• Title/Summary/Keyword: Solvent additives

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Manufacture of Precheese Powder by Use of Low-temperature Renneting Made from Raw Milk Using Spray Dryer

  • An, Shuo-Feng;Piao, Jing-Zhu;Chang, Oun-Ki
    • Food Science of Animal Resources
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    • v.30 no.4
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    • pp.551-559
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    • 2010
  • Among the food constituents, proteins differ in coagulation properties as compared to other constituents in food system. Especially milk protein coagulate through different pathways thus this coagulability can be used for manufacture of various dairy products or as a determinant of dairy product analysis. These milk coagulation methods include organic solvent, isoelectric point, trichloroacetic acid, Ca-sensitive casein, heavy metal ion and rennet coagulation. The coagulation experiment was performed using above parameters at $0^{\circ}C$ and $25^{\circ}C$ to find the dehydration conditions before coagulating for precheese powder making. After different chemical treatments, there was no coagulation at $0^{\circ}C$ rather at $25^{\circ}C$ whatever the mode of coagulation methods was. The appearance of precipitate with coagulation methods was quite different from above mentioned methods of coagulation illustrated by scanning electron microscope. These powders were used for fabrication of camembert cheese by renneting coagulation at $0^{\circ}C$, showing the possibility of cheese materials and of food additives for fabrication of products.

A Newly Developed Analytical and Semi-preparative Enantiomer Separation of Fluoxetine using Polysaccharide-derived Chiral Stationary Phases by High Performance Liquid Chromatography (고성능 액체 크로마토그래피에 의한 다당 유도체의 키랄 고정상에서 플록세틴의 새롭게 개발된 분석 및 반분취의 광학분리)

  • Kim, Seok Jin;Nam, Kyung Wook;Park, Bohyun;Islam, Md. Fokhrul;Lee, Wonjae
    • KSBB Journal
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    • v.31 no.3
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    • pp.186-191
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    • 2016
  • A liquid chromatographic method for the enantiomer separation of fluoxetine was performed using covalently bonded and coated type polysaccharide-derived chiral stationary phases (CSPs). The degree of enantioseparation is affected by the used CSPs and mobile phases. The performance of Chiralpak IC was superior to the other CSPs used in this study. Out of various solvent composition and additives, the greatest separation and resolution was observed using Chiralpak IC with mobile phase of 2-propanol in hexane with diethylamine as an additive. Semi-preparative separation of fluoxetine was performed on the analytical Chiralpak IC column to obtain (R)- and (S)-fluoxetine enantiomer with high chemical and optical purity. From the overall study, the developed liquid chromatographic method on polysaccharide-derived CSPs is expected to be very useful for the enantiomer separation of fluoxetine.

Screening of Antimicrobial Substances against Brachyspira hyodysenteriae (Brachyspira hyodysenteriae에 대한 항균물질 탐색)

  • Kim, Jin-Gyu;O, Se-Taek;Yang, Si-Yong;Kim, Seon-Yeo;Gang, Hyeon-Mi;Mun, Jin-San;Song, Min-Dong
    • Microbiology and Biotechnology Letters
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    • v.32 no.4
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    • pp.352-355
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    • 2004
  • The extracts from 70 different plant natural products were used to investigate the antimicrobial activities against Brachyspira hyodrsenteriae, the causative agent of swine dysentery. Among them, the extracts from Terminalia chehula exhibited the highest antimicrobial activities against B. hyodysenteriae. It showed the antimicrobial activity against B. hyodysensteriae mostly in parts of its shell. Minimum inhibitory concentration (MIC) of the water extracts of T chehula was 12.5 mg/ml. After organic solvent extractions, the ethylacetate extracts exhibited higher antimicrobial activities against B. hyodysenteriae, and their antimicroactivities were similar to that of the tannin. In conclusion, these findings suggest that the extracts from T chebula may be used as animal feed additives for their antimicrobial activities against B. hyodysenteriae.

