• 제목/요약/키워드: Solution combustion method

검색결과 127건 처리시간 0.024초

유체에 입자가 부상된 2상난류운동에서 유체-입자속도 2차상관관계에 관한 연구 (Investigation on fluid-particle velocity double correlation in fluid- particle two-phase turbulent flows)

  • 양선규;최영돈
    • 대한기계학회논문집
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    • 제12권6호
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    • pp.1438-1449
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    • 1988
  • 본 연구에서는 입자유동을 연속유체(continuous fluid)라 간주하는 2유체모델 을 적용하였고(Fig.2 참조), 실제 유동으로 2상난류제트유동, 관유동에 개발된 모델을 적용하여 모델의 타당성을 검토하였다.

Removal of sulfur element from high-sulfur coal by superconducting HGMS technology

  • Han, Shuai-shuai;Li, Su-qin;Yang, Rui-ming;Yang, Chang-qiao;Xing, Yi
    • 한국초전도ㆍ저온공학회논문지
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    • 제21권2호
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    • pp.26-30
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    • 2019
  • Coal is the most abundant fossil fuel on Earth and is used in a wide range of applications. The direct combustion of high-sulfur coal produces a large amount of sulfur dioxide, which is a toxic and corrosive gas. A new superconducting high gradient magnetic separation (HGMS) technology was studied to remove sulfur from high sulfur coal. The magnetic separation concentrate was obtained under the optimum parameters, such as a particle size of -200 mesh, a magnetic field strength of 2.0 T, a slurry concentration of 15 g/L, and a slurry flow rate of 600 ml/min. The removal rate of sulfur is up to 59.9%. The method uses a magnetic field to remove sulfur-containing magnetic material from a pulverized coal solution. It is simple process with, high efficiency, and is a new way.

저온연소법에 의한 이산화티탄의 합성 및 메틸렌블루의 광촉매 분해반응 (Synthesis of Titanium Dioxides Using Low Temperature Combustion Method and Photocatalytic Decomposition of Methylene Blue)

  • 백승희;정원영;이근대;박성수;홍성수
    • 공업화학
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    • 제20권3호
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    • pp.329-334
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    • 2009
  • 저온연소법을 이용하여 이산화티탄과 이트륨 이온이 첨가된 이산화티탄을 합성하였다. 합성조건에 따른 입자의 크기와 모양, 결정성 등에 미치는 영향을 알아보았고, 또한 제조된 촉매의 메틸렌블루의 광분해 활성을 조사하였다. XRD 분석 결과로부터 염기성 조건에서 합성된 경우에는 아나타제형 구조만 나타났으나 산성 및 중성에서는 아나타제와 루틸형이 혼합되어 나타났다. CA/TTIP 비에 관계없이 아나타제형 구조만 나타났으며, CA/TTIP 비가 증가할수록 입자의 크기는 작아지는 것을 볼 수 있다. 소성온도가 $600^{\circ}C$ 이상에서는 아나타제 결정구조가 루틸 결정구조로 변환되기 시작하였다. 한편, 입자들의 모양은 소성온도가 높아질수록 구형으로 변화되었으며, 입자의 크기가 증가하였다. 광촉매 반응의 활성은 CA/TTIP 몰비가 증가할수록, 염기성 조건에서 제조한 경우에 더 높게 나타났으며, $500^{\circ}C$에서 소성시킨 경우에 가장 높은 활성을 보여주었다. 그리고 1 mole% 이트륨 이온을 첨가 시킨 것이 가장 높은 광촉매 활성을 보여주었으며, 상업용 촉매인 P-25 경우보다 높은 활성을 보여주고 있다.

Characteristics Evaluation on Welding Metal Zones Welded with Inconel 625 Filler Metal to Cast Steel for Piston Crown Material

