• Title/Summary/Keyword: Soret Effect

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Degradation of Functional Materials in Temperature Gradients - Thermodiffusion and the Soret Effect

  • Janek, Jurgen;Sann, Joachim;Mogwitz, Boris;Rohnke, Marcus;Kleine-Boymann, Matthias
    • Journal of the Korean Ceramic Society
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    • v.49 no.1
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    • pp.56-65
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    • 2012
  • Functional materials are often exposed to high temperatures and inherent temperature gradients. These temperature gradients act as thermodynamic driving forces for the diffusion of mobile components. The detailed consequences of thermodiffusion depend on the boundary conditions of the non-isothermal sample: Once the boundaries of the sample are inert and closed for exchange of the mobile components, thermodiffusion leads to their pile-up in the stationary state (the so called Soret effect). Once the system is open for an exchange of the mobile component, chemical diffusion adds to the Soret effect, and stationary non-zero component fluxes are additionally observed in the stationary state. In this review, the essential aspects of thermodiffusion and Soret effect in inorganic functional materials are briefly summarized and our current practical knowledge is reviewed. Major examples include nonstoichiometric binary compounds (oxides and other chalcogenides) and ternary solid solutions. The potential influence of the Soret effect on the long term stability of high temperature thermoelectrics is briefly discussed. Typical Soret coefficients for nonstoichiometric compounds are found to be of the order of (d${\delta}$/dT) ${\approx}$ 1%/K.

A Study on Buoyancy Effects in Double-Diffusive Convecting System(II) - Theoretical Study - (이중확산 대류계에서의 부력효과에 관한 연구(II) - 이론적 연구 -)

  • Hong, Nam-Ho;Kim, Min-Chan;Hyun, Myung-Taek
    • Journal of Ocean Engineering and Technology
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    • v.13 no.2 s.32
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    • pp.129-137
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    • 1999
  • The time of the onset of double-diffusive convection in time-dependent, nonlinear concentration fields is investigated theoretically. The initially quiescent horizontal fluid layer with a uniform temperature gradient experiences a sudden concentration change from below, but its stable thermal stratification affects concentration effects in such way to invoke convective motion. The related stability analysis, including Soret effect, is conducted on the basis of the propagation theory. Under the linear stability theory the concentration penetration depth is used as a length scaling factor, and the similarity transform for the linearized perturbation equations. The newlly obtained stability equations are solved numerically. The resulting critical time to mark the onset of regular cells are obtained as a function of the thermal Rayleigh number, the solute Rayleigh number, and the Soret effect coefficient. For a certain value of the Soret effect coefficient, the stable thermal gradient promote double-diffusive convective motion.

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Soret effect on the convective instability in binary nanofluids (Soret 효과를 고려한 이성분 나노유체에서의 대류 불안정성 해석)

  • Kim Jake;Jung Chung Woo;Kang Yong Tae;Choi Chang Kyun
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.17 no.3
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    • pp.256-261
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    • 2005
  • The objective of the present study is to study the Soret effect of both nanoparticles and solute on the convective instabilities in binary nanofluids. A new stability criterion is obtained based on the linear stability theory. The results show that the Soret effect of solute(${\psi}_{bf}$) makes the binary nanofluids unstable significantly and the convective motion in a binary nanofluid sets in easily as the ratio of Soret coefficient of nanofluid to that of binary basefluid ${\delta}_4$ increases for ${\delta}_4$ > -1. It is also found that as an increase of the volume fraction of nanoparticles, nanofluid becomes stable but at a separation ratio of ${\psi}=-0.3$ the state of fluid changes from stable to unstable.

