• Title/Summary/Keyword: Soluble particle

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Dynamic Runoff of Non-point Sources Pollutants from Agricultural Areas (농촌지역에서 유출시간에 따른 비점오염물질의 유출평가)

  • Yi, Qitao;Hur, Chinhyu;Kim, Youngchul
    • Journal of Korean Society on Water Environment
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    • v.24 no.6
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    • pp.773-783
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    • 2008
  • In this paper, data collected from 22 different rural watersheds during stormflow conditions were analyzed. Those watersheds consisted of forest and cultivated land. EMC data analysis indicates that as agricultural land use increases, EMC values of TSS, COD and TN clearly tends to increase, but TP does not show a significant increase. Pattern of the pollutographs mostly has a similarity in hydrograph shape except nitrogen which inherently shows a variability and complication. The fraction of soluble reactive-P to TP increases as cultivated land use increases while mobile-nitrogen portion was higher in the runoff from forested watersheds than agricultural areas. During stormflow, pollutograph of the nitrogen was determined mainly by change in Particle-TKN as other pollutants but its effect is thought to be masked by decrease of dissolved form of nitrogen due to the dilution.

Effects of Moisture Content and Particle Size of Rice Flour on the Physical Properties of the Extrudate (쌀가루의 수분함량과 입자크기에 따른 Extrudate 의 물성학적 성질)

  • Ryu, Gi-Hyung;Lee, Cherl-Ho
    • Korean Journal of Food Science and Technology
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    • v.20 no.4
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    • pp.463-469
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    • 1988
  • The effects of moisture content and particle size of rice flour on the physical properties of the extrudate were examined by using a autogeneous single screw extruder. The moisture contents tested were in the range of 17-28% and the particle sizes were 18-60mesh and 60-120mesh. Samples were taken at different temperatures from the start-up period to the steady state operation. The expansion ratio increased and bulk density decreased as the moisture content and particle size of the flour decreased. The cutting force decreased and the air cell size became uniform as the moisture content and particle size of the flour decreased. As the moisture content increased, the yellowness of the extrudate powder decreased, while the lightness increased, the apparent viscosity increased and the water soluble index decreased. Gelatinization and partial dextrinization were apparent during the extrusion process, and the degree of dextrinization was appeared to be influenced by the levels of moisture content and particle size of rice flour.

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Study on the Factor of Water Retention Capacity of Cement Mortar by Hydroxyalkyl Methylcellulose Ether (히드록시알킬 메틸셀룰로오스가 시멘트 모르타르의 보수성에 미치는 영향에 관한 연구)

  • 이무진
    • Journal of the Korea Concrete Institute
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    • v.11 no.3
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    • pp.153-160
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    • 1999
  • Water soluble hydroxyalkyl methycellulose ethers are used in a variety of applications incluing building industry as a supplementary agent used for incresing adhesives, water retention capacity, workability and viscosity modify. Water retention capacity(WRC) is the capability to contain water in the ploymer chain under condition of being mixed with cement. In general, the WRC is affected by the viscosity, the adding amount, the particle size, the rate of dissolving and the amount of substituted chemical in cellulose ethers. In the other words, WRC is increased as higher the viscosity, more adding amount, finer the particle size and longer the dissolving time of cellulose ethers. This thesis investigated each factor that effect the WRC, particularly the relation between degree of substitution(DS), molar of substitution(MS) and WRC. It is observed that WRC is not nearly affected by DS of cellulose ethers, but is changes proportionally as MS increases in the narrow range(0.10~2.25)

Mass Concentration and Ion Composition of Size-segregated Particulate Matter during the Non-Asian Dust Storm of Spring 2007 in Iksan (익산지역에서 봄철 비황사기간 중 입경별 대기먼지농도와 이온조성)

  • Kang, Gong-Unn;Kim, Nam-Song;Lee, Hyun-Ju
    • Journal of Environmental Health Sciences
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    • v.34 no.4
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    • pp.300-310
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    • 2008
  • In order to further determine the mass concentration and ion composition of size-segregated particulate matter (PM) during the non-Asian dust storm of spring, $PM_{2.5}$ (fine particle), $PM_{10-2.5}$ (coarse particle), and $PM_{over-10}$ (PM with an aerodynamic diameter larger than $10{\mu}m$) were collected using a MCI (multi-nozzle cascade impactor) sampler of a three-stage filter pack in the spring season of 2007 in the Iksan area. During the sampling period from 5 April to 21 April, a total of 34 samples for size-segregated PM were collected, and then measured for PM mass concentrations by gravimetric measurements and for water-soluble inorganic ion species by using ion chromatography. Average mass concentrations of $PM_{2.5}$, $PM_{10-2.5}$, $PM_{over-10}$ were $35.4{\pm}11.5{\mu}g/m^3$, $13.3{\pm}5.5{\mu}g/m^3$ and $9.5{\pm}4.7{\mu}g/m^3$, respectively. On average, $PM_{2.5}$ accounted for 74% of $PM_{10}$. Compared with the literature from other areas in Korea, the measured concentration of $PM_{2.5}$ were relatively high. Water-soluble inorganic ion fractions in $PM_{2.5}$, $PM_{10-2.5}$, and $PM_{over-10}$ were found to be 47.8%, 28.5%, and 14.7%, respectively. Among the water-soluble inorganic ion species, $SO_4^{2-}$, $NO_3^-$ and $NH_4^+$ were the main components in $PM_{2.5}$, while $NO_3^-$ dominantly existed in both $PM_{10-2.5}$ and $PM_{over-10}$. Non-seasalt $SO_4^{2-}$ (nss-$SO_4^{2-}$ and $NO_3^-$ were found to mainly exist as the neutralized chemical components of $(NH_4)_2SO_4$ and $NH_4NO_3$ in fine particles.