  • Jeong, Jae-Hyun;Moon, Kyung-Man;Lee, Sung-Yul;Lee, Myeong-Hoon;Baek, Tae-Sil
    • Journal of Advanced Marine Engineering and Technology
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    • 제39권5호
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    • pp.542-547
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    • 2015
  • Since the oil price has been significantly jumped for several years, a heavy oil of low quality has been mainly used in the diesel engine of the merchant ship. Thus, a combustion chamber of the engine has been often exposed to severely corrosive environment more and more because temperature of the exhaust gas of the combustion chamber has been getting higher and higher with increasing of using the heavy oil of low quality. As a result, wear and corrosion of the engine parts such as exhaust valve, piston crown and cylinder head surrounded with combustion chamber are more serious compared to the other parts of the engine. Therefore, an optimum repair welding for these engine parts is very important to prolong their lifetime in a economical point of view. In this study, Inconel 625 filler metal were welded with GTAW method in the cast steel which would be generally used with piston crown material. And the corrosion properties of weld metal, heat affected and base metal zones were investigated using electrochemical methods such as measurement of corrosion potential, anodic polarization curves, cyclic voltammogram and impedance etc. in 35% $H_2SO_4$ solution. The weld metal and base metal zones exhibited the highest and lowest values of hardness respectively. Furthermore, the corrosion current density of the weld metal zone revealed the lowest value, having the highest value of hardness. The corrosive products with red color and local corrosion like as a pitting corrosion were considerably observed at the base metal zone, while these morphologies were not wholly observed in the weld metal zone. In particular, the polarization characteristics such as impedance, polarization curve and cyclic voltammogran associated with corrosion resistance property were well in good agreement with each other. Consequently, it is suggested that the mechanical and corrosion characteristics of the piston crown can be predominantly improved by repair welding method using the Inconel 625 electrode.

Application of Cathodic Protection on Metallic Structure in Extremely Acidic Fluids

  • Chang, H.Y.;Yoo, Y.R.;Jin, T.E.;Kim, Y.S.
    • Corrosion Science and Technology
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    • 제4권4호
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    • pp.140-146
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    • 2005
  • Fossil fired power plant produces the electric energy by using a thermal energy by the combustion of fossil fuels as like oil, gas and coal. The exhausted flue gas by the combustion of oil etc. contains usually many contaminated species, and especially sulfur-content has been controlled strictly and then FGD (Flue Gas Desulfurization) facility should be installed in every fossil fired power plant. To minimize the content of contaminations in final exhaust gas, high corrosive environment including sulfuric acid (it was formed during the process which $SO_2$ gas combined with $Mg(OH)_2$ solution) can be formed in cooling zone of FGD facility and severe corrosion damage is reported in this zone. These conditions are formed when duct materials are immersed in fluid that flows on the duct floors or when exhausted gas is condensed into thin layered medium and contacts with materials of the duct walls and roofs. These environments make troublesome corrosion and air pollution problems that are occurred from the leakage of those ducts. The frequent shut down and repairing works of the FGD systems also demand costs and low efficiencies of those facilities. In general, high corrosion resistant materials have been used to solve this problem. However, corrosion problems have severely occurred in a cooling zone even though high corrosion resistant materials were used. In this work, a new technology has been proposed to solve the corrosion problem in the cooling zone of FGD facility. This electrochemical protection system contains cathodic protection method and protection by coating film, and remote monitoring-control system.

