• Title/Summary/Keyword: Spectral studies

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Tumor cell growth inhibition and antioxydative activity of flavonoids from the stem bark of Cudrania tricuspidata (꾸지 뽕나무로부터 분리한 flavonoid계 화합물의 암세포성장 저해 및 항산화 활성)

  • Lee, In-Kyoung;Song, Kyung-Sik;Kim, Chang-Jin;Kim, Hwan-Muk;Oh, Goo-Taeg;Yoo, Ick-Dong
    • Applied Biological Chemistry
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    • v.37 no.2
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    • pp.105-109
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    • 1994
  • Five cytotoxic and antioxidative flavonoids were isolated from the stem bark of Cudrania tricuspidata by consecutive purification using HP-20, silicagel and prep-HPLC. They were identified as taxifolin, orobol, eriodictyol, dihydrokaempferol and steppogenin by means of spectral studies. The antioxidative activities $(IC_{50})$ assayed by TBA method of these compound $1{\sim}5$ to were 6, 3, 3, >50, and $10\;{\mu}g/ml$, respectively. The effect on the growth inhibition $(IC_{50})$ of these compounds against P388 cell line were found to be 0.18, 3.3, 15 and $6.2\;{\mu}g/ml$, respectively in the order of compound 2 to 5.

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Fault Diagnosis Method for Automatic Machine Using Artificial Neutral Network Based on DWT Power Spectral Density (인공신경망을 이용한 DWT 전력스펙트럼 밀도 기반 자동화 기계 고장 진단 기법)

  • Kang, Kyung-Won
    • Journal of the Institute of Convergence Signal Processing
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    • v.20 no.2
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    • pp.78-83
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    • 2019
  • Sounds based machine fault diagnosis recovers all the studies that aim to detect automatically abnormal sound on machines using the acoustic emission by these machines. Conventional methods that use mathematical models have been found inaccurate because of the complexity of the industry machinery systems and the obvious existence of nonlinear factors such as noises. Therefore, any fault diagnosis issue can be treated as a pattern recognition problem. We propose here an automatic fault diagnosis method of hand drills using discrete wavelet transform(DWT) and pattern recognition techniques such as artificial neural networks(ANN). We first conduct a filtering analysis based on DWT. The power spectral density(PSD) is performed on the wavelet subband except for the highest and lowest low frequency subband. The PSD of the wavelet coefficients are extracted as our features for classifier based on ANN the pattern recognition part. The results show that the proposed method can be effectively used not only to detect defects but also to various automatic diagnosis system based on sound.

Analysis of learning preferenece using student's sympathetic-parasympathetic response (학습자의 교감/부교감 반응 분석에 의한 학습 선호도 분석에 관한 연구)

  • Kim, Bo-Yeon;Cha, Jae-Hyuk
    • Journal of Digital Contents Society
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    • v.8 no.3
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    • pp.355-363
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    • 2007
  • One of major factors for learning achievement is the student's learning preference according to his character type. In course of learning, if a student studies e-learning contents opposed to his preference, then he would be under stress and his blood pressure and heart beat be changed. For measuring unwillingness, we used spectral components in frequency domain known as stress measure. For 13 children attending kindergarten we examined S(sensing)/ N(intuition) of MBTI and presented same learning contents during 10 minutes. During learning we gathered ECG signals, changed into HRV(heart rate variability), transformed time-varying HRV signal into spectral density in frequency domain. And then, we divided it into three areas of low(LF), middle(MF), and high-frequency(HF) and calculated stress measures by rates of those frequency area. We compared estimated stress measures of S group with them of N group whether students in different group preferred different contents or not. Experimental shows that students according to MBTI type prefer different contents.

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A Study on Development of an Anti-Rolling System for the Ship Stability Improvement (선박안정성 향상을 위한 횡동요 방지 장치 개발에 관한 연구)

  • Kim, Young-Bok;Lee, Kwon-Soon;Kim, Jun-Hyo;Chae, Gyu-Hoon
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.11 no.1 s.22
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    • pp.23-28
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    • 2005
  • We have investigated the usefulness cf active stabilizing system to reduce ship rolling under disturbances, using varying reaction cf the flaps. In the proposed anti-rolling system for a ship, the flaps as the actuator are installed on the stem to reject rolling motion induced by disturbances like wave. The action induced by flaps which depends on power of disturbances am take the ship balance. Especially, in this study we identify the controlled system under the undefined system structure using spectral analysis and experimental studies. Based on these informations, we design the controller to evaluate the usefulness of the proposed system.

