• Title/Summary/Keyword: Specific surface are

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Triple-layer Surface Complexation Modeling on the Adsorption of cs-137 and Sr-90 onto Kaolinite: Effect of Groundwater Ions and pH (캐올리나이트의 셰슘-137 및 스트론튬-90 흡착에 대한 삼중층 표면복합반응 모델링: 지하수 이온성분 및 pH의 영향)

  • 정찬호;박상원;김수진
    • Journal of the Mineralogical Society of Korea
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    • v.11 no.2
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    • pp.106-116
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    • 1998
  • The adsorption of Cs-137 and Sr-90 onto kaolinite in prescence of major groundwater cations (Ca2+, K+, Na+) with different concentrations was simulated by using triple-layer surface complexation model (TL-SCM). The site density (8.73 sites/nm2) of kaolinite used for TL-SCM was calculated from it's CEC and specific surface area. TL-SCM modeling results indicate that concentrations dependence on 137Cs and 90Sr adsorption onto kaolinite as a function of pH is best modeled as an outer-sphere surface reaction. This suggests that Cs+ and Sr2+ are adsorbed at the $\beta$-layer in kaolinite-water interface where the electrolytes, Nacl, KCl and CaCl2, bind. However, TL-SCM results on Sr adsorption show a discrepancy between batch data and fitting data in alkaline condition. This may be due to precipitation of SrCO3 and complexation such as SrOH+. Intrinsic reaction constants of ions obtained from model fit are as follows: Kintcs=10-2.10, KintSr=10-2.30, KintK=10-2.80, KintCa=10-3.10 and KintNa=10-3.32. The results are in the agreement with competition order among groundwater ions (K+>Ca2+>Na+) and sorption reference of nuclides (Cs-137>Sr-90) at kaolinite-water interface showed in batch test.

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Comparative assessment of surface and ground water quality using geoinformatics

  • Giridhar, M.V.S.S.;Mohan, Shyama;Kumar, D. Ajay
    • Advances in environmental research
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    • v.9 no.3
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    • pp.151-160
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    • 2020
  • Water quality demonstrates physical, chemical and biological characteristics of water. The quality of surface and groundwater is currently an important concern with population growth and industrialization. Over exploitation of water resources due to demand is causing the deterioration of surface water and ground water. Periodic water quality testing must be carried out to protect our water resources. The present research analyses the spatial variation of surface water and groundwater in and around the lakes of Hyderabad. Twenty-Seven lakes and their neighboring bore water samples are obtained for water quality monitoring. Samples are evaluated for specific physico-chemical parameters such as pH, Total Dissolved Solids (TDS), Cl, SO4, Na, K, Ca, Mg, and Total Hardness (TH). The spatial variation of water quality parameters for the 27 lakes and groundwater were analysed. Correlation and multiple regression analysis were carried out to determine comparative study of lake and ground water. The study found that most of the lakes were polluted and this had an impact on surrounding ground water.

Adsorption and Antibacterial Properties of Metal Ion Treated Activated Carbon Fiber (금속이온이 처리된 활성탄소섬유의 흡착과 항균성)

  • Oh, Won-Chun;Bang, Seong-Ho
    • Analytical Science and Technology
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    • v.13 no.2
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    • pp.131-135
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    • 2000
  • We studied adsorption isotherm, surface properties and antibacterial activity of Cu treated activated carbon fiber (ACF). The BET surface area of Cu treated ACF are distributed to $688.2-887.8m^2/g$. The adsorption results show that BET surface areas move gradually to lower value with increasing treated Cu mole concentration. Using t-method, the specific micropore volumes and average pore size were obtained. From the SEM study, it is also observed that many of micropores in activated carbon fiber are blocked surface after the treatment. And we also observed that the activity of E. coli in kind of colon bacillus increases gradually to larger range with increasing Cu mole ratio. From these results, we suggest the antibacterial mechanism for metal treated ACF.

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Biosurfactants : Their Structures, Properties, and Applications (생체 계면 활성제의 구조, 특성 및 응용)

  • Lim, Kyung-Hee
    • Journal of the Korean Applied Science and Technology
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    • v.13 no.2
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    • pp.1-20
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    • 1996
  • Surfactants are the surface-active molecules that display amphiphilicity, Because of this surface activity and amphiphilicity, surfactants have been used in wide industrial applications such as foods, detergents, cosmetics, medicine, polymers, paints, flotation, textiles. These days, their applications extend to high-technology industries such as microelectronics, magnetic recording material, advanced batteries, novel separations, etc. As new applications of surfactants are found and the demand of the surfactants increases, surfactant industry has been more pressed to face a formidable challenge, which is to develop surfactants that are envirionmentally friendly. In this regard biosurfactants may be alternatives to chemical surfactants, since biosurfactants are biologically compatible, more biodegradable, less toxic, and highly specific. Because of these excellent advantages over those of chemical surfactants, much efforts have been made in biosurfactant research. This article reviews biosurfactants in several aspects, that is, their definition, structures, properties, applications, and prospects.