Recent research activities on hybrid rocket in Japan

  • Harunori, Nagata
    • 한국추진공학회:학술대회논문집
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    • 한국추진공학회 2011년도 제36회 춘계학술대회논문집
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    • pp.1-2
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    • 2011
  • Hybrid rockets have lately attracted attention as a strong candidate of small, low cost, safe and reliable launch vehicles. A significant topic is that the first commercially sponsored space ship, SpaceShipOne vehicle chose a hybrid rocket. The main factors for the choice were safety of operation, system cost, quick turnaround, and thrust termination. In Japan, five universities including Hokkaido University and three private companies organized "Hybrid Rocket Research Group" from 1998 to 2002. Their main purpose was to downsize the cost and scale of rocket experiments. In 2002, UNISEC (University Space Engineering Consortium) and HASTIC (Hokkaido Aerospace Science and Technology Incubation Center) took over the educational and R&D rocket activities respectively and the research group dissolved. In 2008, JAXA/ISAS and eleven universities formed "Hybrid Rocket Research Working Group" as a subcommittee of the Steering Committee for Space Engineering in ISAS. Their goal is to demonstrate technical feasibility of lowcost and high frequency launches of nano/micro satellites into sun-synchronous orbits. Hybrid rockets use a combination of solid and liquid propellants. Usually the fuel is in a solid phase. A serious problem of hybrid rockets is the low regression rate of the solid fuel. In single port hybrids the low regression rate below 1 mm/s causes large L/D exceeding a hundred and small fuel loading ratio falling below 0.3. Multi-port hybrids are a typical solution to solve this problem. However, this solution is not the mainstream in Japan. Another approach is to use high regression rate fuels. For example, a fuel regression rate of 4 mm/s decreases L/D to around 10 and increases the loading ratio to around 0.75. Liquefying fuels such as paraffins are strong candidates for high regression fuels and subject of active research in Japan too. Nakagawa et al. in Tokai University employed EVA (Ethylene Vinyl Acetate) to modify viscosity of paraffin based fuels and investigated the effect of viscosity on regression rates. Wada et al. in Akita University employed LTP (Low melting ThermoPlastic) as another candidate of liquefying fuels and demonstrated high regression rates comparable to paraffin fuels. Hori et al. in JAXA/ISAS employed glycidylazide-poly(ethylene glycol) (GAP-PEG) copolymers as high regression rate fuels and modified the combustion characteristics by changing the PEG mixing ratio. Regression rate improvement by changing internal ballistics is another stream of research. The author proposed a new fuel configuration named "CAMUI" in 1998. CAMUI comes from an abbreviation of "cascaded multistage impinging-jet" meaning the distinctive flow field. A CAMUI type fuel grain consists of several cylindrical fuel blocks with two ports in axial direction. The port alignment shifts 90 degrees with each other to make jets out of ports impinge on the upstream end face of the downstream fuel block, resulting in intense heat transfer to the fuel. Yuasa et al. in Tokyo Metropolitan University employed swirling injection method and improved regression rates more than three times higher. However, regression rate distribution along the axis is not uniform due to the decay of the swirl strength. Aso et al. in Kyushu University employed multi-swirl injection to solve this problem. Combinations of swirling injection and paraffin based fuel have been tried and some results show very high regression rates exceeding ten times of conventional one. High fuel regression rates by new fuel, new internal ballistics, or combination of them require faster fuel-oxidizer mixing to maintain combustion efficiency. Nakagawa et al. succeeded to improve combustion efficiency of a paraffin-based fuel from 77% to 96% by a baffle plate. Another effective approach some researchers are trying is to use an aft-chamber to increase residence time. Better understanding of the new flow fields is necessary to reveal basic mechanisms of regression enhancement. Yuasa et al. visualized the combustion field in a swirling injection type motor. Nakagawa et al. observed boundary layer combustion of wax-based fuels. To understand detailed flow structures in swirling flow type hybrids, Sawada et al. (Tohoku Univ.), Teramoto et al. (Univ. of Tokyo), Shimada et al. (ISAS), and Tsuboi et al. (Kyushu Inst. Tech.) are trying to simulate the flow field numerically. Main challenges are turbulent reaction, stiffness due to low Mach number flow, fuel regression model, and other non-steady phenomena. Oshima et al. in Hokkaido University simulated CAMUI type flow fields and discussed correspondence relation between regression distribution of a burning surface and the vortex structure over the surface.

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THE MORPHOLOGY OF CHROMIUM AND LIF MEASUREMENT OF ATOMIC ARSENIC IN LAMINAR DIFFUSION FLAMES

  • Yoon, Young-Bin
    • 한국연소학회:학술대회논문집
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    • 한국연소학회 1997년도 제15회 KOSCO SYMPOSIUM 논문집
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    • pp.61-68
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    • 1997
  • The morphology and size distribution of chromium oxides and the concentration measurement of atomic arsenic have been studied in laminar diffusion flames. Nitrogen was added to vary flame temperatures in hydrogen flames. Ethene flames were used in order to investigate the potential for interaction between the soot aerosol that is formed in these flames and the chromium aerosol. Two sources of chromium compounds were introduced: chromium nitrate and chromium hexacarbonyl. A detailed investigation of the morphology was carried out by scanning electron microscopy (SEM). The amounts of Cr(VI) and total Cr were determined by a spectrophotometric method and by X-ray fluorescence spectrometry, respectively. Also, LIF was used for the measurement of atomic arsenic, which was excited at 197.2 nm and was detected at 249.6 nm. Results showed that the morphology of the particles varied with the flame temperature and with the chromium source. The particles were characterized by porous structures, cenospheres and agglomerated dense particles when chromium nitrate solution was added to the flames. At low to moderate temperatures, porous sintered cenospheric structures were formed, in some cases with a blow hole. At higher temperatures, an agglomerated cluster which was composed of loosely sintered submicron particles was observed. It was also found that the emission of Cr(VI) from the undiluted $H_2$ flame was more than 10 times larger than in the 50% $H_2$ / 50% $N_2$ flame on a mass basis. Single point LIF measurement of atomic arsenic indicated that arsenic exist only in the low temperature, fuel rich region.

