• Title/Summary/Keyword: Solution behavior

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Effect of Co2O3 addition on liquid phase sintering behavior and mechanical properties of commercial alumina (Co2O3 첨가가 알루미나의 액상소결 및 기계적 물성에 미치는 영향)

  • Oh, Bok Hyun;Yoon, Tae-Gyu;Kong, Heon;Kim, Nam-Il;Lee, Sang-Jin
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.30 no.4
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    • pp.150-155
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    • 2020
  • Alumina (Al2O3) is mainly used as a structural ceramic material and to have good mechanical properties requires a dense microstructure. In commercial fabrication, the liquid phase sintering process is adjusted to reduce the sintering temperature of alumina. In this study, the effect of added amounts of cobalt oxide as a coloring agent on the microstructure and mechanical properties was investigated in the CaO-SiO2-MgO-system liquid phase sintering of 92 % alumina at various sintering temperatures. When 11 wt% Co2O3 was added, a rearrangement of alumina particles, which is the main densification step in liquid phase sintering, occurred from a sintering temperature of 1200℃. Solution re-precipitation and coalescence steps followed from 1300℃ with the grain growth of alumina particles. The addition of excess Co2O3 and sintering temperatures above 1400℃ resulted in a decrease in sintered density and Vickers hardness, because of the low viscosity of the liquid phase. In 92 % alumina with the addition of 11 wt% Co2O3, a sintered density and Vickers hardness of 3.86 g/㎤ and 12.32 GPa, respectively, were obtained at a sintering temperature of 1350℃.

Mixed Micellar Properties of Sodium n-Octanoate(SOC) with n-Octylammonium Chloride(OAC) in Aqueous Solution (Sodium n-Octanoate(SOC)와 n-Octylammonium Chloride(OAC)의 혼합마이셀화에 관한 연구)

  • Lee, Byeong Hwan
    • Journal of the Korean Chemical Society
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    • v.46 no.6
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    • pp.495-501
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    • 2002
  • The critical micelle concentration(CMC) and the counterion binding constant(B) for the mixed micel-lization of sodium n-octanoate(SOC) with n-octylammonium chloride(OAC) were determined as a function of the overall mole fraction of $SOC({\alpha}_1).$ Various thermodynamic parameters($x_i$, $Y_i$, $C_i$, $${\alpha}_i^M$$, and $\Delta$$H_{mix}$) for the mixed micellization of the SOC/OAC systems have been calculated and analyzed by means of the equations derived from the nonideal mixed micellar model. The results show that there are great deviations from the ideal behavior for the mixed micellization of these systems. And other thermodynamic parameters(${\Delta}$$G^0_m$, ${\Delta}$$H^0_m$, and ${\Delta}$$S^0_m$) associated with the micellization of SOC,OAC, and their $mixture({\alpha}_1=0.5)$ have been also estimated from the temperature dependence of CMC and B values, and the significance of these parameters and their relation to the theory of the micelle formation have been considered and analyzed by comparing each other.

An Economic Analysis of Alternative Mechanisms for Optimal IT Security Provision within a Firm (기업 내 최적 정보기술보안 제공을 위한 대체 메커니즘에 대한 경제적 분석)

  • Yu, Seunghee
    • Asia-Pacific Journal of Business Venturing and Entrepreneurship
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    • v.8 no.2
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    • pp.107-117
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    • 2013
  • The main objective of this study lies at examining economic features of IT security investment and comparing alternative mechanisms to achieve optimal provision of IT security resources within a firm. There exists a paucity of economic analysis that provide useful guidelines for making critical decisions regarding the optimal level of provision of IT security and how to share the costs among different users within a firm. As a preliminary study, this study first argues that IT security resources share some unique characteristics of pure public goods, namely nonrivalry of consumption and nonexcludability of benefit. IT security provision problem also suffers from information asymmetry problem with regard to the valuation of an individual user for IT security goods. Then, through an analytical framework, it is shown that the efficient provision condition at the overall firm level is not necessarily satisfied by individual utility maximizing behavior. That is, an individual provision results in a suboptimal solution, especially an underprovision of the IT security good. This problem is mainly due to the nonexcludability property of pure public goods, and is also known as a free-riding problem. The fundamental problem of collective decision-making is to design mechanisms that both induce the revelation of the true information and choose an 'optimal' level of the IT security good within this framework of information asymmetry. This study examines and compares three alternative demand-revealing mechanisms within the IT security resource provision context, namely the Clarke-Groves mechanism, the expected utility maximizing mechanism and the Groves-Ledyard mechanism. The main features of each mechanism are discussed along with its strengths, weaknesses, and different applicability in practice. Finally, the limitations of the study and future research are discussed.