SORET AND ELECTROMAGNETIC RADIATION EFFECT OF MHD MICRO POLAR FLUID PAST A POROUS MEDIUM IN THE PRESENCE OF CHEMICAL REACTION

  • SHEEBA JULIET S.;VIDHYA, M.
    • Journal of applied mathematics & informatics
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    • v.41 no.5
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    • pp.1085-1102
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    • 2023
  • In this study the magneto hydrodynamic (MHD) micro polar fluid flow of a viscous incompressible fluid past a porous medium in the presence of chemical reaction is considered. This work is devoted to investigate the Soret effect and Electromagnetic radiation effect and analyze analytically. In the energy equation the applied magnetic field strength and in the concentration equation the Soret effect are incorporated. The basic PDE (partial differential equations) are reduced to ODE (ordinary differential equations) using non dimensional variables. Then the analytical solution of the dimensionless equations are found using perturbation technique. The features of the fluid flow parameters are analyzed, discussed and explained graphically. The graphical solutions are found using MATLAB R2019b. Skin friction coefficient at the wall, Couple stress coefficient at the plate and the local surface heat flux are also thoroughly examined. Overall, this study sheds light on the complex interplay between physical parameters in the behavior of MHD micro-polar fluid past a porous medium in the presence of chemical reaction.

SORET, HALL CURRENT, ROTATION, CHEMICAL REACTION AND THERMAL RADIATION EFFECTS ON UNSTEADY MHD HEAT AND MASS TRANSFER NATURAL CONVECTION FLOW PAST AN ACCELERATED VERTICAL PLATE

  • VENKATESWARLU, M.;LAKSHMI, D. VENKATA;RAO, K. NAGA MALLESWARA
    • Journal of the Korean Society for Industrial and Applied Mathematics
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    • v.20 no.3
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    • pp.203-224
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    • 2016
  • The heat and mass transfer characteristics of the unsteady hydromagnetic natural convection flow with Hall current and Soret effect of an incompressible, viscous, electrically conducting, heat absorbing and optically thin radiating fluid flow past a suddenly started vertical infinite plate through fluid saturated porous medium in a rotating environment are taken into account in this paper. Derivations of exact analytical solutions are aimed under different physical properties. The velocity, concentration and temperature profiles, Sherwood number and Nusselt number are easily examined and discussed via the closed forms obtained. Soret effect and permeability parameter tends to accelerate primary and secondary fluid velocities whereas hall current, radiation and heat absorption have reverse effect on it. Radiation and heat absorption have tendency to enhance rate of heat transfer at the plate. The results obtained here may be further used to verify the validity of obtained numerical solutions for more complicated transient free convection fluid flow problems.

EFFECTS OF SORET AND DUFOUR ON NATURAL CONVECTIVE FLUID FLOW PAST A VERTICAL PLATE EMBEDDED IN POROUS MEDIUM IN PRESENCE OF THERMAL RADIATION VIA FEM

  • RAJU, R. SRINIVASA
    • Journal of the Korean Society for Industrial and Applied Mathematics
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    • v.20 no.4
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    • pp.309-332
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    • 2016
  • Finite element method has been applied to solve the fundamental governing equations of natural convective, electrically conducting, incompressible fluid flow past an infinite vertical plate surrounded by porous medium in presence of thermal radiation, viscous dissipation, Soret and Dufour effects. In this research work, the results of coupled partial differential equations are found numerically by applying finite element technique. The sway of significant parameters such as Soret number, Dufour number, Grashof number for heat and mass transfer, Magnetic field parameter, Thermal radiation parameter, Permeability parameter on velocity, temperature and concentration evaluations in the boundary layer region are examined in detail and the results are shown in graphically. Furthermore, the effect of these parameters on local skin friction coefficient, local Nusselt number and Sherwood numbers is also investigated. A very good agreement is noticed between the present results and previous published works in some limiting cases.

