• Journal of the Korean Ceramic Society
• /
• v.33 no.7
• /
• pp.832-838
• /
• 1996

Thermite reaction products of MgO and Al were added to MgO-C refractory to improve the properties of corrosion against the attack of slag, oxidation and mechanical spalling. Corrosion rate of MgO-C-MgAl2O4 spinel refractory at the ratio of 3.3(CaO/SiO2) slag was smaller than that of MgO-C and MgO-C-Al refractory. The excellent corrosion resistance of the MgO-C-MgAl2O4 spinel refractory against the slag attack was appeared by Al and MgAl2O4 spinel with high melting point and corrosion resistance and the high thermal conductivity and low thermal expansion of AIN. Hot M.O.R at 140$0^{\circ}C$ and the resistance of oxidation weight loss at 90$0^{\circ}C$ were 210kg/cm2 and -12% respectively.

• Proceedings of the Korea Institute of Fire Science and Engineering Conference
• /
• 2009.04a
• /
• pp.147-154
• /
• 2009

화재와 같은 고온의 환경에서 콘크리트의 고강도화는 폭렬(Explosive Spalling)이라는 큰 위험성을 가지고 있으며, 이러한 폭렬의 원인으로는 콘크리트 내부의 수증기압이 가장 큰 원인으로 제기되고 있다. 본 논문은 콘크리트의 폭렬발생 있어서 압축강도 및 함수율이 초기 폭렬특성에 미치는 영향을 실험적으로 검토하기위하여 건축구조물의 화재 온도조건인 ISO834 화재온도이력곡선을 15분, 30분 적용하여 콘크리트의 초기 폭렬특성을 검토하였다. 그 결과 압축강도 가열시간 함수율이 증가할수록 폭렬발생 및 폭렬현상이 증대되는 경향이 나타났으며, 15분, 30분 가열시간에 따른 잔존강도율을 나타내었다. 또한, 압축강도 및 함수율에 따른 폭렬발생영역을 분석하였으며, 압축강도 50${\sim}$100 MPa의 경우 함수율 3%이하, 100 MPa이상의 경우는 1%이하로 제어할 경우 폭렬현상이 발생하지 않을 것으로 판단되었다.

• Advances in concrete construction
• /
• v.6 no.3
• /
• pp.311-322
• /
• 2018

This paper presents an experimental investigation on the performance of concrete with and without glass powder (GP) subjected to elevated temperatures. Mechanical and physicochemical properties of concretes were studied at both ambient and high temperatures. One of the major environmental concerns is disposal or recycling of the waste materials. However, a high volume of the industrial production has generated a considerable amount of waste materials which have a number of adverse impacts on the environment. Further, use of glass or by-products in concrete production has advantages for improving some or all of the concrete properties. The economic incentives and environmental benefits in terms of reduced carbon footprint are also the reason for using wastes in concrete. The occurrence of spalling, compressive strength, mass loss, chemical composition, crystalline phase, and thermal analysis of CPG before and after exposure to various temperatures (20, 200, 400, and $600^{\circ}C$) were comprehensively investigated. The results indicated that, the critical temperature range of CPG was between $400^{\circ}C$ and $600^{\circ}C$.

• Journal of the Korean Ceramic Society
• /
• v.34 no.1
• /
• pp.63-69
• /
• 1997

The effects of Cr2O3 content on the properties of direct-bonded MgO-Cr2O3 bricks were investigated in the range of 10 to 30 wt% of Cr2O3. Modulus of rupture of bricks was excellent in about 20 wt% of Cr2O3 content. The corrosion resistance of bricks was improved by increasing Cr2O3 content and was directly pro-portional to the amount of secondary spinels. On the other hand, the spalling resistance of bricks depended on the amount of flux rather than Cr2O3 content.

• Proceedings of the Korean Institute of Building Construction Conference
• /
• 2007.04a
• /
• pp.55-58
• /
• 2007

This study investigates the spatting properties of high strength concrete, $60\sim80MPa$ class, designed with diverse aspect ratios and fiber content of nylon(NY). Test showed that increase of fiber content and aspect ratio in concrete decreased the fluidity of fresh concrete, especially for 1580 and 3000 aspect ratio of fiber. As for the compressive and tensile strength, adding NY fiber did not significantly affect the values In the range of high strength. After completing the fire test, the specimens containing both 750 and 1000 aspect ratios of fiber protected the spatting occurrence even in 0.05vol.% of fiber content. This specimens indicated the residual compressive strength ratio at 37%, showing the most favorable value among other specimens. Therefore, it is demonstrated that to protect the spalling in high strength concrete considering the effective fluidity, strength and economic efficiency altogether, adding 0.05vol.% of NY fiber with 750 aspect ratio Is beneficial.