Permeation of Ultrafiltration Membranes of Anion Charged poly(bis[4-(3-aminophenoxy) phenyl]sulfone/trimellite amide) Containing Carboxylic Acid (Carboxylic acid 함유한 음이온성 Poly(bis[4-(3-aminophenoxy)phenyl]sulfone/trimellite amide) 한외여과막의 투과특성)

  • Jeon, Jong-Young
    • Membrane Journal
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    • v.19 no.2
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    • pp.104-112
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    • 2009
  • Ultrafiltration membranes (UF) were manufactured by the conventional phase inversion method using an additives with N-methyl-2-pyrrolidinone as a solvent. Characteristics of performance could be controlled by the preparation conditions and the operating methods. The fouling resistance was observed by the relative ratio of permeate flux $(J_t)$/pure water flux $(J_o)$. Compared with the anion charged membranes and its original polyamide membrane, fouling resistance to the protein was increasing in proportion to the ion exchange capacity. The relative flux for the bovin serum albumin (BSA) solution increased as pH value further away from isoelectric point of BSA. The hydrophilicity of a membrane, the pH condition, and the operating temperature played the important role in the membrane permeations.

Microstructure and electrical properties of high power laser thermal annealing on inkjet printed Ag films

  • Yoon, Yo-Han;Yi, Seol-Min;Yim, Jung-Ryoul;Lee, Ji-Hoon;Joo, Young-Chang
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2009.05a
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    • pp.36.2-36.2
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    • 2009
  • In this work, the high power CW Nd:YAG laser has been used for thermal treatment of inkjet printed Ag films-involving eliminating organic additives (dispersant, binder, and organic solvent) of Ag ink and annealing Ag nanoparticles. By optimizing laser parameters, such as laser power and defocusing value, the laser energy can totally be converted to heat energy, which is used to thermal treatment of inkjet printed Ag films. This results in controlling the microstructures and the resistivity of films. We investigated the thermal diffusion mechanisms during laser annealing and the resulting microstructures. The impact of high power laser annealing on microstructures and electrical characteristic of inkjet printed Ag films is compared to those of the films annealed by a conventional furnace annealing. Focused ion beam (FIB) channeling image shows that the laser annealed Ag films have large columnar grains and dense structure (void free), while furnace annealed films have tiny grains and exhibit void formation. Due to these microstructural characteristics of laser annealed films, it has better electrical property (low resistivity) compared to furnace annealed samples.

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Retention Factors and Resolutions of Amino Benzoic Acid Isomers with Some Ionic Liquids

  • Zheng, Jinzhu;Polyakova, Yulia;Row, Kyung-Ho
    • Biotechnology and Bioprocess Engineering:BBE
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    • v.11 no.6
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    • pp.477-483
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    • 2006
  • Ionic liquids in the form of organic salts are being widely used as new solvent media. In this paper three positional isomers, o-amino benzoic acid, m-amino benzoic acid, and p-amino benzoic acids were separated with four different ionic liquids as mobile phase additives using high performance liquid chromatography (HPLC). The following ionic liquids were used: 1-butyl-3-methylimidazolium tetrafluoroborate ([BMIm][$BF_{4}$]), 1-ethyl-3-methylimidazolium tetrafluoroborate ([EMIm][$BF_{4}$]), 1-ethyl-3-methylimidazolium methylsulfate ([EMIm][MS]), and 1-octyl-3-methylimidazolium methylsulfate ([OMIm][MS]). The effects of the alkyl group length on the imidazolium ring and its counterion, and the concentrations of the ionic liquids on the retention factors and resolutions of amino benzoic acid isomers were tested. The results of the separations with ionic liquids as the eluents were better than those without ionic liquids. Excellent separations of the three isomers were achieved using 2.0-8.0 mM/L [OMIm][MS] and 1.0-8.0 mM/L [EMIm][MS] as the eluent modifiers.

A Study on Explosive Limits of Flammable Materials - Explosive Limits of Ternary System by Means of Solution Thermodynamics and MRSM Model - (가연성물질의 폭발한계에 관한 연구 - 용액열역학 및 MRSM 모델에 의한 3성분계 폭발한계 -)

  • Ha, Dong-Myeong
    • Journal of the Korean Society of Safety
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    • v.20 no.3 s.71
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    • pp.91-97
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    • 2005
  • The research on the explosive limits is one of fundamental fields of combustion process, and information on the explosive limits of mixture of fuel and oxidant, with or without additives, is very important for the prevention in industrial fire and explosion accidents. Explosive limits of all compounds and solvent mixtures can be calculated with the appropriate use of the fundamental laws of Raoult, Batten, Le Chatelier and MRSM(modified response surface methodology) model. In this study, the reference values of lower explosive limits(LEL) of the ethanol+toluene+ethylacetate system were compared with the calculated values by using the solution thermodynamics and the MRSM model, respectively. The values calculated by the proposed equations were a good agreement with literature data within a few percent. By means of this methodology, it is possible to evaluate reliability of experimental data of the lower explosive limits of the flammable mixtures. Also, from given results, it is possible to predict explosive limits of the other flammable liquid mixtures used in the chemical process by the use of the proposed equations.

