• Title/Summary/Keyword: Spectral studies

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Synthesis and Spectral Characterization of Antifungal Sensitive Schiff Base Transition Metal Complexes

  • Raman, N.;Sakthivel, A.;Rajasekaran, K.
    • Mycobiology
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    • v.35 no.3
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    • pp.150-153
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    • 2007
  • New $N_2O_2$ donor type Schiff base has been designed and synthesized by condensing acetoacetanilido-4-aminoantipyrine with 2-aminobenzoic acid in ethanol. Solid metal complexes of the Schiff base with Cu(II), Ni(II), Co(II), Mn(II), Zn(II), VO(IV), Hg(II) and Cd(II) metal ions were synthesized and characterized by elemental analyses, magnetic susceptibility, molar conduction, fast atom bombardment (FAB) mass, IR, UV-Vis, and $^1H$ NMR spectral studies. The data show that the complexes have the composition of ML type. The UV-Vis. and magnetic susceptibility data of the complexes suggest a square-planar geometry around the central metal ion except VO(IV) complex which has square-pyramidal geometry. The in vitro antifungal activities of the compounds were tested against fungi such as Aspergillus niger, Aspergillus flavus, Rhizopus stolonifer, Candida albicans, Rhizoctonia bataicola and Trichoderma harizanum. All the metal complexes showed stronger antifungal activities than the free ligand. The minimum inhibitory concentrations (MIC) of the metal complexes were found in the range of $10{\sim}31{\mu}g/ml$.

An Experimental Study on Smoothness Regularized LDA in Hyperspectral Data Classification (하이퍼스펙트럴 데이터 분류에서의 평탄도 LDA 규칙화 기법의 실험적 분석)

  • Park, Lae-Jeong
    • Journal of the Korean Institute of Intelligent Systems
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    • v.20 no.4
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    • pp.534-540
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    • 2010
  • High dimensionality and highly correlated features are the major characteristics of hyperspectral data. Linear projections such as LDA and its variants have been used in extracting low-dimensional features from high-dimensional spectral data. Regularization of LDA has been introduced to alleviate the overfitting that often occurs in a small-sized training data set and leads to poor generalization performance. Among them, a smoothness regularized LDA seems to be effective in the feature extraction for hyperspectral data due to its capability of utilizing the high correlatedness. This paper studies the performance of the regularized LDA in hyperspectral data classification experimentally with varying conditions of the training data. In addition, a new dual smoothness regularized LDA is proposed and evaluated that makes use of both the spectral-domain and spatial-domain correlations between neighboring pixels.

Seismic behavior of steel cabinets considering nonlinear connections and site-response effects

  • Tran, Thanh-Tuan;Nguyen, Phu-Cuong;So, Gihwan;Kim, Dookie
    • Steel and Composite Structures
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    • v.36 no.1
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    • pp.17-29
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    • 2020
  • This paper presents experimental and numerical studies on the seismic responses of the steel cabinet facility considering the nonlinear behavior of connections and site-response effects. Three finite element (FE) models with differences of type and number of connections between steel plates and frame members have been developed to demonstrate adequately dynamic responses of structures. The screw connections with the bilinear force-deformation relationship are proposed to represent the inelastic behavior of the cabinet. The experiment is carried out to provide a verification with improved FE models. It shows that the natural frequencies of the cabinet are sensitive to the plate and frame connectors. The screw connections reduce the free vibration compared to the weld one, with decreased values of 2.82% and 4.87% corresponding to front-to-back and side-to-side directions. Additionally, the seismic responses are investigated for various geological configurations. Input time histories are generated so that their response spectrums are compatible with a required response spectrum via the time-domain spectral matching. The results indicate that both site effects and nonlinear behavior of connections affect greatly on the seismic response of structures.

A study on the optimal equation of the continuous wave spectrum

  • Cho, Hong-Yeon;Kweon, Hyuck-Min;Jeong, Weon-Mu;Kim, Sang-Ik
    • International Journal of Naval Architecture and Ocean Engineering
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    • v.7 no.6
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    • pp.1056-1063
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    • 2015
  • Waves can be expressed in terms of a spectrum; that is, the energy density distribution of a representative wave can be determined using statistical analysis. The JONSWAP, PM and BM spectra have been widely used for the specific target wave data set during storms. In this case, the extracted wave data are usually discontinuous and independent and cover a very short period of the total data-recording period. Previous studies on the continuous wave spectrum have focused on wave deformation in shallow water conditions and cannot be generalized for deep water conditions. In this study, the Generalized Extreme Value (GEV) function is proposed as a more-optimal function for the fitting of the continuous wave spectral shape based on long-term monitored point wave data in deep waters. The GEV function was found to be able to accurately reproduce the wave spectral shape, except for discontinuous waves of greater than 4 m in height.

