• Title/Summary/Keyword: Solution-diffusion Model

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Solvent diffusion model in polymer membrane (고분자막내에서 용매 확산 모델)

  • 김종수;이광래
    • Proceedings of the Membrane Society of Korea Conference
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    • 1998.10a
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    • pp.59-62
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    • 1998
  • 1. 서론 : 막내부에서 물질전달을 설명하는 이론으로 현재 solution-diffusion model과 pore-flow model 두 가지가 있다. 이 중에서 흡착, 확산, 탈착의 3과정을 거치는 solution-diffusion model이 주로 사용되고 있다. 본 연구에서는 solution-diffusion model 에서 상호확산계수를 구하기 위해서 Vrentas-Duda식을 이용하여 자기확산계수를 구하고 Bearman식으로부터 상호확산계수를 구하는 과정을 UNIFAC-FV와 modified UNIFAC-FV을 이용하여 계산하였으며 Flory-Huggins식을 이용한 기존방법과 비교하였다.(생략)

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Modeling of ion diffusion coefficient in saturated concrete

  • Zuo, Xiao-Bao;Sun, Wei;Yu, Cheng;Wan, Xu-Rong
    • Computers and Concrete
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    • v.7 no.5
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    • pp.421-435
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    • 2010
  • This paper utilizes the modified Davis model and the mode coupling theory, as parts of the electrolyte solution theory, to investigate the diffusivity of the ion in concrete. Firstly, a computational model of the ion diffusion coefficient, which is associated with ion species, pore solution concentration, concrete mix parameters including water-cement ratio and cement volume fraction, and microstructure parameters such as the porosity and tortuosity, is proposed in the saturated concrete. Secondly, the experiments, on which the chloride diffusion coefficient is measured by the rapid chloride penetration test, have been carried out to investigate the validity of the proposed model. The results indicate that the chloride diffusion coefficient obtained by the proposed model is in agreement with the experimental result. Finally, numerical simulation has been completed to investigate the effects of the porosity, tortuosity, water-cement ratio, cement volume fraction and ion concentration in the pore solution on the ion diffusion coefficients. The results show that the ion diffusion coefficient in concrete increases with the porosity, water-cement ratio and cement volume fraction, while we see a decrease with the increasing of tortuosity. Meanwhile, the ion concentration produces more obvious effects on the diffusivity itself, but has almost no effects on the other ions.

Removal of Phenols by Granular Activated Carbon in Aqueous Solution (수용액에서 입상활성탄에 의한 페놀류의 제거)

  • 권성헌;강원석
    • Journal of Environmental Science International
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    • v.7 no.4
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    • pp.541-548
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    • 1998
  • Aqueous phase adsorption of phenols by granular activated carbon was studied in a batch adsorption vessel. Adsorption Isotherms of phenol(Ph), p-chlorophenol(PCP) and p-nitrophenol (PNP) from aqueous solution on granular activated carbon have been obtained. The experimental data were analyzed by the surface and pore diffusion models. Both models could be applied to predict the adsorption phenomena. However, the pore diffusion model was slightly better than the surface diffusion model In representing the experimental data for the initial concentration changes. Therefore, the pore diffusion model was used to predict the change of operating variables such as the agitation speed and Particle size of adsorbent which have influence on the film resistance and intraparticle diffusion.

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Fundamental and plane wave solution in non-local bio-thermoelasticity diffusion theory

  • Kumar, Rajneesh;Ghangas, Suniti;Vashishth, Anil K.
    • Coupled systems mechanics
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    • v.10 no.1
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    • pp.21-38
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    • 2021
  • This work is an attempt to design a dynamic model for a non local bio-thermoelastic medium with diffusion. The system of governing equations are formulated in terms of displacement vector field, chemical potential and the tissue temperature in the context of non local dual phase lag (NL DPL) theories of heat conduction and mass diffusion. Based on this considered model, we study the fundamental solution and propagation of plane harmonic waves in tissues. In order to analyze the behavior of the NL DPL model, we construct basic theorem in the terms of elementary function which determine the existence of three longitudinal and one transverse wave. The effects of various parameters on the characteristics of waves i.e., phase velocity and attenuation coefficients are elaborated by plotting various figures of physical quantities in the later part of the paper.

