• 한국자동차공학회논문집
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• 제5권2호
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• pp.173-182
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• 1997

The instantaneous flame temperature and soot formation and oxidation in a D. I. diesel engine are measured by using a two-color method. The proposed method based on the continuous spectral radiation from the soot particles in flames is applicable to industrial diesel engines without major modifications of their main characteristics. Measurements are performed at one location inside the combustion chamber of a D.I. diesel engine. Effects of different engine speeds and loads on flame temperature and KL factor which is an index of soot concentrations were examined. A little temperature change were observed with increasing engine speed, while increased with loads. The higher the flame temperature is, the lower the KL factor is.

• 대한기계학회논문집B
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• 제27권5호
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• pp.596-603
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• 2003

Present study has been conducted to see the relative effects of adding N: to fuel-side and air-side on flame structure, soot formation and NOx emissions. Experiments were carried out to ascertain to what degree chemical kinetics and/or molecular transport effects can explain the differences in soot formation and NOx emission by studying laminar diffusion flames. Direct photograph was taken to see the flame structure. CARS techniques was used to get the flame temperature profiles. And spatial distribution of soot could be obtained by PLII method. CHEMKIN code was also used to estimate the global residence time to predict NOx emissions at each condition. Results from these studies indicate that fuel-side dilution is more effective than air-side dilution in view of NOx emissions. However, air-side dilution shows greater effectiveness over fuel-side dilution in soot formation. And turbulent mixing and heat transfer problems were thought to be considered in practical applications.

• International Journal of Automotive Technology
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• 제7권4호
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• pp.391-397
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• 2006

The soot yield has been studied by a premixed propane-oxygen-inert gas combustion in a specially designed disk-type constant-volume combustion chamber to investigate the effect of pressure, temperature and turbulence on soot formation. Premixtures are simultaneously ignited by eight spark plugs located on the circumference of chamber at 45 degrees intervals in order to observe the soot formation under high temperature and high pressure. The eight converged flames compress the end gases to a high pressure. The laser schlieren and direct flame photographs with observation area of 10 mm in diameter are taken to examine the behaviors of flame front and gas flow in laminar and turbulent combustion. The soot volume fraction in the chamber center during the final stage of combustion at the highest pressure is measured by the in-situ laser extinction technique and simultaneously the corresponding burnt gas temperature by the two-color pyrometry method. The changes of pressure and temperature during soot formation are controlled by varying the initial charging pressure and the volume fraction of inert gas compositions, respectively. It is found that the soot yield increases with dropping the temperature and raising the pressure at a constant equivalence ratio, and the soot yield in turbulent combustion decreases as compared with that in laminar combustion because the burnt gas temperature increases with the drop of heat loss for laminar combustion.

• 대한기계학회논문집B
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• 제41권6호
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• pp.389-395
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• 2017

본 연구는 정적 연소 조건에서 Octane 단일 연료 액적의 매연 생성 거동에 관한 정보를 제공하기 위해 수행하였다. 이를 위해 동일한 분위기 압력($P_{amb}$) 1.0 atm과 산소 농도($O_2$) 21%, 질소 농도($N_2$) 79% 조건에서 초기 액적 직경($d_0$) 변화에 따른 Octane 액적의 매연 생성 특성 실험 결과를 제시하였다. Octane 액적 연소 가시화는 초고속 카메라를 사용하여 촬영하였고, 분위기 조건은 제어 시스템에 의해 동일한 조건을 유지하였다. Octane 액적 연소 결과, 매연 생성량은 동일한 분위기 조건에서 초기 액적 직경 변화의 영향이 크게 나타나지 않았다. 또한, 매연 체적 분율 최댓값($f_{vmax}$)은 $135^{\circ}{\sim}315^{\circ}$ 측정 방향에서 높은 결과를 보였다. 이는 액적 점화 이후 Igniter의 이동 과정에서 생성된 Soot-tail로 인해 매연 체적분율 결과가 증가된 것으로 나타났다.

• 대한기계학회논문집B
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• 제26권3호
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• pp.402-409
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• 2002

Experiments were performed with double-concentric diffusion flame(DDF) in order to investigate the characteristics of soot formation and temperature distributions. The flame size and shape of the DDF are similar to those of the well-known normal co-flow diffusion flame(WF), except the formation of a tiny inverse flame near the central tube exit. A laser light extinction technique was used to measure the soot volume fractions. The temperature distributions in the flame were measured by rapid insertion of a R-type thermocouple. Soot concentrations along the flame axis of the DDF were higher than those of the NDF. However, the maximum soot volume fraction of the DDF along the periphery of the flame was lower than that of the NDF. It is mainly due to the effect of nitrogen-dilution from the inner air. Measured temperature distribution explains these trends of soot concentration. The temperature along the flame axis was also higher in DDF than that of the NDF. However, the flame temperatures at the flame front of the two flames were almost same regardless of the inner flame. This phenomenon means that the inverse flame inside the DDF did not affect on the flame structure including the temperature and soot concentration, except the region around the flame axis.