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Physical and Mechanical Properties of Cements for Borehole and Stability Analysis of Cement Sheath (관정 시멘팅 재료의 물리역학물성 및 시멘트층의 안정성 분석)

  • Kim, Kideok;Lee, Hikweon;Kim, Taehee;Kim, Gyo-Won
    • The Journal of Engineering Geology
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    • v.26 no.1
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    • pp.101-115
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    • 2016
  • We carried out laboratory material tests on two cements (KS-1 ordinary Portland and Class G) with changing W/S (Water/Solid) and the content of fly ash in order to evaluate their physical and mechanical properties. The specimens of KS-1 ordinary Portland cement were prepared with varying W/S (Solid=cement) in weight, while those of Class G cement were prepared with changing the content of fly ash in volume but maintaining W/S (Solid=cement+fly ash). The results of the material tests show that as the W/S in KS-1 ordinary Portland cement and the content of fly ash in Class G cement increase, the properties (density, sonic wave velocity, elastic constants, compressive and tensile strengths, thermal conductivity) decrease, but porosity and specific heat increase. In addition, an increase in confining pressure and in the content of fly ash leads to plastic failure behavior of the cements. The laboratory data were then used in a stability analysis of cement sheath for which an analytical solution for computing the stress distribution induced around a cased, cemented well was employed. The analysis was carried out with varying the injection well parameters such as thickness of casing and cement, injection pressure, dip and dip direction of injection well, and depth of injection well. The analysis results show that cement sheath is stable in the cases of relatively lower injection pressures and inclined and horizontal wells. However, in the other cases, it is damaged by mainly tensile failure.

Measurement of $\textrm{CO}_2$ Concentration and Leaf Area Index for Crop Photosynthesis Model in Sweet Pepper (단고추의 작물 광합성 모델을 위한 $\textrm{CO}_2$ 농도와 엽면적지 수 측정)

  • Lee, Beom-Seon;Chung, Soon-Ju;Jang, Hong-Gi
    • Journal of Bio-Environment Control
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    • v.8 no.3
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    • pp.192-201
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    • 1999
  • This study was aimed to introduce the measurement of $CO_2$ concentration and leaf area index in the phytotron for predicting the effect of CO.E, light and leaf area index on the instantaneous photosynthetic rate of sweet pepper with the existing ASKAM model. Measurements were made in 2 semi-closed phytotron compartments in which three different $CO_2$ concentrations were applied at random. Plants were grown on containers with circulating nutrient solution at 21$^{\circ}C$ and 80-95% relative humidity. The model estimates crop net $CO_2$ uptake for short time intervals during the day based on short-term data of daily radiation, temperature and $CO_2$ concentration. During the photosynthesis measurements, $CO_2$ concentrations in both compartments and in the basement were measured every minute. This was also done for the flow of pure $CO_2$ into the compartment, global radiation, photosynthetic active radiation inside the compartment, temperature and relative humidity. Crop growth models summarize our knowledge on crop behavior and have as such a wide range of applications in analysis, crop management and thus as a farm management tool.

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The Relationship of Psychosocial Factors to Blood Pressure (사회심리학적인 요인과 혈압의 관계)

