• Title/Summary/Keyword: Specific Energy Absorption

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Solvent Effects on the Solvatochromism of 7-Aminocoumarin Derivatives in Neat and Binary Solvent Mixtures: Correlation of the Electronic Transition Energies with the Solvent Polarity Parameters

  • Choi, Jin-Yeong;Park, Eun-Ju;Chang, Seung-Hyun;Kang, Tai-Jong
    • Bulletin of the Korean Chemical Society
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    • v.30 no.7
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    • pp.1452-1458
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    • 2009
  • The change in the electronic absorption and emission energy of 7-aminocoumarin derivatives in binary solvent mixtures has been studied. The electronic transition energy along with the Stokes' shift is correlated with the orientation polarizability of the solvent as well as the empirical solvent polarity parameters $E_T$ (30). It is observed that the emission peak shift traces the change of $E_T$ (30) value very closely in binary solvent mixtures. The emission transition more strongly depends on the solvent polarity than the absorption, which indicates the dipole moment gets larger on excitation. From the dependence of the Stokes’ shift of 7-aminocoumarins with the solvent polarity parameters and the ground state dipole moment obtained by the semi-empirical calculations, the excited state dipole moment was estimated. The fluorescence lifetime change of 7-aminocoumarins in binary solvent mixtures was measured and the results are explained in terms of molecular conformation and solvent polarity. The study indicates the empirical solvent polarity $E_T$ (30) is a good measure of microscopic solvent polarity and it probes in general the non-specific solvent interactions.

Characterization of Carbon Nanofiber Electrode with different Ketjenblack Conducting Material Mixing Amount Using EDLC (Ketjenblack 전도제 혼합량에 따른 EDLC용 탄소나노섬유 전극의 특성)

  • Choi, Weon-Kyung
    • Transactions of the Korean hydrogen and new energy society
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    • v.19 no.2
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    • pp.163-170
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    • 2008
  • Carbon nanofibers with nano-sized structures were evaluated as a active material using supercacitor electrode which could store electrochemical energy reversibly. A feasibility of EDLC electrode was estimated with specific surface area measurement by BET method and mesopore structure of carbon nanofiber surface could be explained electrochemical absorption-desorption in aqueous electrolyte. A capacitance of carbon nanofiber electrode was increased gradually, depending on the ratio of Ketjenblack as a conducting material. Ketjen Black $20{\sim}25\;wt.%$ ratio in electrode was observed a suitable amount of conducting material by cyclic voltametry results.

The Study of The Collector Efficiency Curve (태양열 집열기 효율곡선에 대한 연구)

  • Shin, J.C.
    • Journal of Energy Engineering
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    • v.23 no.3
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    • pp.198-202
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    • 2014
  • In the solar heat collection system, we can determine how the collector will perform under specific conditions from the efficiency curve. By understanding the basic principles which govern the operation, designers can maximize the output from the collector. Absorptance, transmission and the total heat transfer coefficient were introduced to induce this efficiency curve. Designers who can make use of the implicit information on the curve in this report will generate systems which obtain the best return from their client's investment.

Electrochemical Properties of Carbon Nanofiber Electrode with Different PVDF Binder Concentration (PVDF 접합제 농도 변화와 탄소나노섬유 전극의 전기화학적 특성)

  • Choi, Weon-Kyung;Cho, Tae-Hwan
    • Transactions of the Korean hydrogen and new energy society
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    • v.18 no.4
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    • pp.446-451
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    • 2007
  • Physicochemical properties of carbon nanofibers were evaluated as a supercacitor electrode materials could store electrochemical energy reversibly. A capacitance of carbon nanofiber electrode was increased gradually, depending on the PVDF binder ratio. A feasibility of EDLC electrode was estimated with specific surface area measurement by BET method and mesopore structure of carbon nanofiber surface could be explained electrochemical absorption-desorption in aqueous electrolyte. PVDF 5 wt.% ratio in electrode was observed a suitable binder amount by CV result.