Thermal Diffusion Process Modeling with Adaptive Finite Volume Method (적응성 유한체적법을 적용한 다차원 확산공정 모델링)

  • 이준하;이흥주
    • Journal of the Semiconductor & Display Technology
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    • v.3 no.3
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    • pp.19-21
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    • 2004
  • This paper presents a 3-dimensional diffusion simulation with adaptive solution strategy. The developed diffusion simulator VLSIDIF-3 was designed to re-refine areas. Refine scheme was calculated by the difference of doping concentration between any of two nodes. Each element is greater than tolerance and redo diffusion process until error is tolerable. Numerical experiment in low doping diffusion problem showed that this adaptive solution strategy is very efficient in both memory and time, and expected this scheme would be more powerful in complex diffusion model.

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적응성 유한체적법을 적용한 다차원 확산공정 모델링

  • 이준하;이흥주;변기량
    • Proceedings of the Korean Society Of Semiconductor Equipment Technology
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    • 2004.05a
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    • pp.55-58
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    • 2004
  • This paper presents a 3-dimensional diffusion simulation with adaptive solution strategy. The developed diffusion simulator VLSIDIF-3 was designed to re-refine areas where difference of doping concentration between any of two nodes of each element is greater than tolerance and redo diffusion process until error is tolerable. Numerical experiment in low doping diffusion problem showed that this adaptive solution strategy is very efficient in both memory and time, and expected this scheme would be more powerful in complex diffusion model.

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Derivation of the First-Order Mass-Transfer Equation for a Diffusion-Dominated Zone of a 2-D Pore (2차원으로 구현한 다공성 매질의 확산주도영역에 관한 1차 물질이동 방정식의 유도)

  • Kim, Young-Woo;Seo, Byong-Min;Hwang, Seung-Min;Park, Cha-Sik
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.34 no.2
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    • pp.99-103
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    • 2010
  • A new analytic solution was derived for the diffusion into or from an immobile zone of a rectangular 2-D pore. For a long time, the new solution converges to a traditional mobile-immobile zone (MIM) model, but only if the latter is used with an apparent initial concentration that is smaller by almost 20% than the true one. This is the tradeoff for using a simple MIM model instead of an exact model based on the diffusion equation. The mass-transfer coefficient was found to be constant for a sufficiently long time; it was proportional to the molecular diffusion and inversely proportional to the square of the pore depth. The mass-transfer coefficient was time-dependent for a sufficiently short time and may be significantly larger than its asymptotic value.

Comparison of the Bass Model and the Logistic Model from the Point of the Diffusion Theory (확산이론 관점에서 로지스틱 모형과 Bass 모형의 비교)

  • Hong, Jung-Sik;Koo, Hoon-Young
    • Journal of the Korean Operations Research and Management Science Society
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    • v.37 no.2
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    • pp.113-125
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    • 2012
  • The logistic model and the Bass model have diverse names and formulae in diffusion theory. This diversity makes users or readers confused while it also contributes to the flexibility of modeling. The method of handling the integration constant, which is generated in process of deriving the closed form solution of the differential equation for a diffusion model, results in two different 'actual' models. We rename the actual four models and propose the usage of the models with respect to the purpose of model applications. The application purpose would be the explanation of historical diffusion pattern or the forecasting of future demand. Empirical validation with 86 historical diffusion data shows that misuse of the models can draw improper conclusions for the explanation of historical diffusion pattern.

Interpretation of Permeation Characteristics and Membrane Transport Models Through Polyamide Reverse Osmosis Membrane (Polyamide 역삼투막의 투과성능과 막 이동 모델의 해석)

  • 김노원;김영길;이용택
    • Membrane Journal
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    • v.14 no.1
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    • pp.75-84
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    • 2004
  • In this study, we present a noble study far membrane transport models using chlorine resistance of polyamide RO membranes. Membrane transport mechanism is investigated by the comparison of membrane permeation performance under the continuous and Intermittent operation modes with mixed feed solution containing NaOCl and NaCl. Analysis of permeation performance indicates that solution-diffusion model and preferential adsorption-capillary flow model are relatively efficient according to operation mode. Under the continuous flow state, mass transfer depends on preferential adsorption-capillary flow model rather than solution-diffusion model. On the other hand, it prefers solution-diffusion model to preferential adsorption-capillary flow model under the stationary state. SEM images of NaOCl treated membrane surfaces strongly support these conclusions. These surface images reveal that NaOCl treated membrane in continuous operation mode exhibits ridge and valley structure in some fraction of the surface area, whereas that in intermittent operation mode shows surface degradation entirely.