• Nuclear Engineering and Technology
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• v.34 no.1
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• pp.42-59
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• 2002

In order to transmute long-lived radioactive nuclides such as transuranics(TRU), Tc-99, and I- l29 in LWR spent fuel, a preliminary conceptual design study has been performed for the accelerator driven subcritical reactor system, called HYPER(Hybrid Power Extraction Reactor) The core has a hybrid neutron energy spectrum: fast and thermal neutrons for the transmutation of TRU and fission products, respectively. TRU is loaded into the HYPER core as a TRU-Zr metal form because a metal type fuel has very good compatibility with the pyre- chemical process which retains the self-protection of transuranics at all times. On the other hand, Tc-99 and I-129 are loaded as pure technetium metal and sodium iodide, respectively. Pb-Bi is chosen as a primary coolant because Pb-Bi can be a good spallation target and produce a very hard neutron energy spectrum. As a result, the HYPER system does not have any independent spallation target system. 9Cr-2WVTa is used as a window material because an advanced ferritic/martensitic steel is known to have a good performance under a highly corrosive and radiation environment. The support ratios of the HYPER system are about 4∼5 for TRU, Tc-99, and I-129. Therefore, a radiologically clean nuclear power, i.e. zero net production of TRU, Tc-99 and I-129 can be achieved by combining 4 ∼5 LWRs with one HYPER system. In addition, the HYPER system, having good proliferation resistance and high nuclear waste transmutation capability, is believed to provide a breakthrough to the spent fuel problems the nuclear industry is faced with.

• Korean Journal of Materials Research
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• v.31 no.8
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• pp.439-444
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• 2021

The oxidation resistance of the diffusion aluminide bond coat (BC) is compromised largely by interdiffusion (ID) effects on coated turbine blades of aeroengines. The present study is designed to understand the influence of ID on βNiAl coatings or BC. In this regard, nickel substrate and CMSX-4 superalloy are deposited. In total, four sets of BCs are developed, i.e. pure βNiAl (on Ni substrate), simple βNiAl (on CMSX-4 substrate), Zr-βNiAl (on CMSX-4 substrate) and Pt-βNiAl (on CMSX-4 substrate). The main aim of this study is to understand the interdiffusion of Al, Zr and Pt during preparation and oxidation. In addition, the beneficial effects of both Zr and platinum are assessed. Pure βNiAl and simple βNiAl show Ni-out-diffusion, whereas for platinum inward diffusion to the substrate is noticed under vacuum treatment. Interestingly, Zr-βNiAl shows the least ID in all BCs and exhibit stability under both vacuum and oxidation treatments. However, its spallation resistance is slightly lower than that of Pt-βNiAl BC. All BCs show similar oxide growth trends, except for Zr-βNiAl, which exhibits two-stage oxidations, i.e. transient and steady-state. Moreover, it is suggested that the localized spallation in all BCs is caused by βNiAl - γ'-Ni₃Al transformation.

• Journal of Powder Materials
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• v.28 no.3
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• pp.201-207
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• 2021

Ni-Cr-Al metal-foam-supported catalysts for steam methane reforming (SMR) are manufactured by applying a catalytic Ni/Al₂O₃ sol-gel coating to powder alloyed metallic foam. The structure, microstructure, mechanical stability, and hydrogen yield efficiency of the obtained catalysts are evaluated. The structural and microstructural characteristics show that the catalyst is well coated on the open-pore Ni-Cr-Al foam without cracks or spallation. The measured compressive yield strengths are 2-3 MPa at room temperature and 1.5-2.2 MPa at 750℃ regardless of sample size. The specimens exhibit a weight loss of up to 9-10% at elevated temperature owing to the spallation of the Ni/Al₂O₃ catalyst. However, the metal-foam-supported catalyst appears to have higher mechanical stability than ceramic pellet catalysts. In SMR simulations tests, a methane conversion ratio of up to 96% is obtained with a high hydrogen yield efficiency of 82%.

• Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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• 2002.10b
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• pp.185-186
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• 2002

Fretting of fuel rod cladding material, Zircaloy-4 tube, in PWR nuclear power plants must be reduced and avoided. Nowadays the introduction of surface treatments or coatings is expected to be an ideal solution to fretting damage since fretting is closely related to wear. corrosion and fatigue. Therefore. in this study the fretting wear experiment was performed using TiAlN coated Zircaloy-4 tube as the fuel rod cladding and uncoated Zircaloy-4 as on of grids, especially concentrating on the sliding component. Fretting wear resistance of TiAlN coated Zircaloy-4 tubes was improved compared with that of TiN coated tubes and uncoated tubes and fretting wear mechanisms were brittle fracture and plastic flow at lower slip amplitude but severe oxidation and spallation of oxidative layer at higher ship amplitude.