Multidisciplinary optimization of collapsible cylindrical energy absorbers under axial impact load

  • Mirzaei, M.;Akbarshahi, H.;Shakeri, M.;Sadighi, M.
    • Structural Engineering and Mechanics
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    • v.44 no.3
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    • pp.325-337
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    • 2012
  • In this article, the multi-objective optimization of cylindrical aluminum tubes under axial impact load is presented. The specific absorbed energy and the maximum crushing force are considered as objective functions. The geometric dimensions of tubes including diameter, length and thickness are chosen as design variables. D/t and L/D ratios are constricted in the range of which collapsing of tubes occurs in concertina or diamond mode. The Non-dominated Sorting Genetic Algorithm-II is applied to obtain the Pareto optimal solutions. A back-propagation neural network is constructed as the surrogate model to formulate the mapping between the design variables and the objective functions. The finite element software ABAQUS/Explicit is used to generate the training and test sets for the artificial neural networks. To validate the results of finite element model, several impact tests are carried out using drop hammer testing machine.

Low-velocity Impact Characterization of Laminated Composite Materials (복합재료의 저속충격 특성)

  • Han, Ji-Won
    • Journal of the Korean Society of Safety
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    • v.23 no.6
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    • pp.34-37
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    • 2008
  • The composite materials are widely used in the many applications of industry as well as aerospace field because of their high specific stiffness and strength which benefits the material and provides potential energy savings. However, composite materials also have a low property about external applied impact. In this paper, impact tests were conducted on different sample types(glass, carbon and kevlar composite) to obtain information such as absorbed energy and composite deformation using an instrumented impact test machine (DYNATUP 8250). 3 type samples were compared to experimental results. The data from impact test provided valuable information between the different type samples by wet lay up. This paper shows results of that kevlar composite has larger absorption energy and deformation than others.

The research on static and dynamic mechanical properties of concrete under the environment of sulfate ion and chlorine ion

  • Nie, Liangxue;Xu, Jinyu;Bai, Erlei
    • Computers and Concrete
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    • v.20 no.2
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    • pp.205-214
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    • 2017
  • The Hydraulically driven test system and ${\Phi}100mm$ split Hopkinson pressure bar(SHPB) test device were employed to research the quasi-static and dynamic mechanical properties of concrete specimens which has been immersed for 60 days in sodium sulfate (group S1) and sodium chloride (group S2) solution, the evolution of their mass during corrosive period was explored at the same time, and the mechanism of performances lost was analyzed from the microscopic level by using scanning electron microscope. Results of the experimental indicated that: their law of mass both presents the trend of continuous rising during corrosive period, and it increases rapidly on the early days, the mass growth of group S1 and group S2 in first 7 days are 76.78% and 82.82% of their total increment respectively; during the corrosive period, the quasi-static compressive strength of specimens in two groups are significantly decreased, both of which present the trend of increase first and then decrease, the maximum growth rate of group S1 and group S2 are 7.52% and 12.71% respectively, but they are only 76.23% and 82.84% of specimens which under normal environment (group N) on day 60; after immersed for 60 days, there were different decrease to dynamic compressive strength and specific energy absorption, and so as their strain rate sensitivities. So the high salinity environment has a significant effect of weaken the quasi-static and dynamic mechanical performance of concrete.

Low Speed Crash Behaviour of Aluminium Bumper System W.R.T. Design Variables (설계변수에 따른 알루미늄 범퍼 시스템의 저속 충돌해석)

