• Journal of the Korean Ceramic Society
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• v.35 no.12
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• pp.1316-1322
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• 1998

The amount of VC and C/N ratio in Ti(CN) was varied to investigate the effect of VC addition on the mi-crostructural change in Ti(CN)-Ni system. As the amount of VC addition increases in Ti(C0.7N0.3)-20Ni sys-tem a complete solid solution was observed in Ti(C0.7N0.3)-20Ni-25VC system. It implies that the ratio of the dissolution rates of Ti(C0.7N0.3)to that of VC is nearly 2:1 at the sintering conditions used in this study. It was found from the experiments that the system composed of the Ti(C0.7N0.3) phase exhibits a rimless structure and relatively small amount of solid solution. That is among Ti(C0.7N0.3) phase exhibits a rimless structure and relatively small amount of solid solution. This is among Ti(C1-xNx) phases the dissolution rate of Ti(C0.3N0.7) is the lowest. Also fracture toughness(KIC) of the cermet was measured by indentation method. Attentions were paid to crack propagation path to look for a dominant fracture mode and to cor-relate it with fracture toughness values. The fracture toughness was relatively high with the addition of VC content. But the addition of a large VC content reduced the overall toughness of the cermet. This result is explained with the difference in fracture mode.

• Geomechanics and Engineering
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• v.2 no.4
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• pp.229-252
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• 2010

In this paper, Soil-Structure Interaction (SSI) effect is investigated using a new and integrated approach. Faster solution of time dependant differential equation of motion is achieved using numerical representation of wavelet theory while dynamic Infinite Elements (IFE) concept is utilized to effectively model the unbounded soil domain. Combination of the wavelet theory with IFE concept lead to a robust, efficient and integrated technique for the solution of complex problems. A direct method for soil-structure interaction analysis in a two dimensional medium is also presented in time domain using the frequency dependent transformation matrix. This matrix which represents the far field region is constructed by assembling stiffness matrices of the frequency dependant infinite elements. It maps the problem into the time domain where the equations of motion are to be solved. Accuracy of results obtained in this study is compared to those obtained by other SSI analysis techniques. It is shown that the solution procedure discussed in this paper is reliable, efficient and less time consuming as compared to other existing concepts and procedures.

• Bulletin of the Korean Chemical Society
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• v.19 no.1
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• pp.57-62
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• 1998

We have synthesized a 17-residue peptide with the amino acid sequence RQMKEDAKGKSEEELAD corresponding to residues 84-100 of chicken skeletal troponin C. This stretch of the protein sequence is in the middle one-third of the 32-residue 9-turn α-helix that connects the two globular domains of the dumbell-shaped molecule and includes the D/E linker helix. We describe here the solution conformation of the helix linker as studied by circular dichroism (CD) and two-dimensional nuclear magnetic resonance (2-D NMR) spectroscopy. The NOE connectivities together with the vicinal $^3J_{N{\alpha}}$ coupling constants suggest that the peptide exists in a fast conformational equilibrium among several secondary structure: a nascent helix near the N-terminus, a helix, and a substational population of extended and random coil forms. In addition, two interresidue α-α NOEs are observed suggesting a bent structure with a bend that includes the single glycine in position 92. These results are consistent with the ideas that in neutral solution the D/E linker region of the central helix in troponin C can adopt a helical conformation and the central helix may have a segmental flexibility around Gly 92.

• Bulletin of the Korean Chemical Society
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• v.17 no.10
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• pp.925-929
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• 1996

Uranyl hydrolysis precipitates were obtained by increasing pH value of aqueous uranyl solution in the range of neutral to alkaline pH value and their phase transformation during the solubility experiment under various conditions has been examined. The precipitates formed in the hydrolysis reaction of uranyl ion had a layered structure such as a meta-schoepite phase, a schoepite structure, or a mixed phase of meta-schoepite and schoepite. Phase transformation between them was strongly dependent on the pH value at which the precipitate was formed. The distance between the layers in meta-schoepite or schoepite phase was ∼7.35 Å, and it was increased with the pH value at which the precipitate was synthesized as well as the pH values of the aqueous solution. The phase transformation from a meta-schoepite to schoepite was fast for the precipitates formed at low pH values, however, it was not the case for the precipitates formed at high pH values. A small difference of pH value in aqueous solution gave a great change on its solubilities near pH 9.7, because a layered structure of the precipitates became amorphous above that pH value. Greater solubility for the precipitate formed at higher pH value can be explained from the fact that the precipitates formed at low pH value had a better crystallinity and also that the precipitates formed at higher pH value has a slower rate of crystallization.

