• 제목/요약/키워드: Solution growth method

검색결과 641건 처리시간 0.033초

Selective Growth of Nanosphere Assisted Vertical Zinc Oxide Nanowires with Hydrothermal Method

  • Lee, Jin-Su;Nam, Sang-Hun;Yu, Jung-Hun;Yun, Sang-Ho;Boo, Jin-Hyo
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2013년도 제45회 하계 정기학술대회 초록집
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    • pp.252.2-252.2
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    • 2013
  • ZnO nanostructures have a lot of interest for decades due to its varied applications such as light-emitting devices, power generators, solar cells, and sensing devices etc. To get the high performance of these devices, the factors of nanostructure geometry, spacing, and alignment are important. So, Patterning of vertically- aligned ZnO nanowires are currently attractive. However, many of ZnO nanowire or nanorod fabrication methods are needs high temperature, such vapor phase transport process, metal-organic chemical vapor deposition (MOCVD), metal-organic vapor phase epitaxy, thermal evaporation, pulse laser deposition and thermal chemical vapor deposition. While hydrothermal process has great advantages-low temperature (less than $100^{\circ}C$), simple steps, short time consuming, without catalyst, and relatively ease to control than as mentioned various methods. In this work, we investigate the dependence of ZnO nanowire alignment and morphology on si substrate using of nanosphere template with various precursor concentration and components via hydrothermal process. The brief experimental scheme is as follow. First synthesized ZnO seed solution was spun coated on to cleaned Si substrate, and then annealed $350^{\circ}C$ for 1h in the furnace. Second, 200nm sized close-packed nanospheres were formed on the seed layer-coated substrate by using of gas-liquid-solid interfacial self-assembly method and drying in vaccum desicator for about a day to enhance the adhesion between seed layer and nanospheres. After that, zinc oxide nanowires were synthesized using a low temperature hydrothermal method based on alkali solution. The specimens were immersed upside down in the autoclave bath to prevent some precipitates which formed and covered on the surface. The hydrothermal conditions such as growth temperature, growth time, solution concentration, and additives are variously performed to optimize the morphologies of nanowire. To characterize the crystal structure of seed layer and nanowires, morphology, and optical properties, X-ray diffraction (XRD), field emission scanning electron microscopy (FE-SEM), Raman spectroscopy, and photoluminescence (PL) studies were investigated.

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Strength and Crack Growth Computation for Various types of Stringers for Stiffened Panels using XFEM Techniques

  • Krishna, Lok S;Reshma, G;Dattaguru, B
    • International Journal of Aerospace System Engineering
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    • 제7권1호
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    • pp.7-15
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    • 2020
  • In this paper the crack growth, modeling, and simulation of the stiffened and un-stiffened cracked panels presented using commercially available finite element software packages. Computation of stresses and convergence of stress intensity factor for single edge notch (SEN) specimens carried out using the finite element method (FEM) and extended finite element method (XFEM) and compared with an analytical solution. XFEM techniques like cohesive segment method and LEFM using virtual crack closure technique (VCCT), used for crack growth analysis and presented results for un-stiffened and stiffened panels considering various crack domain. The non-linear analysis considering both geometric and material non-linearity on stiffened panels with various stringers like a blade, L, inverted T and Z sections the results were presented. Arrived at the optimum stringer section type for the considered panel under axial loading from the numerical analysis.

FRACTIONAL POLYNOMIAL METHOD FOR SOLVING FRACTIONAL ORDER POPULATION GROWTH MODEL

  • Krishnarajulu, Krishnaveni;Krithivasan, Kannan;Sevugan, Raja Balachandar
    • 대한수학회논문집
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    • 제31권4호
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    • pp.869-878
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    • 2016
  • This paper presents an ecient fractional shifted Legendre polynomial method to solve the fractional Volterra's model for population growth model. The fractional derivatives are described based on the Caputo sense by using Riemann-Liouville fractional integral operator. The theoretical analysis, such as convergence analysis and error bound for the proposed technique has been demonstrated. In applications, the reliability of the technique is demonstrated by the error function based on the accuracy of the approximate solution. The numerical applications have provided the eciency of the method with dierent coecients of the population growth model. Finally, the obtained results reveal that the proposed technique is very convenient and quite accurate to such considered problems.

와편모조류 시스트 분리를 위한 Panning 방법과 SPT 용액방법의 비교 (Comparison of Panning and Sodium Polytungstate Methods for Separating Dinoflagellate Cysts)

  • 강윤자;문창호;조현진
    • 한국수산과학회지
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    • 제41권3호
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    • pp.228-231
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    • 2008
  • Two methods for separating dinoflagellate cysts from marine sediments were compared: panning and sodium polytungstate (SPT). After pretreatment with the SPT solution, Protoperidinium species had a high germination rate and cell growth rate. The germinated cells grew continuously, even in a low nutrient environment. Alexandrium cysts did not germinate, because their germination is usually active in winter. Using SPT solution, the separation process was easier, quicker, and caused much less eye fatigue than the panning method. Therefore, SPT solution offers a convenient way of pretreating dinoflagellate cysts for separation and analysis.