  • Lee, Choong-Won;Lee, Sung-Kwan
    • Journal of Preventive Medicine and Public Health
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    • v.21 no.1 s.23
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    • pp.99-112
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    • 1988
  • Questionnaires and blood pressure measurements were administered to 279 medical school undergraduates in 1987 to investigate the relationship between psychosocial factors and blood pressure as well as reliability and validity of the Framingham Type A Behavior Scale(FTA). The reliability coefficients of SCL-90-R and nh measured by Spearman-Brown haves split test were $0.57{\sim}0.91$. The factors of FTA extracted by principal component analysis were hard-driving competitiveness factor and impatience factor(2-factor solution) . The total score of nh was positively correlated with relative weight and place raised but the correlations were insignificant, and had significantly positive but weak correlations with depression, anxiety, hostility, paranoid, and psychoticism subscales of SCL-90-R. In the univariate analysis of blood pressures, relative weight and family history were significant in systolic pressure in males and economic status was significant in blood pressures in both sexes. For diastolic pressure, relative weight and frequency of alcohol intake were significant in males and relative weight was in females. After controlling relative weight, the frequency of alcohol intake for diastolic pressure and economic status for systolic pressure were significant in males. The important variables selected by stepwise regression analysis were relative weight and economic status for systolic pressure of males and relative weight and the frequency of alcohol intake for diastolic pressure. At the level of alpha 0.1, depression subscale was added to the model, changing coefficient of determination 0.206 to 0.217. In females, economic status and relative weight were selected for systolic pressure and for diastolic pressure body mass index alone, but the model of blood pressure for females was considered to be unstable due to small sample size(56). FTA was unrelated to the blood pressures in both sexes.

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Experimental Study on the Hydrodynamic Dispersion of Contaminants in Geologic Media : Adsorption and Diffusion of Sr and Cr-EDTA in Granitic Rocks (수리지질계에서 지질매체에 따른 오염물질의 수리분산에 관한 실험적 연구 : 화강암질암에서 Sr과 Cr-EDTA의 흡착 및 확산에 관한 연구)

  • Chang, Ho-Wan;Lee, Kwang-Sik
    • Journal of the Korean Society of Groundwater Environment
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    • v.1 no.2
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    • pp.105-112
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    • 1994
  • To investigate the migration behavior of contaminants in rocks. adsorption and diffusion experiments for Sr as a sorbing contaminant and for Cr-EDTA as a non-sorbing contaminant were carried out on granitic rocks. The Sr adsorption on separated minerals and crushed rocks tends to slightly increase with increasing pH. It also greatly decreases with the increase of ionic strength in NaCl solution. Among separated minerals, biotite and sericite have adsorbed much more amount of Sr than other rock-forming minerals, such as quartz, plagioclase, and potassic feldspar, because the specific surfaces and cation exchange capacities of phyllosilicates are generally much greater than those of the other rock-forming minerals. The intrinsic diffusion coefficients of Cr-EBTA for granitic rocks differ little from those of Sr. This indicates that they are independent of water-rock interactions. Experimental data show that the intrinsic diffusion coefficients are positively correlated with the porosities of the rocks. They are close to the theoretically predicted values, especially in pre-steady state diffusion region, with the increase of rock sample thickness.

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Effects of Addition of Sulfuric Acid on the Etching Behavior of Al foil for Electrolytic Capacitors II. Microstructures of Dielectric Layers and AC Impedance Analysis (전해 콘텐사용 알루미늄박의 애칭특성에 미치는 황산첨가의 영향 II. 유전층의 조직 및 임피던스 분석)

  • Kim, Seong-Gap;Yu, In-Jong;Sin, Dong-Cheol;O, Han-Jun;Ji, Chung-Su
    • Korean Journal of Materials Research
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    • v.10 no.5
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    • pp.375-381
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    • 2000
  • Aluminium foil for electrolytic capacitors was anodized at the voltage of 100V and 140V for 10 minutes in ammonium adipate solution to form aluminum oxide layer on aluminum substrate as an dielectric film. The thickness, the stoichiometry and the crystal structure of the layer were investigated by using RBS and TEM . In addition EIS technique was employed to study the effects of addition of sulfuric acid on the increment of the foil surface area. It was found that the thickness values of the layers anodized at 100V and 140V were about 130 nm and 190 nm respectively and the stoichiometry of the elements of aluminum and oxygen was 2:3. The anodic oxide layer was shown to be amorphous. but the structure irradiated with electron beam resulted in the transformation into crystalline structure of $${\gamma}$-Al_2$$O_3$ . From a comparison of the impedance results and the capacitance variation to investigate the ef- fects of sulfuric acid addition to the etching bath of hydrochloric acid, the EIS techinque could be useful to analyze the capacitance variation.