Site effect microzonation of Babol, Iran

  • Tavakoli, H.R.;Amiri, M. Talebzade;Abdollahzade, G.;Janalizade, A.
    • Geomechanics and Engineering
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    • v.11 no.6
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    • pp.821-845
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    • 2016
  • Extensive researches on distribution of earthquake induced damages in different regions have shown that geological and geotechnical conditions of the local soils significantly influence behavior of alluvial areas under seismic loading. In this article, the site of Babol city which is formed up of saturated fine alluvial soils is considered as a case study. In order to reduce the uncertainties associated with earthquake resistant design of structures in this area (Babol city), the required design parameters have been evaluated with consideration of site's dynamic effects. The utilized methodology combines experimental ground ambient noise analysis, expressed in terms of horizontal to vertical (H/V) spectral ratio, with numerical one-dimensional response analysis of soil columns using DEEPSOIL software. The H/V spectral analysis was performed at 60 points, experimentally, for the region in order to estimate both the fundamental period and its corresponding amplification for the ground vibration. The investigation resulted in amplification ratios that were greater than one in all areas. A good agreement between the proposed ranges of natural periods and alluvial amplification ratios obtained through the analytical model and the experimental microtremor studies verifies the analytical model to provide a good engineering reflection of the subterraneous alluviums.

The Effect of Slip on the Convective Instability Characteristics of the Stagnation Point Flow Over a Rough Rotating Disk

  • Mukherjee, Dip;Sahoo, Bikash
    • Kyungpook Mathematical Journal
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    • v.61 no.4
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    • pp.831-843
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    • 2021
  • In this paper we look at the three dimensional stagnation point flow problem over a rough rotating disk. We study the theoretical behaviour of the stagnation point flow, or forced flow, in the presence of a slip factor in which convective instability stationary modes appear. We make a numerical investigation of the effects of slip on the behaviour of the flow components of the stagnation point flow where the disk is rough. We provide, for the first time in the literature, a complete convective instability analysis and an energy analysis. Suitable similarity transformations are used to reduce the Navier-Stokes equations and the continuity equation into a system of highly non-linear coupled ordinary differential equations, and these are solved numerically subject to suitable boundary conditions using the bvp4c function of MATLAB. The convective instability analysis and the energy analysis are performed using the Chebyshev spectral method in order to obtain the neutral curves and the energy bars. We observe that the roughness of the disk has a destabilising effect on both Type-I and Type-II instability modes. The results obtained will be prominently treated as benchmarks for our future studies on stagnation flow.

Spectroscopic Detection of Alfvénic Waves in Chromospheric Mottles of a Solar Quiet Region

  • Kwak, Hannah;Chae, Jongchul
    • The Bulletin of The Korean Astronomical Society
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    • v.46 no.2
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    • pp.78.2-78.2
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    • 2021
  • We present high resolution spectroscopic observations of transverse magnetohydrodynamic (MHD) waves in mottles located near the solar disk center. Different from previous studies that used transversal displacements of the mottles in the imaging data, we investigated the line-of-sight (LOS) velocity oscillations of the mottles in the spectral data. The observations were carried out by using the Fast Imaging Solar Spectrograph of the 1.6 meter Goode Solar Telescope of Big Bear Solar Observatory. Utilizing the spectral data of the Hα and Ca II 8542 Å lines, we measure the LOS velocity of a quiet region including the mottles and rosettes that correspond to the footpoints of the mottles. Our major findings are as follows: (1) Alfvénic waves are pervasive in the mottles. (2) The dominant period of the waves is 2 to 4 minutes. (3) From the time-distance maps of the three-minute filtered LOS velocity constructed along the mottles, it is revealed that the transverse waves in the mottles are closely related to the longitudinal waves in the rosettes. Our findings support the notion that Alfvénic waves can be generated by mode conversion of the slow magnetoacoustic waves as was shown in sunspot regions by Chae et al. (2021).