pH Solubility Properties and Improved Dissolution of Pranlukast as an Poorly Water-soluble Model Drug Prepared by Spray-drying with Plasdone S-630 (플라스돈 S-630과 함께 분무건조된 모델 난용성 약물로서 프란루카스트의 pH 용해도 특성 및 용출률 개선)

  • Cho, Won-Hyung;Lee, Young-Hyun;Song, Byung-Joo;Yoo, Seok-Cheol;Lim, Dong-Kyun;Khang, Gil-Son
    • Polymer(Korea)
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    • v.35 no.4
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    • pp.277-283
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    • 2011
  • Solid dispersion is mainly used for improved dissolution of poorly water-soluble drugs. Solid dispersion of pranlukast was prepared by spray-drying with plasdone S-630. When pH of water was high, pranlukast was highly soluble in the solubility experiment of solid dispersions with varying pH. The particle size of pranlukast particles in solid dispersions was measured to be in nanometers scale based on particle size analysis. Zeta-potential analysis confirmed the negative charge of solid dispersion. SEM was used to observe the surface of solid dispersion, which confirmed spherical morphology, DSC and XRD confirmed the amorphous nature of solid dispersions. The in vitro test was carried out to find improved dissolution rate of pranlukast solid dispersion in simulated juice gastric and a controlled experiment was carried out to compare pranlukast solid dispersions with a conventional drug (Onon$^{(R)}$), These results showed the dissolution properties of pranlukast solid dispersions prepared by spray drying proper for the oral pharmaceutical formulation.

Preparation and Characterizations of C60/Polystyrene Composite Particle Containing Pristine C60 Clusters

  • Kim, Jung-Woon;Kim, Kun-Ji;Park, Soo-Yeon;Jeong, Kwang-Un;Lee, Myong-Hoon
    • Bulletin of the Korean Chemical Society
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    • v.33 no.9
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    • pp.2966-2970
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    • 2012
  • Fullerene/polystyrene ($C_{60}$/PS) nano particle was prepared by using emulsion polymerization. Styrene and fullerene were emulsified in aqueous media in the presence of poly(N-vinyl pyridine) as an emulsion stabilizer, and polymerization was initiated by water soluble radical initiator, potassium persulfate. The obtained nano particles have an average diameter in the range of 400-500 nm. The fullerene contents in the nano particle can be controlled up to 15 wt % by varying the feed ratio, which was confirmed by themogravimetric analysis (TGA) and elemental analysis (EA). The structure and morphologies of the $C_{60}$/PS nano particles were examined by various analytical techniques such as dynamic light scattering (DLS), scanning electron microscope (SEM), transmission electron microscope (TEM), electron diffraction (ED) pattern, X-ray powder diffraction (XRD), and UV spectroscopy. Unlike conventional $C_{60}$/PS particles initiated by organic free radical initiators, in which the fullerene is copolymerized forming a covalent bond with styrene monomer, the prepared $C_{60}$/PS nano particles contain pristine fullerene as secondary particles homogeneously distributed in the polystyrene matrix.

Development of New Products and High Value Added Biopolymer from Softwoods by Chemical Modification - Quantitative Variation of Water-soluble Extracts from Coniferous Barks for Tannin-based Adhesives - (화학가공에 의한 침엽수재의 품질귀화 및 고부가 Biopolymer 개발 (I) - 타닌접착제를 위한 침엽수 수피의 수용성 추출물의 양적 변이 -)

  • Cho, Nam-Seok;Han, Gyu-Seong
    • Journal of the Korean Wood Science and Technology
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    • v.24 no.4
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    • pp.1-6
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    • 1996
  • Extracts from bark have been studied with a view to producing water-proof wood adhesives. Lately many softwoods, such as radiata pine from New Zealand and larch from Siberia, Russia, have been imported and utilized, and their residual barks would be expecting as potential raw materials for something useful chemicals. The great effort toward utilization of bark extractives as a chemical feedstock has been made on a worldwide level. However few report has been done for the utilization of tree bark extractives in Korea. Hot-water extracts were prepared from barks of Japanese larch(Larix leptolepis). Siberian larch(Larix gmelinii) and Radiata pine(Pinus radiata). The effect of various factors, such as particle size, liquor ratio, extraction temperature, and reaction time, on the extractive yields was discussed. Particle sizes affected the hot-water extractives: the finer the particle size, the higher extractives and extract efficiency. Higher temperature and higher liquor ratio were more effective. Extractives from Japanese larch were relatively less than those from Siberian larch and Radiata pine barks. Formaldehyde precipitates was the highest in extractives of Radiata pine barks. It could be concluded that Siberian larch bark was the best raw material for tannin adhesives, because its extractive yield was higher than those of the other barks.