• Journal of the Korean Ceramic Society
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• v.32 no.4
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• pp.471-481
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• 1995

Unirradiated UO2 pellets were pulverized by oxidation in air at 40$0^{\circ}C$, and the oxidized powders were reduced in H2 and CO atmospheres at $600^{\circ}C$. During the oxidation of UO2 at 40$0^{\circ}C$, intergranular cracks which caused the spallation were mainly developed by the volume contraction due to the formation of intermediate phase (U4O9 or U3O7). As oxidation proceeded, U3O8 finally formed. As the oxidation/reduction cycles were repeated, the powder surface became coarser, specific surface area was increased and average particle size was decreased. The sintered densities of the powder were increased by the oxidation/reduction cycle due to the characteristic changes of the powder.

• Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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• 2002.05a
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• pp.88-95
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• 2002

Fretting of fuel rod cladding material, Zircaloy-4 Tube, in PWR nuclear power plants must be reduced and avoided. Nowadays the introduction of surface treatments or coatings is expected to bean ideal solution to fretting damage since fretting is closely related to wear, corrosion and fatigue. Therefore, in this study the fretting wear experiment was peformed using TiAIN coated Zircaloy-4 tube as the fuel rod cladding and uncoated Zircaioy-4 tube as one of grids, especially concentrating on the sliding component. Fretting wear resistance of TiAIN coated Zircaloy-4 tubes was improved compared with that of TiN coated tubes and uncoated tubes and the fretting wear mechanisms were delamination and plastic flow following by brittle fracture at lower slip amplitude but severe oxidation and spallation of oxidative layer at higher slip amplitude.

• Journal of the Korean Society for Precision Engineering
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• v.31 no.1
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• pp.15-20
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• 2014

Thermal barrier coating (TBC) is used to protect the substrate and extend the operating life of the gas turbine for a power plant and an aircraft. The major cause of failure of such a coating is the spallation of coating, and it results from the thermal stress between top coating and bond coating. To improve the durability of TBC system, the dense vertical cracked (DVC) coating method to insert vertical cracks is applied to a gas turbine blade. In this study, a criterion for the design of vertical crack in the DVC coating was presented using the finite element analysis.

• Geomechanics and Engineering
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• v.12 no.1
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• pp.1-8
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• 2017

An experimental technique for determining the spalling strength of rock-like materials under a high strain rate is developed. It is observed that the spalling strength of a specimen can be determined by only knowing the wavelength, loading peak value and length of the first spallation of an incident wave under a specific loading waveform. Using this method in combination with a split-Hopkinson pressure bar (SHPB) and other experimental devices, the spalling strength of granite specimens under a high strain rate is tested. Comparisons with other experimental results show that the new measuring method can accurately calculate the dynamic tensile strength of rock materials under a high strain rate.

• Journal of the Korean Society of Safety
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• v.23 no.4
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• pp.25-29
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• 2008

Recently, new functionally graded material(FGM) that has a spatial variation in composition and properties is developed because of its good quality. This material yields the demands for resistance to corrosion and high temperature in turbine blade, wear resistance as in gears and high strength machine parts. Especially coating treatment in FGM surface brings forth a mechanical weak at the interface due to discontinuous stress resulting from a steep material change. It often, leads cracks or spallation in a coating area around an interface. The behavior of propagation cracks in FGMs was here investigated. The interface stresses were reduced because of graded material properties. Also graded material parameter with exponential equation was founded to influence the stress intensity factor. And the resistance curve with FGM coating was slightly increased.

• Journal of Ocean Engineering and Technology
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• v.12 no.3 s.29
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• pp.42-48
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• 1998

구형 관입시험에 의한 얼음의 균열을 연구 하였다. $-10^{circ}C$에서 S2 기둥얼음의 시편(152mm X 152mm X 152mm)에 stainless 강으로 된 구(지름 25.4mm)로 하중을 가하였다. 구형indentor는 얼음 시편의 장축인 기둥방향에 수직으로 하중을 가하였으며 이때 변위율은 0.038mm/s로 하여 단조증가 하중 시험을 하였다. 하중을 가하기 시작하면 indentor 하부에서 crushing 이 발생하고, 하중이 증가함에 따라서 방사선 균열 또는 횡균열이 성장하여 splitting 또는 spallation이 발생하였다. 단조증가 하중 때와 동일한 indentor를 사용하여 하중 및 비하중율 0.5KN/s로 맥박하중을 가할 때 이들 방사선 균열 및 횡 균열이 발생 성장하였다. 첫 맥박 하중의 크기는 1KN으로 하고 그 뒤 계속 이어지는 시험은 맥박 하중의 크기를 증가시킨 뒤 행하였으며 균열 길이는 맥박과 맥박 사이에서 계측 하였다. 기타 취성고체에서 관찰 되었던 것과 같이 방사선 균열 및 측면균열의 길이는 impression 반지름과 하나의 지수법칙이 성립함을 보여주었다.