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http://dx.doi.org/10.5012/jkcs.2013.57.3.341

Microwave-assisted Synthesis of Mixed Ligand Complexes of Zn(II), Cd(II) and Hg(II) Derived from 4-aminopyridine and Nitrite Ion: Spectral, Thermal and Biological Investigations  

Dhaveethu, Karuthakannan (PG and Research Department of Chemistry, Bishop Heber College (Autonomous))
Ramachandramoorthy, Thiagarajan (PG and Research Department of Chemistry, Bishop Heber College (Autonomous))
Thirunavukkarasu, Kandasamy (National Centre for Catalysis Research (NCCR), Indian Institute of Technology Madras)
Publication Information
Journal of the Korean Chemical Society / v.57, no.3, 2013 , pp. 341-351 More about this Journal
Abstract
Zn(II), Cd(II) and Hg(II) complexes with a general composition[$M(L)_2(X)_2$], where L=4-aminopyridine (4AP) and $X=NO_2{^-}$ were prepared under microwave irradiation. The metal complexes were characterized by elemental analyses, molar conductance, IR, Far-IR, electronic, NMR ($^1H$, $^{13}C$), XPS spectral and thermal studies. The spectroscopic studies reveal the composition, different modes of bonding, electronic transition, different chemical environment of C and H atoms and the electronic state of the metal atoms. On the basis of the characterization data, tetrahedral geometry is suggested for all the complexes. The free ligand (4-aminopyridine) and their metal complexes were screened against phytopathogenic fungi and bacteria in vitro and the activities were compared.
Keywords
Mixed ligand complexes; 4-aminopyridine; Nitrito; Biological activities;
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