글루타르알데하이드 고정 소심 낭막에서의 내피세포 증식에 대한 글루탕산 및 파라벤용액의 효과 (Effect of L-Glutamic Acid and Paraben Solution on the Endothelial Cell Proliferation in the Glutaraldehyde- Fixed Bovine Pericardium)

  • 김범식;이문환;유세영;김원곤
    • Journal of Chest Surgery
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    • 제29권1호
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    • pp.7-13
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    • 1996
  • The conventional glutaraldehyde (GA) fixation method of tissue valves is considered to be responsible for accelerated valve degeneration. The release of toxic GA from the valve tissue is believed to limit endothelial cell (EC) ingrowth. Removal of toxic GA by reaction with L-glutamic acid and storage in a Paraben solution may offer good EC growth. To investigate the conditions for endothelialization of tissue valves, the growth properties of ECs on the conventionally and alternatively treated pericardial tissue were compared. Conventional preparation included zero-pressure fixation for 72 hours in phosphated-buffered saline (PBS) solution containing 0.5% GA at 4$^{\circ}C$ and storage into PBS containing 0.2% GA(group I). Alternatively treated pericardial tissues were divided into three postfixation treatment groups : (1) storage in PBS solution containing Paraben(group II), (2) treatment with PBS containing 8$^{\circ}C$ L-glutamic acid(PH 7.35) and storage in PBS solution containing Paraben (g oup III), (3) treatment with L-glutamic acid dissolved in distilled water (PH 3.5) (group IV). Pericardial tissue were transferred into the 24-well plate after storage for 4 weeks. ECs were harvested enzymatically from the bovine pulmonary artery and grown to confluence on culture flask surfaces. Detached ECs by trypsin were incubated into the each well of the 24-well plate including test pericardial tissues. Cells were detached by trypsin, 1, 2, 3, 5, 7 days after incubation and counted on the hemacytometer. Cell viability test was performed by frypan-blue exclusion method. Acute cell death in the group I were found even after prolonged washing. The group II showed prolonged cell survival compared with the group I. Both group III and group IV showed better cell growth than group II. There was no statistically significant difference between group III and group IV method in terms of EC growth. This results suggest that treatment by L-glutamic ac id and storage in a Paraben solution be a promising approach for improvement of durability of GA-treated tissue valves.

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Dip-coating법에 의한 ${alpha}-Fe_2O_3$막 제조에 관한 연구 (A study on the preparation of ${alpha}-Fe_2O_3$films by dip-coating method)

  • 강경원;정용선;현부성;오근호
    • 한국결정성장학회지
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    • 제8권2호
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    • pp.292-298
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    • 1998
  • 출발원료로 ferric nitrate, ethylene glycol, acethyl acetone 혼합용액을 사용하여 dip-coating된 ${\alpha}-Fe_2O_3$ 막을 제조하였다. coating을 위한 혼합용액의 시간 경과에 따른 용액내의 가교(polymerization) 효과를 관찰하기 위해서 적외선 분광기(FT-IR)를 사용하였고, 막 형성시 유기물 분해 및 결정화 시작온도를 확인하기 위하여 FT-IR, XRD, DSC 등을 이용하여 분석을 행하였다. 또한 AFM과 SEM을 통하여 각 조건에서 제조된 막의 표면상태 및 두께 변화에 대하여 관찰되었다.

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2차원 ZnO 나노벽 구조 제조 (Fabrication of 2-Dimensional ZnO Nanowall Structure)

  • 김영정;;김영철;안승준;민준원
    • 한국세라믹학회지
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    • 제42권7호
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    • pp.521-524
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    • 2005
  • ZnO 2-D nanowall structure with around 100 nm thickness, which is composed of tens of nm scale ZnO single crystals, was fabricated through the low temperature chemical solution growth method. Electro Chemical Deposition (ECD) technique was applied to attach the ZnO seed crystals on ITO coated glass substrate. The ZnO nanowall structure was grown in the 0.015 mol$\%$ of aqueous solution of zinc nitrate and hexamethenamine at 60$^{\circ}C$ for 20 - 40 h. The nanowall structure depends on the ECD condition or the applied voltage and duration time. The nanowall shows a photoluminescence around 550 - 700 nm spectrum range.

Particle Growth in Oxalate Process I

  • Park, Zee-Hoon;Shin, Hyo-Soon;Lee, Byung-Kyo
    • The Korean Journal of Ceramics
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    • 제2권2호
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    • pp.63-69
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    • 1996
  • Barium titanyl oxalates, strontium titanyl oxalates and calcium zirconyl oxalates were prepared with variation of solution concentration and method of adding mixed metal ion solution into oxalic acid. Then they were aged in distilled water, ethanol or methanol, respectively. Barium titanyl oxalates and calcium zironyl oxalates were grown in water and strontium titanyl oxalates were groun in both water and methanol. They were supposed to be grown through the solutionl and reprecipitation mechanism. Nonuniform dispersion of particles in liquid phase is thought to cause abnormal particle growth.

