• 제목/요약/키워드: Solution Mixing Method

검색결과 238건 처리시간 0.031초

용액혼합법에 따른 나노복합재료 분산성 및 전기적 특성 (Dispersibility, Electrical Property of Nano-Composite by Solution Mixing Method)

  • 양훈;박대희
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2008년도 춘계학술대회 논문집 센서 박막재료연구회 및 광주 전남지부
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    • pp.73-74
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    • 2008
  • In this paper, we have investigated dispersibility, volume resistivity of nano-composite by solution mixing method. Dispersibility measured by FE-SEM(Field Emission Scanning Electron Microscope. And volume resistivity measured by ASTM D991. To expect interaction used dual filler system. But, dual filler system had influence on polymer complex. So, polymer chain mobility doesn't resist.

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마이크로 믹서에서 와도 지수와 혼합 지수의 관계;비용해성 물질 (The Relation between Vortex Index and Mixing Index in Micromixer;Insoluble Solution;Insoluble Solution)

  • 맹주성;김범중;조일대
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2004년도 춘계학술대회
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    • pp.1841-1844
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    • 2004
  • 'Mixing Index($D_I$)'s generally used to measure the degree of mixing. A new method to calculate $D_I$ was proposed, when insoluble solution flows in micromixer. 'Vortex Index (${\Omega}_I$)'which indicate the degree of chaotic advection, is defined and formulated. A lots of arbitrary shaped microchannels were tested to calculate the $D_I$ and ${\Omega}_I$. And then a simple algebraic equation, $D_I=A{\Omega}_I+B$, was obtained. This equation may be used instead of partial differential equation, concentration equation.

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3차 상태방정식과 여러 혼합법칙 및 Kirkwood-Buff용액이론을 이용한 초임계유체내에서의 용질의 무한희석 부분몰부피의 계산 (Prediction of partial molar volumes of solutes in supercritical CO2 using the Peng-Robinson equation of state with various mixing rules and Kirkwood-Buff solution theory)

  • 전영표;박종선;권영중
    • 산업기술연구
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    • 제19권
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    • pp.253-260
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    • 1999
  • Two thermodynamic models were used to predict the partial molar volumes of solutes in supercritical carbon dioxide at infinite dilution: (1) the Peng-Robinson equation of state with various mixing rules including those based on $EOS/G^E$ (2) the Kirkwood Buff fluctuation integral with the hard sphere expansion (HSE) method. The Kirkwood-Buff fluctuation integral method, in which an equation of state for pure component and molecular parameters are required, produced better results especially near the critical point than the Peng-Robinson equation of state with the several mixing rules based an $EOS/G^E$. When the $EOS/G^E$ mixing rules were used, poorer results were obtained compared with the classical mixing rule and Kirkwood-Buff model.

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電氣傳導度 測定에 依한 連續流 攪拌槽의 混合時間 測定 (A Mixing Time Measurement by a Conductivity Method in a Continuous Flow Stirred Tank)

  • 강웅기
    • 대한화학회지
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    • 제6권2호
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    • pp.130-132
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    • 1962
  • A new method of evaluating the mixing time in the continuous flow stirred tank is herein proposed. Experimental results to test the concept are also presented.The mixing time is defined as the time interval between the injection of a slug of an electrolyte solution into the tank and the moment at which an essentially straight line begins on a plot of the conductivity of effluent versus time.The proposed method of measuring the mixing time is valid even for the low mixing time (5 seconds) and the results obtained agree well with previous work, where the mixing time measurements were carried out by the injection of a dye into the feed stream.

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마이크로 믹서에서 와도 지수에 의한 비용해성 물질의 혼합 예측 (Prediction of Degree of Mixing for Insoluble Solution with Vortex Index in a Passive Micromixer)

  • 조일대;김범중;맹주성
    • 대한기계학회논문집B
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    • 제29권2호
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    • pp.232-238
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    • 2005
  • The 'Mixing Index($D_I$)' is used as a conventional guidance measuring the degree of mixing for multiphase flows. For the case when insoluble solutions flow in a passive micromixer, a new method to calculate $D_I$ is proposed. The 'Vortex Index(${\Omega}_I$)' is suggested and formulated. We infer that ${\Omega}_I$ relates to the degree of chaotic advection. Various arbitrary shaped microchannels were tested to calculate the $D_I\;and\;{\Omega}_I$, and then a simple algebraic equation, $D_I=Aexp(B{\Omega}_I)$, is obtained. This equation may be used instead of the conventional partial differential equation, concentration equation, to estimate the degree of mixing.