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Characteristics of SiO2/Si Quantum Dots Super Lattice Structure Prepared by Magnetron Co-Sputtering Method (마그네트론 코스퍼터링법으로 형성한 SiO2/Si 양자점 초격자 구조의 특성)

  • Park, Young-Bin;Kim, Shin-Ho;Ha, Rin;Lee, Hyun-Ju;Lee, Jung-Chul;Bae, Jong-Seong;Kim, Yang-Do
    • Korean Journal of Materials Research
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    • v.20 no.11
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    • pp.586-591
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    • 2010
  • Solar cells have been more intensely studied as part of the effort to find alternatives to fossil fuels as power sources. The progression of the first two generations of solar cells has seen a sacrifice of higher efficiency for more economic use of materials. The use of a single junction makes both these types of cells lose power in two major ways: by the non-absorption of incident light of energy below the band gap; and by the dissipation by heat loss of light energy in excess of the band gap. Therefore, multi junction solar cells have been proposed as a solution to this problem. However, the $1^{st}$ and $2^{nd}$ generation solar cells have efficiency limits because a photon makes just one electron-hole pair. Fabrication of all-silicon tandem cells using an Si quantum dot superlattice structure (QD SLS) is one possible suggestion. In this study, an $SiO_x$ matrix system was investigated and analyzed for potential use as an all-silicon multi-junction solar cell. Si quantum dots with a super lattice structure (Si QD SLS) were prepared by alternating deposition of Si rich oxide (SRO; $SiO_x$ (x = 0.8, 1.12)) and $SiO_2$ layers using RF magnetron co-sputtering and subsequent annealing at temperatures between 800 and $1,100^{\circ}C$ under nitrogen ambient. Annealing temperatures and times affected the formation of Si QDs in the SRO film. Fourier transform infrared spectroscopy (FTIR) spectra and x-ray photoelectron spectroscopy (XPS) revealed that nanocrystalline Si QDs started to precipitate after annealing at $1,100^{\circ}C$ for one hour. Transmission electron microscopy (TEM) images clearly showed SRO/$SiO_2$ SLS and Si QDs formation in each 4, 6, and 8 nm SRO layer after annealing at $1,100^{\circ}C$ for two hours. The systematic investigation of precipitation behavior of Si QDs in $SiO_2$ matrices is presented.

Effects of Methacrylamide Treatment on Silk Fibers III. Polymerization Behavior of Methacrylamide (견섬유에 대한 메타크릴아미드의 처리효과 III. 메타크릴아미드의 중합거동)

  • 신봉섭;남중희
    • Journal of Sericultural and Entomological Science
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    • v.34 no.2
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    • pp.32-40
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    • 1992
  • Many studies have been carried out on the graft finishing in order to improve the quality of silk fiber. Various vinyl monomers, for instance, styrene, methylmethacrylate, 2-hydroxyeth-ylmethacrylate and methacrylamide, have been used practically up to date. Among these monomers, methacrylamide has been applied as the most favourable monomer onto silk fibers in recent years. The polymerization mechanism about styrene- and methylmethacrylate-grafted silk fiber has been studied by many researchers. They proposed that free radicals were formed and vinyl monomers were polymerized in silk fibroin by graft polymerization mechanism, while active sites were varied by the types of monomer and initiator as well as by the reaction condition. In general. there is another Opinion that monomers are polymerized and impregnated in the internal side of the fiber by homopolymerization, which has not been proved experimentally yet More than 10 years have been passed since methacrylamide was applied on the silk fiber, and at the present time most finishings are being achieved by methacrylamide. However, no attention has been paid to the polymerization mechanism of the methacrylamide-treated silk fiber yeL In this paper, the treatments of methacrylamide on silk fibers were studied in aqueous solution using potassium persulfate as an initiator. The polymerization mechanism of the methacrylamide-treated silk fibers was investigated and analyzed on the basis of the results of infrared spectroscopy, amino acid analysis and scanning electron microscopy. From the results of these instrumental analyses, it can be suggested that polymerization mechanism about the methacrylamide-treated silk fibers is not performed by graft polymerization which has been accepted generally in styrene and methylmethacrylate-grafted silk fibers. The different mechanism is supposed to be due to the difference in monomer types, initiator types and treatment conditions.

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