A Study on the Local Grain Coarsening in Surface of Al 7050 Forged Part (Al 7050 단조품 표면의 입도성장층 방지에 관한 연구)

  • Lee, Jeong-Hwan;Lee, Sang-Yong;Lee, Yeong-Seon
    • 연구논문집
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    • s.26
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    • pp.113-120
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    • 1996
  • Age hardenable aluminium alloys show high specific strength, good thermal and electrical conductivity as well as lightness, and are typical aircraft materials. High fatigue strength and good resistancy against stress corrosion cracking are also important for aircraft aluminium alloys. Al alloy 7050 has been developed to meet the above mentioned requirements and the use of this alloy as forged aircraft part becomes more important. However, forged 7050 parts showed undersiable structures such as severe local grain coarsening in surface area and unproper metal flow that is degrading mechanical properties. In this paper, microstructural aspects of die forging in the Al alloy 7050 are investigated. Also suggested are the optimal forging conditions for microstructural control of Al alloy 7050.

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Influence of Selective Oxidation Phenomena in CGLs on Galvanized Coating Defects Formation

  • Gong, Y.F.;Birosca, S.;Kim, Han S.;De Cooman, B.C.
    • Corrosion Science and Technology
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    • v.7 no.1
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    • pp.1-5
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    • 2008
  • The gas atmosphere in continuous annealing and galvanizing lines alters both composition and microstructure of the surface and sub-surface of sheet steel. The formation and morphology of the oxides of alloying elements in High Strength Interstitial Free (HS-IF), Dual Phase (DP) and Transformation-Induced Plasticity (TRIP) steels are strongly influenced by the furnace dew point, and the presence of specific oxide may result in surface defects and bare areas on galvanized sheet products. The present contribution reviews the progress made recently in understanding the selective formation of surface and subsurface oxides during annealing in hot dip galvanizing and conventional continuous annealing lines. It is believed that the surface and sub-surface composition and microstructure have a pronounced influence on galvanized sheet product surface quality. In the present study, it is shown that the understanding of the relevant phenomena requires a combination of precise laboratory-scale simulations of the relevant technological processes and the use of advanced surface analytical tools.

Seismic analysis of shear wall buildings incorporating site specific ground response

  • Jayalekshmi, B.R.;Chinmayi, H.K.
    • Structural Engineering and Mechanics
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    • v.60 no.3
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    • pp.433-453
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    • 2016
  • During earthquake, the motion of ground is affected significantly by source characteristics, source-to-site path properties and local site conditions. Due to the influence of local soil conditions different places experience distinctive amplitude of surface ground motion. Ground response analysis of a specific site utilizing the borehole information at different locations is done in present study. The ground motion with the highest peak ground acceleration for this site obtained from the ground response analysis is used in finite element soil-structure interaction analysis of multi-storey shear wall buildings with various positions of shear walls. The variation in seismic response of buildings and advantageous position of shear wall are determined. The study reveals that providing shear wall at the core of buildings at the specific site is advantageous among all shear wall configurations considered.

SITE-SPECIFIC ATMOSPHERIC DISPERSION CHARACTERISTICS OF KOREAN NUCLEAR POWER PLANT SITES

  • Han, M.H.;Kim, E.H.;Suh, K.S.;Hwang, W.T.;Choi, Y.G.
    • Journal of Radiation Protection and Research
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    • v.26 no.3
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    • pp.305-309
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    • 2001
  • Site-specific atmospheric dispersion characteristics have been analyzed. The northwest and the southwest wind prevail on nuclear sites of Korea. The annual isobaric surface averaged for twenty years around Korean peninsula shows that west wind prevails. The prevailing west wind is profitable in the viewpoint of radiation protection because three of four nuclear sites are located in the east side. Large scale field tracer experiments over nuclear sites have been conducted for the purpose of analyzing the atmospheric dispersion characteristics and validating a real-time atmospheric dispersion and dose assessment system FADAS. To analyze the site-specific atmospheric dispersion characteristics is essential for making effective countermeasures against a nuclear emergency.

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Directions for Linkages between Policy Measures and the OECD Agricultural Environmental Indicators (OECD 농업환경지표와 정책연계 방안)

  • Kim, Chang-Gil;Kim, Tae-Young
    • Korean Journal of Environmental Agriculture
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    • v.24 no.3
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    • pp.303-313
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    • 2005
  • Agricultural environmental indicators (AEIs) are useful tool for evaluating environmental performance induced by agri-environmental policy measures. General and specific criteria have been set to assess the linkages between policy measures and environmental states. In addition, a number of specific AEIs such as nutrient balance indicators and farm management indicators have been posit to review environmental performance associated with agri-environmental policy measures. The proposed environmental subjects encompass soil quality, qualities of underground and surface water, water resource preservation, species and genetic diversity, diversity for wildlife habitats, and agricultural landscapes. The developed AEIs may contribute to establishment or adjustment of environmental targets and ex-ante or ex-post evaluation for environmental performance associated with policy measures. In addition, the AEIs may be useful to consider introduction of new agri-environmental measures and enhance policy efficiency by assessing environmental performance, considering specific locality, and harmonizing support measures.

Interaction between Particle with Dual Ligand and Cell under Flow (유동장내 길이가 다른 두 개의 리간드가 부착된 입자-세포간 상호작용)

  • Yoon, Jung Hyun;Lee, Sei Young
    • Journal of Biomedical Engineering Research
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    • v.43 no.2
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    • pp.71-80
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    • 2022
  • The interaction between dual-ligand decorated particle-based delivery system and target cell under shear flow is predicted using probability model developed. We assumed the two kinds of ligand are decorated on the surface of the particle with 10% length difference. Fixed with other biophysical parameters, a study on the particle-cell interaction for the different non-specific interaction parameter is performed. To induce the firm adhesion, short ligand-receptor should be engaged. Also, it is shown that the rational design of ligand-receptor interaction, including receptor number, specific interaction parameter, kinds of ligand-receptor, etc., should be considered.