나노실리카 졸을 배합수 중량치환 방법으로 혼합한 OPC-slag cement의 특성 (The Properties of OPC-Slag Cement Mixed with Nano-Silica Solution by Mixing Water Weight Replacement Method)

  • 서기영;김태완;김성도
    • 한국구조물진단유지관리공학회 논문집
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    • 제24권1호
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    • pp.24-34
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    • 2020
  • 본 연구는 nano-silica solution(NSS)을 배합수 중량치환방법을 사용한 OPC-slag cement의 특성에 관한 연구이다. 새로운 치환방법은 선행연구들보다 높은 NSS 치환율의 시멘트에 대한 거동을 연구하기 위한 기초 단계이다. NSS는 배합수 중량의 10%, 20%, 30%, 40%, 그리고 50% 치환하였다. 그 결과 역학적 및 미세구조적 특성이 향상되는 결과를 보였다. 이는 두 가지 원인으로 요약된다. 첫 번째는 NSS를 배합수중량 치환하면 나노 실리카 입자의 균질한 분산작용이 향상된다. 이는 초기 수화작용을 촉진한다. 두 번째는 배합수 보다 밀도가 큰 NSS의 치환은 w/b를 감소시킨다. 이는 치밀한 수화반응물질을 형성시킨다. 새로운 치환방법은 선행연구에서 밝혀진 분말형 나노 실리카 입자를 사용한 결과와 비교하여 역학적과 미세구조 특성의 저하가 나타나지 않았다. 따라서 본 연구에서 사용한 NSS를 배합수 중량 치환한 방법은 OPC-GGBFS cement의 배합에 적용 가능할 것으로 판단된다.

$^7Li$ NMR studies of LiMn$_2$O$_4$ prepared by eutectic self-mixing method without any mixing

  • Lee, Youngil;Kyooseung Han;Hyunkoo Kang;Jaebum Choo
    • 한국자기공명학회:학술대회논문집
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    • 한국자기공명학회 2002년도 International Symposium on Magnetic Resonance
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    • pp.85-85
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    • 2002
  • Lithiated transition metal oxides such as LiMn2O4, Lil-xMnO$_2$, LiNiO$_2$, LiCoO$_2$, and their solid solution phases are used as cathode materials for lithium rechargeable batteries. We prepared the cathode materials using a novel eutectic self-mixing method without any artificial mixing procedures. This method provides an extraordinarily simple way to make the cathode materials, and it is possible to prepare at very low temperature such as 25$0^{\circ}C$. Furthermore, the cathode materials produced have discharge capacities that are much better than cathode materials prepared by previously reported synthetic methods. The spontaneous and homogeneous mixing is verified by $^{7}$ Li magic-angle-spinning (MAS) NMR spectroscopy.

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탄소나노섬유가 강화된 하이브리드 복합재료의 기계적 물성 (Mechanical Properties of Carbon Nanofiber Reinforced Hybrid Composites)

  • 공진우;정상수;김태욱
    • 한국복합재료학회:학술대회논문집
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    • 한국복합재료학회 2004년도 추계학술발표대회 논문집
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    • pp.31-34
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    • 2004
  • Carbon nanofiber exhibits superior and often unique characteristics of mechanical, electrical chemical and thermal properties. In this study, For improvement of the mechanical properties of composites, carbon nanofiber reinforced hybrid composites was investigated. For the effect of dispersion, The dispersion methods of solution blending and mechanical mixing were used. The mixing of solution blending method was used using ultrasonic. Dispersion of carbon nanofiber was observed by scanning electron microscope (SEM). Mechanical properties were measured by universal testing Machine (UTM).

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두개의 동등한 상호침투 부격자로 구성된 이성분 격자 용액의 혼합자유에너지 (The Free Energy of Mixing for a Binary Lattice Solution Consisting of Two Identical Interpenetrating Sublattices)

  • 정해영
    • 대한화학회지
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    • 제66권4호
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    • pp.278-283
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    • 2022
  • Kirkwood의 방법을 이용하여 단순입방격자나 체심입방격자와 같이 두개의 동등한 상호침투 격자로 구성된 이성분 격자 용액의 자유에너지를 절대온도 역수의 10차항까지 계산하였다. 이를 이용하여 이성분 격자 용액에 대한 액체-액체 공존 곡선과 임계용액온도를 계산하여 분자들의 논랜덤 혼합 효과를 정량적으로 살펴보았다. 그리고 단순입방격자 이성분용액의 공존 곡선을 Monte-Carlo 컴퓨터 모사의 결과와 비교하여 잘 일치하는 것을 알 수 있었다.

화학용액 혼합과 수소환원법을 이용한 나노구조 Fe-Co 합금분말의 제조 (Chemical Solution Mixing and Hydrogen Reduction Method for Fabrication of Nanostructured Fe-Co Alloy Powders)

  • 박광현;박현우;이백희;장시영;이정근;김영도
    • 한국분말재료학회지
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    • 제11권2호
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    • pp.137-142
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    • 2004
  • In this study, chemical solution mixing and hydrogen reduction method was used to fabricate nanostructured $Fe_xCo_{1-x}$ alloy powders. Fe-Co chloride mixture, FeCl$_2$ and COCI$_2$ with 99.9% purity, were reduced in hydrogen atmosphere. Nanostructured Fe-Co alloy powders with a grain size of 50 nm were successfully fabricated. Magnetic properties of fabricated $Fe_xCo_{1-x}$(x=0, 10, 30, 50, 70, 100) alloy powders with the same grain size were measured because size factor can affect magnetic properties. Coercivity of Fe-Co alloy powders were increased with increasing Co contents. Maximum value of coercivity in various Co contented Fe-Co alloy powders with similar grain size was 125 Oe at Fe$_{100}$. Saturation magnetization value at Fe$_{70}$Co$_{30}$ composition showed maximum value of 219 emu/g and saturation magnetization value decreased with increasing Co contents and minimum value of 155 emu/g was observed at Co$_{100}$.