• 한국막학회:학술대회논문집
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• 한국막학회 1996년도 추계 총회 및 학술발표회
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• pp.3-7
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• 1996

A rigorous analysis on the effect of colloidal interactions on the separation characteristic has been extended to the case of non-dilute charged solute concentration. The solute partitioning within slit pores for a wide range of solute concentration has been predicted by performing the Monte Carlo technique. Using a hindered transport model, rejection coefficients have been estimated from the predicted concentration profile.

• 한국물환경학회지
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• 제20권3호
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• pp.296-300
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• 2004

The rejection properties of 6 aromatic pesticides were evaluated by a continuous flow system equipped with a hollow fiber NF membrane. Different from the separation experiment of batch cell, the rejection and the removal could be calculated exactly because the concentration of feed, permeate and retentate was separately obtained. The lowest and the highest rejection were found in carbaryl(54.8%) and methoxychlor(99.2%), respectively, and the removals were always shown higher than rejections. This may be caused by some reasons such as the solute adsorption on the membrane, the variation of feed concentration. Although molecular weight, molecular width regarded as solute characteristics and log P(n-octanol/water partition coefficient) as hydrophobicity could be applied to explain the rejection property, these factors should be considered together for better analysis. According to the higher relationship between log B(solute permeability) and molecular weight, it was revealed that the solute separation with this membrane was influenced more by molecular weight.

• Journal of Oral Medicine and Pain
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• 제25권1호
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• pp.9-28
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• 2000

The purpose of this article, the first part of series, is to describe the general theory applicable to various chromatographic procedures. History of chromatography, separation of matters, classification of chromatography, underlying principles of separation in chromatography, covering resolution, column efficiency, column selectivity, and capacity factor, movement of solute in chromatographic phase, including elution development, displacement development, and frontal analysis, were discussed. Mathematical description of plate theory and thermodynamic viewpoint of retention were emphasized.

• 한국막학회:학술대회논문집
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• 한국막학회 2000년도 추계 총회 및 국제학술발표회
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• pp.71-74
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• 2000

• 한국염색가공학회지
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• 제17권3호
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• pp.34-42
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• 2005

In this work, a practical separation performance was investigated on aqueous alcohol solutions, especially for iso-propyl alcohol (IPA), which is usually used during the semi- conductor rinsing process. The removal of various substances from waste aqueous IPA solutions was carried out by microfiltration with $0.1\~1{\mu}$m pore size of mean diameter as a pre-filter. Permeability and molecular weight cut-off of the functional polysulfone(PSf) ultrafiltration membrane to purify waste aqueous IPA solutions were measured through the ultrafiltration test. The solute rejection of PSf membrane had $92\%$ in 1,000ppm aqueous PEG solution with PEG molecular weight 10,000, the molecular weight cut-off had 10,000. The IPA concentration on the $CMPA-K^+$ membrane performance using pervaporation module system could be increased from $95.04 wt\%$ to more than $98.50wt\%$ in about 9hr at operation temperature of $70^{\circ}C$ using the pervaporation module system.

• 한국막학회:학술대회논문집
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• 한국막학회 2005년도 추계 총회 및 학술발표회
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• pp.96-101
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• 2005

A theory for the material transports through ion exchange membrane has been developed on the basis of nonequilibrium thermodynamics by removing the assumption of solvent flow in the previous paper and applied to a detailed study of the ionic transport properties of new charged mosaic membrane(CMM) system. The CMM having two different fixed charges in the polymer membrane indicated unique selective transport behavior then ion-exchange membrane. The separation behavior of ion transport across the CMM with a parallel array of positive and negative functional charges were investigated. It was well-known the analysis of the volume flux and solute flux based on nonequilibrium thermodynamics. Our suggests preferential salt transport across the charged mosaic membranes. Transport properties of heavy metal ions, $Mg^{2+}$, $Mn^{2+}$and sucrose system across the charged mosaic membrane were estimated. As a result, we were known metal salts transport depended largely on the CMM. The reflection coefficient indicated the negative value that suggested preferential material transport and was independent of charged mosaic membrane thickness.

• 공업화학
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• 제10권4호
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• pp.563-567
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• 1999

용질배제율이 우수한 나권형 FT-30 폴리아미드 복합막을 상용하여 cephalosporin C를 농축하기 역삼투 농축실험을 하였다. $4{\sim}20kg/cm^2$의 압력과 100~1000 mg/L의 농도, 그리고 2.8과 5.6 L/min의 유속을 갖는 실험 조건하에서 cephalosporin C 수용액의 수투과율과 용질의 배제율 및 물질전달 계수를 구하였다. Cephalosporin C를 분리하는데 있어서 압력이 증가함에 따라 투과 플럭스가 증가하는 것으로 나타났다. 이 결과는 Kedem-Katchalsky 모델에서 예측한 것과 일치하였다. 그리고 배제율은 1에 가까웠다. 또한 공급액의 농도가 증가할수록 cephalosporin C의 배제율은 낮아지는 것으로 나타났다. 배제율은 고농도보다는 저온도에서 높게 나타났으나 그 감소 정도는 작았다.

• Korean Chemical Engineering Research
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• 제43권2호
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• pp.266-271
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• 2005

혼합유기산으로부터 숙신산의 분리를 단극 분리막을 사용한 탈염전기투석장치를 이용하여 행하였다. 전류효율, 회수율, 에너지소요량, 분리비 등의 변화를 pH 값과 초기농도비에 따라 측정하였다. 숙신산의 분리는 숙신산과 아세트산의 이온화율, 분자량, 이온전도도, 전자가 크기 그리고 초기농도비 등으로 해석될 수 있었다.

• 멤브레인
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• 제32권1호
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• pp.50-56
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• 2022

본 연구에서는 유기용매용 나노여과막 (Organic Solvent Nanofiltration, OSN)의 유기용매 투과 및 분리성능을 분석하였다. 비극성용매에 적합한 Puramem (PM) 시리즈 분리막의 소재를 분석한 후 다양한 유기용매 분위기에서의 투과성능을 데드엔드셀로 측정하였다. PM 시리즈 분리막은 극성용매 대비 비극성용매에서 더 높은 투과도를 보였으며, 용질의 종류 및 분자량에 따라 매우 독특한 배제성능을 보이는 것을 확인하였다. 이는 기존 수처리에 적용되는 Solution-diffusion 투과모델이 OSN 투과모델에는 적합하지 않다는 것을 알 수 있으며, solvent-solute-membrane 간의 상관관계를 더 정확하게 반영할 수 있는 새로운 인자가 필요하다는 결론을 낼 수 있다.

• 멤브레인
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• 제13권1호
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• pp.29-36
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• 2003

A characterization of the permeation and separation using single salt solution was carried out with charged composite membranes. Various charged composite membranes were fabricated by blending an ionic polymer with a nonionic polymer in different ratios. In this study, sodium alginate, chitosan and poly(vinyl alcohol) were employed as anionic, cationic and nonionic polymers, respectively. The permeation and separation behaviors of the aqueous salt solutions have been investigated through the charged composite membranes with various charge densities. As the content of the ionic polymer increased in the membrane, the hydrophilicity of the membrane increased, and pure water flux and the solution flux increased correspondingly, indicating that the permeation performance through the membrane is determined mainly by its hydrophilicity. Electrostatic interaction between the charged membrane and ionic solute molecules, that is, Donnan exclusion, was observed to be attributed to salt rejection to a greater extent, and molecular sieve mechanism was effective for the separation of salts under a similar electrostatic circumstance of solutes.