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백두옹 추출물의 치주 병인균에 대한 항균효과 (The Antimicrobial Effect of Pulsatilla Koreana Extracts to Oral Micro-Organism)

  • 정성화;정진형;임성빈;김정근;소은희
    • Journal of Periodontal and Implant Science
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    • 제30권3호
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    • pp.661-676
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    • 2000
  • Gingivitis and periodontitis are infectious diseases in that microorganisms are the primary extrinsic cause of the diseases. the occurrence of gingivitis has been associated clearly with the presence of microorganisms at the disease site, and the histologic nature of the tissue involved is indicative of an inflammatory response induced by microorganisms. additional evidence for the microbial etiology of periodontal disease is that numerous antimicrobial agents are effective in reducing plaque accumulation and periodontal diseases. the purpose of this article is to analyze the antimicrobial effects of Pulsatilla koreana. Well-dried Pulsatilla koreana purchased from herbs distributor was ground and extracted into methanol(MeOH), ethylacetate(EtoAc), chlorform($CHCl_3$) and Butyl alcohol(BuOH). we have then applied each solution to the bacteria samples(Bacteroides forsythus, Streptococcus mutans, Streptococcus sanguis, Porphylomonas gingivalis, Actinobacillus actinomycetemcomitans, Eikenella corrodens, Prevotella intermedia, Actinomyces viscosus, Prevotella nigrescens , Rothia dentocariosa, Fusobacterium nucleatum, Pseudomonas aeruginosa, Staphylococcus aureus) collected from several organizations. To conduct susceptibility test(Kirby-Bauer method), plate contained each periodontopathic bacteria is spread extracted into methanol(MeOH), ethylacetate(EtoAc), chlorform($CHCl_3$) and Butyl alcohol(BuOH) and to measure the minimum inhibition concentration(MIC) of the bacteria against the solutions to ultimately determine antimicrobial effects of the solutions, insert bacteria sample into $20{\mu\ell}/{m\ell}$, $10{\mu\ell}/{m\ell}$, $5{\mu\ell}/{m\ell}$, $2.5{\mu\ell}/{m\ell}$ of each solution and control group(not contained solution) 1. Solution extracted into methanol did not show clear zone against all bacteria samples. Only P.nigrescens, S. mutans and S. sanguis in solution extracted into ethylacetate, S. mutans and S. anguis in solutions extracted into chlorform and Butyl alcohol showed clear zone against all bacteria samples. Solution extracted into Butyl alcohol showed clear zone against 13 types of bacteria, excluding P. gingivalis. 2. In Solution extracted into methanol, the bacteria samples grew in the highest concentrated plate, showing minimal variation from control group. 3. In Solution extracted into Butyl alcohol, S. aureus, P. intermedia, E. corrodens, A. actinomycetemcomitans, B. forsythus, P. gingivalis et al. showed decreased growth in the highest concentrated plate. P. auruginosa, R. dentocariosa, A. viscosus, P. nigrescens, S. mutans et al. showed decreased growth at MIC $20{\mu\ell}/{m\ell}$ and S. sanguis showed decreased growth at MIC $10{\mu\ell}/{m\ell}$. 4. By analyzing the MIC level through considering the results from Kirby-Bauer method, Solution extracted into methanol did not reveal any antimicrobial effects and Solution extracted into Butyl alcohol showed the highest antimicrobial effects In conclusion, it can be used the extracts of Pulsatilla koreana as wide spectrum antimicrobial agent.

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인쇄 출판 환경 변화에 따른 디지털 인쇄 방식의 BOD 솔루션에 관한 연구[I]: 템플릿 개발을 중심으로 I (A Study on the BOD Solution of Digital Method Print Publication due to Printing & Publishing Environmental Change[1]: With emphasis on the Development of a Template I)

  • 문성환;김성수;구철회
    • 한국인쇄학회지
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    • 제31권1호
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    • pp.51-64
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    • 2013
  • When it comes to current growth trend for the printing process in Asia printing market, offset printing, gravure printing and screen printing are reduced respectively -4%, -19%, -55%. In judging from the fact, the change in the printing production system from mass production on small amount to small production on mass amount is the biggest issue. For this reason, digital printing shows the significant growth. According to the increase of the growth 78% for electro photography way and 67% for ink-jet, it's not enough to catch up with digital printing which is increasing as time goes by to equip with hardware like as digital press. There's been necessary to install the BOD(Book on Demand) system which is the advanced and regular publication edit solution based on web-to-print model in the prepress, and it has made the BOD system be considered in relation to maximization of efficiency and production. Therefore, this research tries to step forward from the POD concept, which is refired to "Print along with the ordered quantities, the ordered appropriate time and the demanded place", so that it could expand the range of the printing/publishing environment using the BOD system, the order-made publication based on automatically operating template. And it tried to make the relation to digital web press on ink-jet method which is adequate to "mass production on small amount" with such advanced concept. This research also aims to use actively BOD solution model to promote the productivity of labor, and then to produce the printings across all related industries, which means to manufacture maximally the products on the shortest time at minimum place through PC equipments.