydroxyolean-12-en-11-one$ (6).

• Journal of the Optical Society of Korea
• /
• v.7 no.4
• /
• pp.234-239
• /
• 2003

Objective methods to assess quantitatively port wine stain (PWS) blanching in response to laser therapy are needed to improve laser therapeutic outcome. Previous studies have attempted to assess objectively PWS color based on point measurement devices. To date, these approaches have typically been limited by a number of factors such as small test area and need for contact. To address these issues, a polarization spectral imaging system and an image analysis method have been developed to evaluate quantitatively erythema and melanin content distribution in skin. The developed polarization spectral imaging system minimizes artifacts such as glaring, shadowing, and non-uniform illumination that interfere with image fidelity. Furthermore, the image analysis method has been employed to get images of skin melanin and erythema indices from the acquired color images for quantitative analysis. Finally, using PWS patient color image, the effectiveness in laser treatment of PWS was evaluated by calculating relative erythema index image that is the relative erythema index of PWS region to the normal region. The developed device and analysis method appears to be a simple and effective method for quantitative analysis of PWS blanching.

• The Bulletin of The Korean Astronomical Society
• /
• v.40 no.1
• /
• pp.41.4-42
• /
• 2015

The Immersion Grating Infrared Spectrograph (IGRINS) is the first of a new generation of infrared instruments with high sensitivity, high spectral resolution, and broad spectral grasp. IGRINS, a joint project of the University of Texas and the Korea Astronomy and Space Science Institute, designed and constructed by a team at UT, KASI, and Kyung Hee University, has been available to the Korean and Texas communities on the McDonald Observatory 2.7m telescope since 2014 September. On this modest-sized telescope, the instrument has 30 times the spectral grasp of CRIRES at the 8m VLT and is only slightly less sensitive. Already, Korean and UT astronomers have produced a raft of new results in star formation studies, investigations of the interstellar medium, and the nature of cool stars. Several programs are under way to detect and study the atmospheres of exoplanets. We will present highlights from the first 6 months of IGRINS operations and look at the future of IR spectroscopy both with IGRINS and with GMTNIRS, a UT/KASI/KHU instrument for the Giant Magellan Telescope.

• Journal of Astronomy and Space Sciences
• /
• v.33 no.2
• /
• pp.101-104
• /
• 2016

More than 100 γ−ray pulsars have been discovered by the Fermi Gamma-ray Space Telescope. With a significantly enlarged sample size, it is possible to compare the properties of different classes. Radio-quiet (RQ) γ−ray pulsars form a distinct population, and various studies have shown that the properties of the RQ population can be intrinsically different from those of radio-loud (RL) pulsars. Utilizing these differences, it is possible to further classify the pulsar-like unidentified γ−ray sources into sub-groups. In this study, we suggest the possibility of distinguishing RQ/RL pulsars by their spectral shape. We compute the probabilities of a pulsar to be RQ or RL for a given spectral curvature. This can provide a key to the estimation of the intrinsic fraction of radio-quietness in the γ−ray pulsar population, which can place a tight constraint on the emission geometry.