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Novel Erbium(III)-Encapsulated Complexes Based on ${\pi}$-Extended Anthracene Ligands Bearing G3-Aryl-Ether Dendron: Synthesis and Photophysical Studies

  • Baek, Nam-Seob;Kim, Yong-Hee;Roh, Soo-Gyun;Lee, Dong-Hyun;Seo, Kang-Deuk;Kim, Hwan-Kyu
    • Macromolecular Research
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    • v.17 no.9
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    • pp.672-681
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    • 2009
  • A series of inert and photo-stable Er(III)-encapsulated complexes based on ${\pi}$-extended dendritic anthracene ligands bearing G3-aryl-ether dendron ([G3-AnX]-$CO_2H$), which retain different ${\pi}$-bridging systems, such as single (X= S), double (X= D) and triple (X= T) bonds was designed and synthesized to establish the structure-property relationship. The near infrared emission intensities of Er(III)-encapsulated complexes were enhanced dramatically by increasing the ${\pi}$-conjugated extension of anthracene ligands. The time-resolved luminescence spectra show monoexponential decays with a lifetime of $2.0{\sim}2.4ms$ for $Er^{3+}$ ions in thin films, and calculated intrinsic quantum yields of $Er^{3+}$ ions are in the range of $0.025{\sim}0.03%$. As a result, all Er(III)-encapsulated dendrimer complexes exhibit the near IR emission with the following order: $Er^{3+}-[G3-AnD]_3$(terpy) > $Er^{3+}-[G3-AnS]_3$(terpy) ${\approx}$ $Er^{3+}-[G3-AnT]_3$(terpy), because $Er^{3+}-[G3-AnD]_3$(terpy) has a higher relatively spectral overlap J value and energy transfer efficiency. In addition, the lack of detectable phosphorescence and no significant spectral dependence of the ${\pi}$-extended anthracene moieties on the solvent polarity support energy transfer from their singlet state to the central $Er^{3+}$ ion taking place in $Er^{3+}-[G3-AnX]_3$(terpy).

Magnetic and Infrared Spectral Studies of Oxovanadium (IV)-Carboxylate Complexes (옥소바나듐 (IV)-카르복실레이트 착물의 자기적 및 적외적 분광학적 성질)

  • Yoon-Bo Shim;Sung-Nak Choi;Jong-Yul Park
    • Journal of the Korean Chemical Society
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    • v.30 no.1
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    • pp.76-83
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    • 1986
  • Four oxovandium(IV) complexes with carboxylate ligands, $VO(picn)_2$, $VO(htmq)_2$, $VO(quin)_2$ and $VO(pyra)_2{\cdot}2H_2O)$ have been prepared and studied. Infrared spectral data coupled with the results of magnetic susceptibility study strongly suggest that there are relatively strong intermolecular interactions in $VO(picn)_2$ and $VO(htmq)_2$. In all oxovanadium(IV) complexes studied in this work, the carboxylate ligand coordinates to the metal ion in the unidentated fashion. Some fundamental vibration modes of oxovanadium(IV) complexes were empirically assigned from the difference in the spectrum of metal complex with free ligand.

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Synthesis, characterization and spectral studies of various newer long chain aliphatic acid (2-hydroxy benzylidene and 1H-indol-3-ylmethylene) hydrazides as mosquito para-pheromones

  • Awasthi, Suman;Rishishwar, Poonam;Rao, Ambati N.;Ganesan, Kumaran;Malhotra, Ramesh Chandra
    • Journal of the Korean Chemical Society
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    • v.51 no.6
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    • pp.506-512
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    • 2007
  • Various long chain aliphatic acid hydrazides react with aromatic and heterocyclic aldehydes in alcoholic medium in refluxing conditions to give corresponding 2-hydroxy benzylidene and 1H-indol-3-ylmethylene hydrazides, a newer class of mosquito para-pheromones. We describe here synthesis of various novel long chain aliphatic acid (2- hydroxy benzylidene and 1H-indol-3-ylmethylene) hydrazides by conventional as well as microwave irradiation techniques. The structures of these compounds have been confirmed by spectroscopic techniques (FTIR, NMR & MS). Some of the interesting features of the electron impact mass spectral fragmentation pattern of these compounds have also been discussed.