• Journal of the Korean Ceramic Society
• /
• v.31 no.7
• /
• pp.759-766
• /
• 1994

The effect of additives on properties of unfired Al2O3-C bricks were investigated. The increase of carbon content and the addition of MgO or spinel improved the resistances against spalling and corrosion of unfired Al2O3-C bricks. Also, the oxidation resistance of unfired Al2O3-C brick was increased by adopting complex metals of Al and Si in spite of the increase of carbon content.

• Journal of the Korean Ceramic Society
• /
• v.27 no.7
• /
• pp.877-882
• /
• 1990

Effects of metallic Al powder addition on basic and thermal properties of castable refractories were investigated. Generally, low grade prooperties were obtained by metallic Al powder addition with the increase of temperature, comparing with those of non-addition of Al powder. Especially, Al addtion showed severe shrinkage, corrosiion and low strength above 1000$^{\circ}C$. As a result of Al addition, lower strength of and higher corrosion resistance were shown for 2% addition, but it was reversed for above 4% addition. It was found that Al addition was excellent in the explosive spalling test regardless of Al quantity.

• Journal of the Korean Society of Fisheries and Ocean Technology
• /
• v.14 no.2
• /
• pp.69-78
• /
• 1978

It is well known that the aluminizing steel is excellent in corrosion resistance and heat resistance. Therefore it has been used as boiler parts, heat exchanger parts and guide rails which are used under comparatively simple conditions. Recently, it has been noticed that aluminizing steel has high resistance to various atmosphere, high temperature oxidation and seawater resistance. So its usage has been extended widely to the production of parts such as intake and exhaust valve of internal combustion engine, turbine blade and pipelines On ships which required such properties. It is considered that aluminium coated steel is excellent in wear resistance because of high hardness on main ingredient FezAIs of Fe-AI alloy layer existed in diffusion coating layer. And it will beused as a new material taking wear resitance with seawater resistance in marine field. However it is difficult to findout any report concering the wear behaviors or properties of alum in izing steel. In this study the experiment was carried out under the condition of rolling-sliding contact using an Amsler-type wear testing machine at 0.80, 0.91, 1. 10, 1. 25% of slip ratio and 55.43, 78.38, 110.85 kg/mm^2 of Hertz's contact stress in run-in period for the purpose of service-ability test of aluminizing steel as a wear resisting material and obtaining the available design data. The followings are the obtained results from the experimen tal study; 1) The 2nd diffusion material has most excellent wear resistance. This material has brought out about 18% decrease of wear weight in a lower friction load level and 40~G decrease in a higher level comparing to the raw material. 2) Satisfactory effect of wear resistivity cannot be much expected in 2nd diffusion specimens. This is considered due to the formation of fine void in the alloy layer near the boundary to the aluminium layer. 3) Fracture on friction surface of aluminizing steel by the rolling-sliding contact is spalling, and spalling crack occurres initially beneath the specimen surface near the boundary in diffusion coating layer.

• Proceedings of the Korea Concrete Institute Conference
• /
• 2008.11a
• /
• pp.689-692
• /
• 2008

HSC(High Strength Concrete) have superior properties well as improvement in durability compared with normal strength concrete. In spite of durability of HSC, explosive spalling of concrete is serious problem in structure safety. Therefore, Solving methods are required to control the explosive spalling. The properties of concrete are affected by changes of temperatures. Compressive strength and elasticity modulus were degraded depending on a rise of temperatures. Also, change in microstructure and dehydration of concrete subjected to high temperatures. This paper is concerned with change in microstructure and dehydration of the alumino silicate fire protection materials at high temperatures. The testing methods of fire protection materials in high temperature properties are make use of SEM, TG-DSC and XRD. From the experimental test results, influence of high temperatures on microstructure of alumino-silicate fire protection material was identified, including chemical dehydration of C-S-H and CH. The chemical dehydration of CH under various temperatures from to 450 to 600$^{\circ}$C has been measured using the TG-DSC. However, developed alumino silicate fire protection materials showed good stability in high Temperatures. Thus, the results indicate that it is possible to fireproof panels, fire protection of materials.

• Journal of the Korea institute for structural maintenance and inspection
• /
• v.12 no.4
• /
• pp.115-122
• /
• 2008

This paper is to investigate the affecting factors on spalling of the high strength concrete including W/B, air content and moisture condition as well as PP fiber contents subjected to fire. An increase with 0.05% of PP fiber resulted in a reduction of slump flow by as much as 11%. Ten percent of air contents due to excessive amounts of AE agent does not lead to variance of slump flow, regardless of PP fiber content. For the effect of the compressive strength, high strength concrete with 15, 25 and 35% of W/B gained 60 MPa~100 MPa of the compressive strength. High strength concrete with H-air had half of compressive strength of that with L-air due to large amount of air. Fire test was conducted in accordance with KS F 2257-1 for 1 hour. Spalling did not occur with all specimens containing more than 0.10% of PP fiber except those with 15% of W/B. Moreover, it is interesting to note that the specimens with more than 10% of air content and with oven dried condition, respectively, had no spalling even if the content of PP fiber is 0.05 vol.%.