• Coupled systems mechanics
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• v.11 no.3
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• pp.217-231
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• 2022

The present paper is concerned with a delamination analysis of a multilayered frame structure that exhibits non-linear creep behavior. A solution to the strain energy release rate is obtained by considering the time-dependent complementary strain energy in the frame. The mechanical behavior of the frame is treated by using a non-linear stress-strain-time relationship. The time-dependent solution to the strain energy release rate obtained in the present paper holds for a multilayered frame made of arbitrary number of adhesively bonded layers of different thicknesses and material properties. Besides, the dealamination is located arbitrary along the thickness. The solution to the strain energy release rate is verifiedby applying the J-integral approach. A parametric study of the strain energy release rate is carried-out. Two three-layered frame configurations are analyzed in order to evaluate the influence of the delamination crack location along the thickness on the strain energy release rate. The strain energy release is analyzed also for the case when a notch is cut-out in the inner delamination crack arm. The results obtained are compared with these for a frame without a notch.

• The Journal of Korea Robotics Society
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• v.17 no.3
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• pp.288-295
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• 2022

This study shows a system identification method of a balancing loading device for a stair climbing delivery robot. The balancing loading device is designed as a 2-axes gimbal structure and is interpreted as two independent pendulum structures for simplifying. The loading device's properties such as mass, moment of inertia, and position of the center of gravity are changeable for luggage. The system identification process of the loading device is required, and the controller should be optimized for the system in real-time. In this study, the system identification method is based on least squares method to estimate the unknown parameters of the loading device's dynamic equation. It estimates the unknown parameters by calculating them that minimize the error function between the real system's motion and the estimated system's motion. This study improves the accuracy of parameter estimation using a null space solution. The null space solution can produce the correct parameters by adjusting the parameter's relative sizes. The proposed system identification method is verified by the simulation to determine how close the estimated unknown parameters are to the real parameters.

• International Journal of Air-Conditioning and Refrigeration
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• v.14 no.2
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• pp.66-75
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• 2006

The effect of antifreeze solution liquid film on the frost prevention is experimentally investigated. It is desirable that the antifreeze solution spreads widely on the heat exchanger surface forming thin liquid film to prevent frost nucleation while having small thermal resistance across the film. A porous layer coating technique is adopted to improve the wettability of the antifreeze solution on a parallel plate heat exchanger. The antifreeze solution spreads widely on the heat exchanger surface with $100{\mu}m$ thickness by the capillary force resulted from the porous structure. It is observed that the antifreeze solution liquid film prevents a parallel plate heat exchanger from frosting. The reductions of heat and mass transfer rate caused by the thin liquid film are only $1{\sim}2%$ compared with those for non-liquid film surface.

• Communications of the Korean Mathematical Society
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• v.20 no.2
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• pp.381-393
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• 2005

We consider a type of large deviation principle obtained by Freidlin and Wentzell for the solution of Stochastic differential equations in a conuclear space. We are using exponential tail estimates and exit probability of a Ito process. The nuclear structure of the state space is also used.

• Journal of Korean Society of Transportation
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• v.19 no.6
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• pp.131-142
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• 2001

Previous OD matrix estimation methods from link traffic counts have focused on the formulation of mathematical model and its solution algorithm. Thereby those methods have assumed that true or real OD is similar to the target OD and paid little attention to the properties of the change of OD structure. Although it is general situation that each OD pair increases or decreases due to significant land use and to large time variation between target OD with real OD, those methods have set unrealistic assumptions that target OD increases or decreases uniformly and that the OD structure does not change. Therefore those methods have showed poor performance of OD estimation in general situation. To cope with the problem. this paper suggests a new concept of OD matrix structure and shows the shortcomings of previous method′s dependancy on target OD matrix. We divide "OD trips" into "OD scale" and "OD structure". Where OD scale is a quantitative magnitude of OD trips and "OD structure" is ordinal OD scale. This paper use the same solution algorithm developed by Baek et al. (2000) for analysing the OD structure. Results of numerical examples show that the performance of the method is better than that of previous methods, while the previous methods have better performance in estimation only when OD trips increase or decrease. In addition to, if OD structure does not change, the results show that the error of estimation is low relatively regardless of the large difference of trips between target OD and real OD. This paper also shows that the model performance on OD structure and on OD trips is low as the number of origins that OD structure is changed increase. From the results we suggest that the change of OD structure can be more important information than the difference between target OD and real OD in OD estimation steps.

• Polymer(Korea)
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• v.34 no.3
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• pp.210-214
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• 2010

The structural development of triacetyl cellulose (TAC) was studied as a function of solution casting processing parameters such as dope concentration, evaporation temperature, annealing temperature and the addition of plasticizer. The crystalline structure was developed by the solution casting and the level of crystallinity was increased with increasing dope concentration and evaporation temperature. The crystalline structure could be enhanced by the annealing process after formation of TAC film. Introducing plasticizer resulted in decreasing melting temperature and crytallinity of TAC film due to the increase of chain mobility. It was also found that thermal stability of TAC was improved due to the rigid structure of applied plasticizer.