Thermal Process Optimization of Pb-free Ag-paste and Evaluation of Electrical Properties in Mono-Si Solar Cell (단결정 Si 태양전지 적용을 위해 제조된 무연 은 페이스트의 열 공정 최적화 및 전기적 특성 평가)

  • Jeong, Ji-Hyun;Kim, Sung-Jin;Son, Chang-Rok;Ur, Soon-Chul;Kweon, Soon-Yong
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.24 no.10
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    • pp.844-849
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    • 2011
  • Two kind of Ag-pastes were prepared for integrating the bulk Si solar cell. One is the Ag-paste with Pb-based glass frit and the other is that with Bi-based glass frit. The pastes were the mixture of 84 wt% Ag, 2 wt% glass frit, 11 wt% solvent of buthyl cabitol acetate, and 2 wt% additives. After fabricating the Ag-pastes, they was coated on a $SiN_x$/n+/p- stacks of a commercial mono-Si solar cell. The solar cell efficiency was 17.6% in the case of the Pb-based Ag-paste. However that was 16.2% in the solar cell integrated with the Bi-based Ag-paste. The lower performance in Bi-based Ag-paste was caused by the higher series resistance and the lower shunt resistance in comparison with the Pb-based Ag-paste.

Synthesis of Acetins from Glycerol using Lipase from Wheat Extract

  • Pradima, J;Rajeswari, M Kulkarni;Archna, Narula;Sravanthi, V;Rakshith, R;Nawal, Rabia Nizar
    • Korean Chemical Engineering Research
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    • v.57 no.4
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    • pp.501-506
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    • 2019
  • New technology-driven biocatalysts are revolutionizing the biochemical industries. With maximum utilization of renewable feedstock, biocatalysts have been the basis for a major breakthrough. Lipases are the most widely established catalysts used for hydrolysis, esterification and transesterification reactions. In this research, a biochemical process that combines extraction of lipase enzyme from germinated wheat seeds and its application to valorize glycerol to acetins by esterification is presented. Acetins are among highly rated, value-added products derived from glycerol. The favorable conditions for the enzymatic conversion of glycerol were observed as glycerol to acetic acid molar ratio (1:5), reaction temperature ($40^{\circ}C$) and the amount of enzyme (20% v/v). 65.93% of glycerol conversion was achieved for duration of 15 h with the use of tert-butanol solvent. This method proposes to explore the viability of a biological route to convert glycerol derived from biodiesel industry to acetins with further streamlining.

Survey of the oil contaminated level and preliminary field bioremediation test in the Mountain Baegun at Uiwang city (의왕시 백운산 주변 유류 오염도 조사 및 현장 복원 기초실험)

  • 김종석;주춘성;김윤관;권은미;정욱진
    • Journal of Soil and Groundwater Environment
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    • v.7 no.2
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    • pp.3-11
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    • 2002
  • The objective of this study was to survey the oil contamination around the Mountain Baegun at Uiwang city to obtain the preliminary data for bioremediation. For measuring the oil concentrations and physical properties from soil, we analyzed BTEX. TPH and pH, organic content, water content, pormeability coefficient, gravity, porosity and used the purge & trap method for analyzing BTEX. Using the Accelerated Solvent Extractor, we pretreated the samples and then analyzed TPH using GC-FID as soon as possible. From the analysis results, maximum concentration of TPH was 24.773mg/kg and BTEX was 101.7mg/kg. The results of TPH at the Mountain Baegun were higher than the enforcement standard of soil contamination(Korea) and the BTEX concentrations were also higher than the advisory standard of soil contamination(Korea). From these results, the Mountain Baegun may requires to remedy the oil-contaminated soil. In addition, we performed the field bioremediation test for five weeks at the Mountain Baegun using the microbial additives that were developed by our laboratory. From the results of the field test, we could find the about 95% of the oil was removed from the contaminated soil in five weeks. So we consider that it is the one of the useful solutions to remedy the oil-polluted site.