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Domain Decomposition Approach Applied for Two- and Three-dimensional Problems via Direct Solution Methodology

  • Kwak, Jun Young;Cho, Haeseong;Chun, Tae Young;Shin, SangJoon;Bauchau, Olivier A.
    • International Journal of Aeronautical and Space Sciences
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    • 제16권2호
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    • pp.177-189
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    • 2015
  • This paper presents an all-direct domain decomposition approach for large-scale structural analysis. The proposed approach achieves computational robustness and efficiency by enforcing the compatibility of the displacement field across the sub-domain boundaries via local Lagrange multipliers and augmented Lagrangian formulation (ALF). The proposed domain decomposition approach was compared to the existing FETI approach in terms of the computational time and memory usage. The parallel implementation of the proposed algorithm was described in detail. Finally, a preliminary validation was attempted for the proposed approach, and the numerical results of two- and three-dimensional problems were compared to those obtained through a dual-primal FETI approach. The results indicate an improvement in the performance as a result of the implementing the proposed approach.

특성곡선법과 다중길이 척도법을 이용한 가솔린 기관의 기관성능시뮬레이션 개선에 관한 연구 (A Study on the Improvment of Engine Performance Simulation Using Multi-Length-Scale Model and MOC)

  • 김철수
    • Journal of Advanced Marine Engineering and Technology
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    • 제25권3호
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    • pp.605-616
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    • 2001
  • Generally, there are two methods in researching internal combustion engines. One is by experimental research and the other is by computer simulation. The experimental research has many merits that researchers can get data for engine performance, but it has also some demerit of cost and time. If there is an engine simulation code with accuracy for the solution, it is very convenient to predict the performance and optimum design value of the engine. In this study, engine performance simulation program has been improved to predict the transient variation of properties of gas in cylinder, intake and exhaust manifolds, There total program code was developed to calculate the pressure, flame factor and turbulent intensity, As a result of present study, the authors could predicted the in-cylinder pressure, intake manifold pressure and the engine performance in various conditions. The authors also could easily prepare the tool if optimum design of manifold and in-cylinder geometry.

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용액연소법에 의한 CMR용 ${La_{0.7}}{Ca_{0.3}}{MnO_3}$분말 제조 및 전기.자기적 특성 (Powder Preparation and Electrical and Magnetic Properties of ${La_{0.7}}{Ca_{0.3}}{MnO_3}$by Solution Combustion Method for CMR Applications)

  • 이강렬;민복기;박성
    • 한국세라믹학회지
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    • 제38권6호
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    • pp.551-557
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    • 2001
  • La$_{0.7}$Ca$_{0.3}$MnO$_3$분말을 용액연소법으로 제조하였으며 분말 특성과 CMR에 응용하기 위해 박막의 전기적, 자기적 특성을 조사하였다. 조성과 구조 특성을 XRD와 SEM으로부터 조사하였으며 분말의 하소온도를 TG 분석으로부터 결정하였다. 또한 소결성은 dilatometer에 의해 조사되었으며 분말 특성은 BET에 의해 조사되었다. 소결성이 우수한 분말을 이용하여 스퍼터 타겟으로 제조하였으며 SiO$_2$/Si 기판 위에 스퍼터링한 후, 온도에 따른 four point probe 측정으로 막의 MR비를 측정하였다. VSM (Vibrating Sample Magnetometer)를 이용하여 증착된 막의 온도에 따른 자화율(Magnetization:M)을 측정하였다. 분말 특성으로는 평균입자 크기가 sub-micron 이하로 초미세하고 49.44$m^2$/g의 비표면적 값을 얻을 수 있었으며 고순도의 perovskite 구조를 갖는 La$_{0.7}$Ca$_{0.3}$MnO$_3$분말을 쉽게 얻을 수 있었다. 온도에 따른 저항값의 변화로부터 96K에서 최고의 MR값을 얻을 수 있었으며, 240K에서 강자성체로 전이되었다.로 전이되었다.

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