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An enhanced analytical calculation model based on sectional calculation using a 3D contour map of aerodynamic damping for vortex induced vibrations of wind turbine towers

  • Dimitrios Livanos;Ika Kurniawati;Marc Seidel;Joris Daamen;Frits Wenneker;Francesca Lupi;Rudiger Hoffer
    • Wind and Structures
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    • v.38 no.6
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    • pp.445-459
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    • 2024
  • To model the aeroelasticity in vortex-induced vibrations (VIV) of slender tubular towers, this paper presents an approach where the aerodynamic damping distribution along the height of the structure is calculated not only as a function of the normalized lateral oscillation but also considering the local incoming wind velocity ratio to the critical velocity (velocity ratio). The three-dimensionality of aerodynamic damping depending on the tower's displacement and the velocity ratio has been observed in recent studies. A contour map model of aerodynamic damping is generated based on the forced vibration tests. A sectional calculation procedure based on the spectral method is developed by defining the aerodynamic damping locally at each increment of height. The proposed contour map model of aerodynamic damping and the sectional calculation procedure are validated with full-scale measurement data sets of a rotorless wind turbine tower, where good agreement between the prediction and measured values is obtained. The prediction of cross-wind response of the wind turbine tower is performed over a range of wind speeds which allows the estimation of resulting fatigue damage. The proposed model gives more realistic prediction in comparison to the approach included in current standards.

Short Wave Infrared Imaging for Auroral Physics and Aeronomy Studies

  • Trond S. Trondsen;John Meriwether;Craig Unick;Andrew Gerrard;Matthew Cooper;Devin Wyatt
    • Journal of Astronomy and Space Sciences
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    • v.41 no.2
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    • pp.121-138
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    • 2024
  • Advances in solar-terrestrial physics are generally linked to the development of innovative new sensor technologies, affording us ever better sensitivity, higher resolution, and broader spectral response. Recent advances in low-noise InGaAs sensor technology have enabled the realization of low-light-level scientific imaging within the short-wave infrared (SWIR) region of the electromagnetic spectrum. This paper describes a new and highly sensitive ultra-wide angle imager that offers an expansion of auroral and airglow imaging capabilities into the SWIR spectral range of 900-1,700 nm. The imager has already proven successful in large-area remote sensing of mesospheric temperatures and in providing intensity maps showing the propagation and dissipation of atmospheric gravity waves and ripples. The addition of an automated filter wheel expands the range of applications of an already versatile SWIR detector. Several potential applications are proposed herein, with an emphasis on auroral science. The combined data from this type of instrument and other existing instrumentation holds a strong potential to further enhance our understanding of the geospace environment.

Advances, challenges, and prospects of electroencephalography-based biomarkers for psychiatric disorders: a narrative review

  • Seokho Yun
    • Journal of Yeungnam Medical Science
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    • v.41 no.4
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    • pp.261-268
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    • 2024
  • Owing to a lack of appropriate biomarkers for accurate diagnosis and treatment, psychiatric disorders cause significant distress and functional impairment, leading to social and economic losses. Biomarkers are essential for diagnosing, predicting, treating, and monitoring various diseases. However, their absence in psychiatry is linked to the complex structure of the brain and the lack of direct monitoring modalities. This review examines the potential of electroencephalography (EEG) as a neurophysiological tool for identifying psychiatric biomarkers. EEG noninvasively measures brain electrophysiological activity and is used to diagnose neurological disorders, such as depression, bipolar disorder (BD), and schizophrenia, and identify psychiatric biomarkers. Despite extensive research, EEG-based biomarkers have not been clinically utilized owing to measurement and analysis constraints. EEG studies have revealed spectral and complexity measures for depression, brainwave abnormalities in BD, and power spectral abnormalities in schizophrenia. However, no EEG-based biomarkers are currently used clinically for the treatment of psychiatric disorders. The advantages of EEG include real-time data acquisition, noninvasiveness, cost-effectiveness, and high temporal resolution. Challenges such as low spatial resolution, susceptibility to interference, and complexity of data interpretation limit its clinical application. Integrating EEG with other neuroimaging techniques, advanced signal processing, and standardized protocols is essential to overcome these limitations. Artificial intelligence may enhance EEG analysis and biomarker discovery, potentially transforming psychiatric care by providing early diagnosis, personalized treatment, and improved disease progression monitoring.