Automatic Change Detection of MODIS NDVI using Artificial Neural Networks (신경망을 이용한 MODIS NDVI의 자동화 변화탐지 기법)

  • Jung, Myung-Hee
    • Journal of the Institute of Electronics Engineers of Korea CI
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    • v.49 no.2
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    • pp.83-89
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    • 2012
  • Natural Vegetation cover, which is very important earth resource, has been significantly altered by humans in some manner. Since this has currently resulted in a significant effect on global climate, various studies on vegetation environment including forest have been performed and the results are utilized in policy decision making. Remotely sensed data can detect, identify and map vegetation cover change based on the analysis of spectral characteristics and thus are vigorously utilized for monitoring vegetation resources. Among various vegetation indices extracted from spectral reponses of remotely sensed data, NDVI is the most popular index which provides a measure of how much photosynthetically active vegetation is present in the scene. In this study, for change detection in vegetation cover, a Multi-layer Perceptron Network (MLPN) as a nonparametric approach has been designed and applied to MODIS/Aqua vegetation indices 16-day L3 global 250m SIN Grid(v005) (MYD13Q1) data. The feature vector for change detection is constructed with the direct NDVI diffenrence at a pixel as well as the differences in some subset of NDVI series data. The research covered 5 years (2006-20110) over Korean peninsular.

Hyperspectral Remote Sensing for Agriculture in Support of GIS Data

  • Zhang, Bing;Zhang, Xia;Liu, Liangyun;Miyazaki, Sanae;Kosaka, Naoko;Ren, Fuhu
    • Proceedings of the KSRS Conference
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    • 2003.11a
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    • pp.1397-1399
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    • 2003
  • When and Where, What kind of agricultural products will be produced and provided for the market? It is a commercial requirement, and also an academic questions to remote sensing technology. Crop physiology analysis and growth monitoring are important elements for precision agriculture management. Remote sensing technology supplies us more selections and available spaces in this dynamic change study by producing images of different spatial, spectral and temporal resolutions. Especially, the hyperspectral remote sensing should do play a key role in crop growth investigation at national, regional and global scales. In the past five years, Chinese academy of sciences and Japan NTT-DATA have made great efforts to establish a prototype information service system to dynamically survey the vegetable planting situation in Nagano area of Japan mainly based on remote sensing data. For such concern, a flexible and light-duty flight system and some practical data processing system and some necessary background information should be rationally made together. In addition, some studies are also important, such as quick pre-processing for hyperspectral data, Multi-temporal vegetation index analysis, hyperspectral image classification in support of GIS data, etc. In this paper, several spectral data analysis models and a designed airborne platform are provided and discussed here.

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Spectral and Thermal Studies of Transition Metal PSSA Ionomers

  • Shim, Il-Wun;Risen, William M. Jr.
    • Bulletin of the Korean Chemical Society
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    • v.9 no.6
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    • pp.368-376
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    • 1988
  • Transition metal PSSA ionomers containing Co(II), Ni(II), Cr(III), Ru(III), and Rh(III) are investigated by IR, Far-IR, UV-Vis and DSC. Reliable IR Spectroscopic criteria are established for assessing the degree of ion-exchange of PSSA ionomers and the local structures around metal cations in them. In the hydrated transition metal PSSA ionomers, the ionic groups are solvated by water molecules and there is no significant interactions between sulfonate group and metal cations. The visible spectra indicated that metal cations are present as [M$(H_2O)_6$]$^{n+}$ with Oh symmetry. Their $T_g$ values increase as the extent of ionic site concentration increases, but there is no direct dependence of $T_g$ on the nature of metal cations or their oxidation states. Thus, the water content in PSSA ionomer is found to have dominant influence on $T_g$ of hydrated transition metal PSSA ionomers. Dehydration of the hydrated transition metal PSSA ionomers results in direct interaction between ionic groups and significant color changes of the ionomers due to the changes of the local structures around metal cations. On the base of spectral data, their local structures are discussed. In case of dehydrated 12.8 and 15.8 mol % transition metal PSSA ionomers, no glass transition is observed in 25-$250^{\circ}C$ region and this is believed to arise from the formation of highly crosslinked structures caused by direct coordination of sulfonate groups of metal cations. In the 6.9 mol % transition metal PSSA ionomers, the glass transition is always observed whether they are hydrated or dehydrated and this is though to be caused by the sufficient segmental mobility of the polymer backbone.