SORET AND CHEMICAL REACTION EFFECTS ON THE RADIATIVE MHD FLOW FROM AN INFINITE VERTICAL POROUS PLATE

  • MALAPATI, VENKATESWARLU;DASARI, VENKATA LAKSHMI
    • Journal of the Korean Society for Industrial and Applied Mathematics
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    • v.21 no.1
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    • pp.39-61
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    • 2017
  • In this present article, we analyzed the heat and mass transfer characteristics of the nonlinear unsteady radiative MHD flow of a viscous, incompressible and electrically conducting fluid past an infinite vertical porous plate under the influence of Soret and chemical reaction effects. The effect of physical parameters are accounted for two distinct types of thermal boundary conditions namely prescribed uniform wall temperature thermal boundary condition and prescribed heat flux thermal boundary condition. Based on the flow nature, the dimensionless flow governing equations are resolved to harmonic and non harmonic parts. In particular skin friction coefficient, Nusselt number and Sherwood number are found to evolve into their steady state case in the large time limit. Parametric study of the solutions are conducted and discussed.

SORET AND DUFOUR EFFECTS ON RADIATIVE HYDROMAGNETIC FLOW OF A CHEMICALLY REACTING FLUID OVER AN EXPONENTIALLY ACCELERATED INCLINED POROUS PLATE IN PRESENCE OF HEAT ABSORPTION AND VISCOUS DISSIPATION

  • VENKATESWARLU, M.;BHASKAR, P.;LAKSHMI, D. VENKATA
    • Journal of the Korean Society for Industrial and Applied Mathematics
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    • v.23 no.3
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    • pp.157-178
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    • 2019
  • The present correspondence is conveyed on to consider the fascinating and novel characteristics of radiative hydromagnetic convective flow of a chemically reacting fluid over an exponentially accelerated inclined porous plate. Exact solutions for the fluid velocity, temperature and species concentration, under Boussinesq approximation, are obtained in closed form by the two term perturbation technique. The interesting parts of thermal dispersing outcomes are accounted in this correspondence. Graphical evaluation is appeared to depict the trademark direct of introduced parameters on non dimensional velocity, temperature and concentration profiles. Also, the numerical assortment for skin friction coefficient, Nusselt number and Sherwood number is examined through tables. The certification of current examination is confirmed by making an examination with past revelations available in composing, which sets a benchmark for utilization of computational approach.

Thermal diffusion and diffusion thermo effects on an unsteady heat and mass transfer magnetohydrodynamic natural convection Couette flow using FEM

  • Raju, R. Srinivasa;Reddy, G. Jithender;Rao, J. Anand;Rashidi, M.M.
    • Journal of Computational Design and Engineering
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    • v.3 no.4
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    • pp.349-362
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    • 2016
  • The numerical solutions of unsteady hydromagnetic natural convection Couette flow of a viscous, incompressible and electrically conducting fluid between the two vertical parallel plates in the presence of thermal radiation, thermal diffusion and diffusion thermo are obtained here. The fundamental dimensionless governing coupled linear partial differential equations for impulsive movement and uniformly accelerated movement of the plate were solved by an efficient Finite Element Method. Computations were performed for a wide range of the governing flow parameters, viz., Thermal diffusion (Soret) and Diffusion thermo (Dufour) parameters, Magnetic field parameter, Prandtl number, Thermal radiation and Schmidt number. The effects of these flow parameters on the velocity (u), temperature (${\theta}$) and Concentration (${\phi}$) are shown graphically. Also the effects of these pertinent parameters on the skin-friction, the rate of heat and mass transfer are obtained and discussed numerically through tabular forms. These are in good agreement with earlier reported studies. Analysis indicates that the fluid velocity is an increasing function of Grashof numbers for heat and mass transfer, Soret and Dufour numbers whereas the Magnetic parameter, Thermal radiation parameter, Prandtl number and Schmidt number lead to reduction of the velocity profiles. Also, it is noticed that the rate of heat transfer coefficient and temperature profiles increase with decrease in the thermal radiation parameter and Prandtl number, whereas the reverse effect is observed with increase of Dufour number. Further, the concentration profiles increase with increase in the Soret number whereas reverse effect is seen by increasing the values of the Schmidt number.