  • Kim, Dae Young;Han, Bo Seok;Hong, Min Sun;Kim, Dong Ok;Cheon, Seong Sik
    • Transactions of the Korean Society of Automotive Engineers
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    • v.25 no.1
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    • pp.11-18
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    • 2017
  • In the present study, the low speed (4 km/h) crash behaviour of an aluminium bumper system was characterised by FE analyses based on the FMVSS 581, which regulates automotive bumpers. Two types of cross-sectional designs, i.e., Model 1, which contains a single rib and Model 2, double ribs, have been considered along with Al7021, 6082 and 6060 for the aluminium bumper back beam. Variations in thickness starting from 2 to 4 mm of the bumper system cross-section in the FE model was implemented in order to investigate the thickness effect on the bumper's crash behaviour.. Three kinds of design variables, namely, number of ribs, material and thickness, are considered. The FE analysis results are summarised with the maximum load and the Specific Energy Absorption (SEA) since they are the key factors in determining the crashworthiness of automotive structures. The results may also be able to indicate how to achieve lightweight structure of the automotive bumper system either directly or indirectly.

Multi-objective optimization of tapered tubes for crashworthiness by surrogate methodologies

  • Asgari, Masoud;Babaee, Alireza;Jamshidi, Mohammadamin
    • Steel and Composite Structures
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    • v.27 no.4
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    • pp.427-438
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    • 2018
  • In this paper, the single and multi-objective optimization of thin-walled conical tubes with different types of indentations under axial impact has been investigated using surrogate models called metamodels. The geometry of tapered thin-walled tubes has been studied in order to achieve maximum specific energy absorption (SEA) and minimum peak crushing force (PCF). The height, radius, thickness, tapered angle of the tube, and the radius of indentation have been considered as design variables. Based on the design of experiments (DOE) method, the generated sample points are computed using the explicit finite element code. Different surrogate models including Kriging, Feed Forward Neural Network (FNN), Radial Basis Neural Network (RNN), and Response Surface Modelling (RSM) comprised to evaluate the appropriation of such models. The comparison study between surrogate models and the exploration of indentation shapes have been provided. The obtained results show that the RNN method has the minimum mean squared error (MSE) in training points compared to the other methods. Meanwhile, optimization based on surrogate models with lower values of MSE does not provide optimum results. The RNN method demonstrates a lower crashworthiness performance (with a lower value of 125.7% for SEA and a higher value of 56.8% for PCF) in comparison to RSM with an error order of $10^{-3}$. The SEA values can be increased by 17.6% and PCF values can be decreased by 24.63% by different types of indentation. In a specific geometry, higher SEA and lower PCF require triangular and circular shapes of indentation, respectively.

Development of an Algorithm for Predicting the Thermal Distribution by using CT Image and the Specific Absorption Rate

  • Hwang, Jinho;Kim, Aeran;Kim, Jina;Seol, Yunji;Oh, Taegeon;Shin, Jin-sol;Jang, Hong Seok;Kim, Yeon Sil;Choi, Byung Ock;Kang, Young-nam
    • Journal of the Korean Physical Society
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    • v.73 no.10
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    • pp.1584-1588
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    • 2018
  • During hyperthermia therapy, cancer cells are heated to a temperature in the range of $40{\sim}45^{\circ}C$ for a defined time period to damage these cells while keeping healthy tissues at safe temperatures. Prior to hyperthermia therapy, the amount of heat energy transferred to the cancer cells must be predicted. Among various non-invasive methods, the thermal prediction method using the specific absorption rate (SAR) is the most widely used method. The existing methods predict the thermal distribution by using a single constant for the mass density in one organ through assignment. However, because the SAR and the bio heat equation (BHE) vary with the mass density, the mass density of each organ must be accurately considered. In this study, the mass density distribution was calculated using the relationship between the Hounsfield unit and the mass density of tissues in preceding research. The SAR distribution was found using a quasi-static approximation to Maxwell's equation and was used to calculate the potential distribution and the energy distributions for capacitive RF heating. The thermal distribution during exposure to RF waves was determined by solving the BHE with consideration given to the considering contributions of heat conduction and external heating. Compared with reference data for the mass density, our results was within 1%. When the reconstructed temperature distribution was compared to the measured temperature distribution, the difference was within 3%. In this study, the density distribution and the thermal distribution were reconstructed for the agar phantom. Based on these data, we developed an algorithm that could be applied to patients.