• Journal of Advanced Marine Engineering and Technology
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• 제37권8호
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• pp.807-815
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• 2013

대기압에서의 층류 에틸렌 확산 화염 내 매연 생성에 대하여 부력의 영향에 대한 보다 나은 이해를 위해 0g와 1g 조건하에서 수치해석을 수행하였다. 수치해석을 위하여 가스상 메커니즘과 열 및 이송특성을 이용하였다. 매연의 생성과 성장 및 산화에 대하여 예측하기 위하여 간단한 매연 모델이 채택되었으며 이 모델은 가스상과 매연의 화학적 상호작용에 고려되었다. 수치 결과로서 보다 두꺼운 확산층과 축방향 속도의 감소로 인해 0g에서의 화염이 1g하의 화염보다 더 넓은 화염을 가진다는 알 수 있었다. 0g에서의 축방향 속도의 감소는 더 긴 체류 시간을 가지게 하고 그 결과로 더 많은 매연 체적분율을 나타나게 한다. 0g 하에서는 화염이 부력으로 인한 불안정성이 없어져 화염의 흔들거림이 사라졌다.

• 해양환경안전학회지
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• 제29권4호
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• pp.356-362
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• 2023

기후 변화에 따른 위험성은 전 세계적으로 오랜 기간 강조되고 있으며, 이를 극복하기 위한 노력은 해운분야에서도 국제해사 기구를 중심으로 이어지고 있다. 연소과정에서 발생한 매연을 제어하기 위하여 매연 생성 특성에 관한 연구는 필수적이다. 본 연구에서는 에틸렌 가스를 기반으로 한 대향류 확산화염에서 불활성 기체인 질소를 혼합하여 화염온도, 화염형태, 매연 생성 관련된 화학종의 상태변화를 확인하기 위해 광소멸법과 화학반응 수치해석을 수행하였다. 연구 결과. 질소의 혼합비율이 증가함에 따라 화염온도 감소와 매연체적분율 감소로 이루어졌다. 매연 입자가 분포하는 구간도 감소하였으며, 30% 이상 혼합비율이 높아지면 체적분율 감소율이 감소하였다. 매연 성장에 관여하는 화학종들의 몰분율도 감소하였다. HACA 반응 관련 화학종은 탄화수소 연료 비율에 따라 영향을 받으나, 홀수탄소 경로 관련 화학종은 탄화수소 연료 비율뿐만 아니라 화염온도 영향을 받는 것을 확인하였다.

• 한국연소학회:학술대회논문집
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• 한국연소학회 2014년도 제49회 KOSCO SYMPOSIUM 초록집
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• pp.133-134
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• 2014

The full transport equation approach for laminar non-premixed flame with detailed chemistry, soot and radiation has an advantage in accuracy and describing for emission pathway, but this approach requires the excessive computational cost especially for a higher-order hydrocarbon fuel flames. On the other hand, the standard flamelet model has an efficiency and accuracy for non-premixed flame, though this model is not suitable for simulating slow processor like soot and radiation in laminar non-premixed flame situation. To overcome this limitation, modified transient flamelet model is developed which coupled with two-equation soot model involved in soot formation and evolution mechanism such as nucleation, surface growth, oxidation and agglomeration.

• 한국연소학회:학술대회논문집
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• 대한연소학회 2003년도 제27회 KOSCO SYMPOSIUM 논문집
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• pp.19-26
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• 2003

Experimental measurements of flame structure and soot characteristics were performed for ethene inverse diffusion flames (IDF). IDF has been considered as the excellent flow field to study the incipient soot because soot particle do not experience the oxidation process. In this study, LIF image clarified the reaction zone of IDF with OH signal and PAH distribution. laser light scattering technique also identified the being of soot particle. To address the degree of soot maturing, C/H ratio and morphology of soot sample were investigated. From these measurements, the effect of flow residence time and temperature on soot inception could be suggested, and more details on soot characteristic in the IDF was determined according to fuel dilution and flame condition. The fuel dilution results in a decrease of temperature and enhancement of residence time, but the critical dilution mole fraction is existed for temperature not to effect on soot growth. Also, the soot inception evolved on the specific temperature and its morphology are independent of the fuel dilution ratio of fuel.

• 대한기계학회논문집B
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• 제26권6호
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• pp.817-822
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• 2002

Sooting characteristics of counterflow ethylene/propane mixture flames have been experimentally studied to investigate the fuel structure effect on PHM and soot formation. Laser-induced incandescene and laser-induced fluorescene techniques were employed to measure soot volume fraction and polycyclic aromatic hydrocarbon (PAH) concentration, respectively. Importance of $C_{3-}$species on PAH growth as well as the H-abstraction-C$_2$ $H_2$addition (HACA) mechanism has been emphasized, considering that PAH growth rate is greater for with mixed fuel than fer pure fuel flames. It was also confirmed that HACA pathways are the dominant soot growth mechanism. A new PAH growth model including both $C_{2-}$ and $C_{3-}$growth mechanisms is proposed based on the experimental results.