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Effects of Recycled Washwater on Pollutant Removal and Particle Characteristics during Coagulation (회수수가 응집공정의 오염물질 제거 및 입자특성에 미치는 영향)

  • 문병현;김승현;박미선;이향인;이강춘
    • Journal of Environmental Science International
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    • v.11 no.9
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    • pp.955-960
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    • 2002
  • The recycled washwater, which has different water quality and is produced about 5 to 20% of the total water volume treated, affects the unit operation of water treatment, especially coagulation process. However, the effects of recycled washwater on unit operation of water treatment have not been fully investigated. In this study, effects of recycled washwater on coagulation process were investigated to find the optimum coagulation condition by analyzing turbidity, $UV_{254}$, TOC removal efficiencies. In addition, effects of recycled washwater on residual Al after coagulation were studied by analyzing soluble and particulate Al. The size distribution and fractal dimension of coagulated also analyzed. The recycled washwater was lower pH than the raw water. And the recycled washwater had higher $UV_{254}$, TOC and residual Al concentration than the raw water. Residual Al concentration of recycled washwater was about 50 times higher than that of raw water. Optimum coagulant dosages on the blending recycled washwater and the raw water for turbidity, $UV_{254}$ and Al removal were lower than that on the raw water. However, TOC removal increased by increasing coagulant dosage. The size and fractal dimension of coagulated particle produced in the blending recycled washwater were larger, which imply faster settling velocity, than those produced in the raw water only.

Effects of alkali species and concentration on the size distribution of the co-precipitated magnetite particles used for phosphate adsorption (인 흡착용 마그네타이트 합성 시 알칼리 종류 및 농도가 공침 입자크기에 미치는 영향)

  • Lee, Minhyeong;Doliente, Jonica Ella;Nam, Haiuk;Kim, Yunjung;Choi, Younggyun
    • Journal of Korean Society of Water and Wastewater
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    • v.30 no.4
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    • pp.409-415
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    • 2016
  • Magnetite particles were synthesized by co-precipitation of water-soluble 밀 스케일-derived precursor by various concentrations of (0.5, 0.67, 1, 2 N) NaOH and (0.6, 0.8, 1.2, 2.4 N) $NH_4OH$. It is theoretically known that as the concentration of the alkaline additive used in iron oxide synthesis increases, the particle size distribution of that iron oxide decreases. This trend was observed in both kind of alkaline additive used, NaOH and $NH_4OH$. In addition, the magnetite synthesized in NaOH showed a relatively smaller particle size distribution than magnetite synthesized in $NH_4OH$. Crystalline phase of the synthesized magnetite were determined by X-ray diffraction spectroscopy(XRD). The particles were then used as an adsorbent for phosphate(P) removal. Phosphorus adsorption was found to be more efficient in NaOH-based synthesized magnetite than the $NH_4OH$-based magnetite.

Effect of Homogenization Pressure on Plasmin Activity and Mechanical Stress-Induced Fat Aggregation of Commercially Sterilized Ultra High Temperature Milk during Storage

  • Kim, Sun-Chul;Yun, So-Yul;Ahn, Na-Hyun;Kim, Seong-Min;Imm, Jee-Young
    • Food Science of Animal Resources
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    • v.40 no.5
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    • pp.734-745
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    • 2020
  • Commercially sterilized ultra high temperature (UHT) milk was manufactured at different homogenization pressures (20, 25, and 30 MPa), and changes in fat particle size, mechanical stress-induced fat aggregation, plasmin activity, and lipid oxidation were monitored during ambient storage of the UHT milk for up to 16 wk. The particle sizes of milk fat globules were significantly decreased as homogenization pressure increased from 20 to 30 MPa (p<0.05). The presence of mechanical stress-induced fat aggregates in milk produced at 20 MPa was significantly higher than for UHT milk produced at either 25 or 30 MPa. This difference was maintained all throughout the storage. There were no significant differences in plasmin activity, trichloroacetic acid (12%, w/v) soluble peptides, and the extent of lipid oxidation. Based on these results, an increase of homogenization pressure from 20 (the typical homogenization pressure employed in the Korea dairy industry) to 25-30 MPa significantly decreased mechanical stress-induced fat aggregation without affecting susceptibility to lipid oxidation during storage.